1,4-Bis(3,4-dicarboxytrifluorophenoxy)tetrafluorobenzene dianhydride | 143363-91-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,4-Bis(3,4-dicarboxytrifluorophenoxy)tetrafluorobenzene dianhydride
• 英文别名: 4,4'-[(2,3,5,6-tetrafluoro-1,4-phenylene)bis(oxy)]bis(3,5,6-trifluorophthalic anhydride)；5,5'-[(2,3,5,6-Tetrafluoro-1,4-phenylene)bis(oxy)]bis[4,6,7-trifluoro-1,3-isobenzofurandione]；4,5,7-trifluoro-6-[2,3,5,6-tetrafluoro-4-[(4,6,7-trifluoro-1,3-dioxo-2-benzofuran-5-yl)oxy]phenoxy]-2-benzofuran-1,3-dione
• CAS: 143363-91-1
• 化学式: C₂₂F₁₀O₈
• 分子量: 582.221
• InChiKey: WPFASWCWIDNSSX-UHFFFAOYSA-N

物化性质

• 沸点：
  489.7±45.0 °C(Predicted)
• 密度：
  1.947±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  40
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  氯化亚砜 、 1,4-bis(3,4-dicarboxy-2,5,6-trifluorophenoxy)tetrafluorobenzene 反应 26.0h， 以97%的产率得到1,4-Bis(3,4-dicarboxytrifluorophenoxy)tetrafluorobenzene dianhydride
  参考文献：
  名称：

  Fluorinated bis(phthalic anhydride) and method for producing the same

  摘要：

  本发明的目的是提供具有比传统化合物更少着色和更高溶解性的氟化双(邻苯二甲酸酐)以及其生产方法。此外，本发明还旨在提供一种用于生产氟化双(邻苯二腈)化合物的方法，该化合物是生产氟化双(邻苯二甲酸酐)的中间原料化合物，并且提供由氟化双(邻苯二甲酸酐)生产的聚酰胺酸和聚酰亚胺的方法。本发明的氟化双(邻苯二甲酸酐)是由以下式(I1)表示的氟化双(邻苯二甲酸酐)，其中其比表面积为3.0 m2/g或更大。其特征在于，在360 nm波长处，其摩尔吸光系数不超过0.6 L/mol·cm。【其中，m和n独立表示1到3的整数，Z1表示单键基团或二价有机基团。】

  公开号：

  US20050020839A1

文献信息

• Method for production of fluorinated phenylenediamine
  申请人：Nishimae Shinji

  公开号：US20060142539A1

  公开（公告）日：2006-06-29

  A method for the production of a fluorinated phenylenediamine is provided which comprises steps of reacting a diamide represented by the following formula with NaOCl at a molar ratio of the NaOCl to the diamide in the range of 2.0-6.0 and NaOH at a molar ratio of the NaOH to the diamide in the range of 1.8-6.0 is provided. According to this invention, the fluorinated phenylenediamine can be produced conveniently in a high yield.

  本发明提供了一种生产氟代苯二胺的方法，其中包括以下步骤：将以下式子所表示的二酰胺与NaOCl在NaOCl与二酰胺的摩尔比在2.0-6.0范围内以及NaOH在NaOH与二酰胺的摩尔比在1.8-6.0范围内反应。根据本发明，可以方便地高产地生产氟代苯二胺。
• THIN FILM TRANSISTOR SUBSTRATE
  申请人：FUKUDA Shunji

  公开号：US20130126860A1

  公开（公告）日：2013-05-23

  A main object of the present invention is to provide a TFT substrate having excellent switching characteristics. The object is attained by providing a thin film transistor substrate comprising: a substrate, and a thin film transistor having an oxide semiconductor layer that is formed on the substrate and is formed from an oxide semiconductor, and a semiconductor layer-adjoining insulating layer formed to be in contact with the oxide semiconductor layer, wherein at least one semiconductor layer-adjoining insulating layer included in the thin film transistor is a photosensitive polyimide insulating layer formed by using a photosensitive polyimide resin composition.

