{N,N'-bis(3-formyl-5-methylsalicylidene)propane-1,3-diaminato}copper(II) | 33594-19-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {N,N'-bis(3-formyl-5-methylsalicylidene)propane-1,3-diaminato}copper(II)
• CAS: 33594-19-3；37646-70-1
• 化学式: C₂₁H₂₀CuN₂O₄
• 分子量: 427.947
• InChiKey: HODADPYJPNXQDV-NIUDKRPCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  manganese(II) chloride tetrahydrate 、 {N,N'-bis(3-formyl-5-methylsalicylidene)propane-1,3-diaminato}copper(II) 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent copper(I)copper(II) complex

  摘要：

  DOI：

  10.1021/ja00404a017
• 作为产物：
  描述：

  2,6-二甲酰-4-甲基苯酚 、 1,3-丙二胺 、 copper(II) acetate monohydrate 以 N,N-二甲基甲酰胺 为溶剂， 生成 {N,N'-bis(3-formyl-5-methylsalicylidene)propane-1,3-diaminato}copper(II)
  参考文献：
  名称：

  The synthesis, redox properties, and ligand binding of heterobinuclear transition-metal macrocyclic ligand complexes. Measurement of an apparent delocalization energy in a mixed-valent copper(I)copper(II) complex

  摘要：

  DOI：

  10.1021/ja00404a017

文献信息

• Metalloamphiphiles with [Cu ₂ ] and [Cu ₄ ] Headgroups: Syntheses, Structures, Langmuir Films, and Effect of Subphase Changes
  作者：Sarmad Sahiel Hindo、Rajendra Shakya、Rama Shanmugam、Mary Jane Heeg、Cláudio N. Verani

  DOI：10.1002/ejic.200900636

  日期：2009.11

  The metalloamphiphiles [(L PM18 ) 2 Cu 2 Cl 2 ]·H 2 O (1), [(L PMtax ) 2 -Cu 2 Cl 2 ]·2MeOH (2), [(L OF18 ) 2 Cu 2 Cl 2 ] (3), [(L OF18 ) 2 Cu 4 (μ 4 -O)-(μ 2 -OAc) 4 ] (4), [(L OF14 ) 2 Cu 4 (μ 4 -O)(μ 2 -OAc) 4 ] (5) were synthesized and characterized by means of several spectroscopic and spectrometric methods. The acronyms L PMC18 , L PMtax , L OF18 , and L OF14 indicate the deprotonated forms of

  金属两亲化合物[(L PM18 ) 2 Cu 2 Cl 2 ]·H 2 O (1), [(L PMtax ) 2 -Cu 2 Cl 2 ]·2MeOH (2), [(L OF18 ) 2 Cu 2 Cl 2 ] (3), [(L OF18 ) 2 Cu 4 (μ 4 -O)-(μ 2 -OAc) 4 ] (4), [(L OF14 ) 2 Cu 4 (μ 4 -O)(μ 2 -OAc) ) 4 ] (5) 是通过几种光谱和光谱方法合成和表征的。首字母缩写词 L PMC18、L PMtax、L OF18 和 L OF14 表示基于连接到十八烷基的 2,6-双（亚氨基甲基）-4-甲基苯酚的假大环 (PM) 和开框 (OF) 配体的去质子化形式(18)、三烷氧基胺 (tax) 和十四烷基 (14) 部分，而 Cl- 和 OAc - 表示氯和乙酰基多配体。获得了在具有 P1 空间群的三斜晶体系统中结晶的
• A rational assembly of a series of exchange coupled linear heterotrinuclear complexes of the type MAMBMC as exemplified by FeIIICuIINiII, FeIIINiIICuII and CoIIICuIINiII
  作者：Cláudio Nazari Verani、Thomas Weyhermüller、Eva Rentschler、Eckhard Bill、Phalguni Chaudhuri

  DOI：10.1039/a806575f

  日期：——

  A general approach for the rational synthesis of linear trinuclear complexes containing three different metals MAMBMC is described and a member of the series, FeIIICuIINiII, has been characterized by X-ray crystallography and magnetic susceptibility measurements.

  本文介绍了合理合成含有三种不同金属亚甲基溴联苯胺的线性三核络合物的一般方法，并通过 X 射线晶体学和磁感应强度测量对该系列的一个成员--FeIIICuIINiII 进行了表征。
• Dinuclear copper(II), nickel(II) and mixed valence CuII-CuI complexes: influence of donor groups on redox behaviour of dicopper complexes
  作者：B. Srinivas、P.S. Zacharias

  DOI：10.1016/s0277-5387(00)83744-4

  日期：——

  Dinuclear copper(II) and nickel(II) complexes of hexadentate Schiff base ligands derived from 2,6-diformyl-4-methylphenol, 1,3-diaminopropane with various ortho and/or para substituted anilines have been synthesized and investigated for their magnetic and electrochemical properties. The dinuclear copper(II) complexes exhibit strong antiferromagnetic interactions between the metal centres (mu(eff)/copper atom = 0.98-1.10-mu(B)). For the nickel(II) complexes the interaction is weak (mu(eff)/nickel atom = 2.83-3.02 mu(B)). These complexes undergo sequential one-electron transfers at two different potentials. The first electron-reduction potential (E1) shifts to more negative values for copper(II) complexes having potential donor groups at the ortho position of the phenylazomethine ring. This has been attributed to the weak bonding interaction of these groups with the central metal ion. Analogous mononuclear copper(II) complexes with donor groups such as OMe, OEt and SMe are shown to give irreversible CV peaks. Mixed-valence Cu(II)-Cu(I) complexes of analogous para substituted anilines have been synthesized by chemical methods and the unpaired electron is found to be localized on one of the coppers.
• Tadokoro, Makoto; Sakiyama, Hiroshi; Matsumoto, Naohide, Journal of the Chemical Society, Dalton Transactions, 1992, # 1.2, p. 313 - 318
  作者：Tadokoro, Makoto、Sakiyama, Hiroshi、Matsumoto, Naohide、Kodera, Masahito、Oekawa, Hisashi、Kida, Sigeo

  DOI：——

  日期：——
• Srinivas, Bhamidi; Zacharias, Panthappally S., Canadian Journal of Chemistry, 1992, vol. 70, # 12, p. 2906 - 2913
  作者：Srinivas, Bhamidi、Zacharias, Panthappally S.

  DOI：——

  日期：——