  本发明的主要目的是提供一种具有优异开关特性的TFT基板。该目标通过提供一种薄膜晶体管基板来实现，该基板包括：基板和薄膜晶体管，所述薄膜晶体管具有在基板上形成的氧化物半导体层，该氧化物半导体层由氧化物半导体形成，并且与氧化物半导体层接触的半导体层相邻的绝缘层，其中，在薄膜晶体管中包括的至少一个半导体层相邻的绝缘层是使用光敏聚酰亚胺树脂组合物形成的光敏聚酰亚胺绝缘层来实现的。
• BIS (FLUORINE-CONTAINING PHTHALIC ANHYDRIDE) AND METHOD FOR PRODUCTION THEREOF
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1640370A1

  公开（公告）日：2006-03-29

  It is an object of the present invention to provide fluorinated bis(phthalic anhydride) which has less coloration and higher solubility in comparison with conventional compounds, and a method for producing the same. Further, it is also an object of the present invention to provide a method for producing a fluorinated bis(phthalonitrile) compound, which is an intermediate raw material compound of the method for producing the fluorinated bis(phthalic anhydride), and a polyamic acid and a polyimide, which are produced from the fluorinated bis(phthalic anhydride). A fluorinated bis(phthalic anhydride) of the present invention is the fluorinated bis(phthalic anhydride) represented by the following formula (I1), wherein its specific surface area is 3.0 m2/g or larger. It is also characterized in that its molar absorption coefficient is 0.6 L/mol-cm or less at a wavelength of 360 nm. [wherein, m and n independently represent integers of 1 to 3, and Z1 represents a single bond group or a bivalent organic group.]

  本发明的目的是提供与传统化合物相比着色更少、溶解度更高的氟化双（邻苯二甲酸酐），以及生产这种化合物的方法。此外，本发明的另一个目的是提供一种氟化双（邻苯二甲酸酐）化合物的生产方法，该化合物是氟化双（邻苯二甲酸酐）生产方法的中间原料化合物，以及由氟化双（邻苯二甲酸酐）生产的聚酰胺和聚酰亚胺。本发明的氟化双（邻苯二甲酸酐）是由下式（I1）表示的氟化双（邻苯二甲酸酐），其中其比表面积为 3.0 m2/g 或更大。其特征还在于，在波长为 360 纳米时，其摩尔吸收系数为 0.6 L/mol-cm 或以下。 [其中，m 和 n 分别代表 1 至 3 的整数，Z1 代表单键基团或二价有机基团。］
• Fluorinated polyamide acid resin composition for optical materials
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1757957A2

  公开（公告）日：2007-02-28

  A fluorinated polyamide acid resin composition for optical materials containing a fluorinated polyamide acid and a non-polycondensable compound (A) with an aromatic ring having a boiling point of 340°C or lower, the resin composition being used for obtaining a fluorinated polyimide membrane by a baking process. This fluorinated polyamide acid resin composition for optical materials contains a non-polycondensable compound (A) which was found to reduce a light absorption at 1.49 µm and a light absorption at 1.35 µm and extending to visible light, even if the baking temperature is 340°C or lower.

  一种光学材料用氟化聚酰胺酸树脂组合物，含有氟化聚酰胺酸和沸点为 340°C 或更低的带有芳香环的不聚凝化合物 (A)，该树脂组合物用于通过烘烤工艺获得氟化聚酰亚胺膜。这种用于光学材料的氟化聚酰胺酸树脂组合物含有一种非聚凝性化合物 (A)，即使烘烤温度为 340°C 或更低，它也能降低 1.49 µm 处的光吸收和 1.35 µm 处的光吸收，并延伸至可见光。
• Halogenated polyamide acid composition and its applications
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1760114A2

  公开（公告）日：2007-03-07

  A halogenated polyamide acid composition containing a halogenated polyamide acid, a metal oxide precursor, a catalyst of reaction of generating a metal oxide from the precursor, and/or a coupling agent having a reactive group. A halogenated polyimide film is obtained by, for example, carrying out the heat treatment of the halogenated polyamide acid composition. The halogenated polyimide film has a refractive index at wavelength of, for example, 1,550 nm of 1.520 or lower. Further, an optical waveguide uses the halogenated polyimide film as at least one of a core layer and a clad layer, and a relative refractive index difference between the core layer and the clad layer of the optical waveguide is, for example, 0.6 or greater. An optical waveguide device contains such an optical waveguide.

  卤化聚酰胺酸组合物，含有卤化聚酰胺酸、金属氧化物前体、从前体生成金属氧化物的反应催化剂和/或具有活性基团的偶联剂。例如，通过对卤化聚酰胺酸组合物进行热处理，可获得卤化聚酰亚胺薄膜。卤化聚酰亚胺薄膜在波长为 1 550 纳米时的折射率为 1.520 或更低。此外，光波导使用卤化聚酰亚胺薄膜作为芯层和铠装层中的至少一层，光波导的芯层和铠装层之间的相对折射率差为 0.6 或更大。光波导设备包含这样的光波导。