(η-1,5-Cyclooctadien)(η-1'-phenyl-2',4'-cyclopentadienyl)cobalt

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (η-1,5-Cyclooctadien)(η-1'-phenyl-2',4'-cyclopentadienyl)cobalt
• 化学式: C₁₉H₂₁Co
• 分子量: 308.369
• InChiKey: CDZAYQWQXWQIES-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η-1,5-Cyclooctadien)(η-1'-phenyl-2',4'-cyclopentadienyl)cobalt 、 1,6-cyclodecadiyne 以 正辛烷 为溶剂， 以19-26的产率得到(η4:η4-{3(4)}cyclobutadienophane)bis{(η5-(phenyl)cyclopentadienyl)cobalt}
  参考文献：
  名称：

  Reaction of 1,6-cyclodecadiyne and 1,8-cyclotetradecadiyne with substituted CpCo(cod)

  摘要：

  The yields of CpCo-capped cyclobutadiene superphane from 1,6-cyclodecadiyne (1) and (R-C5H4)Co(cod) varies considerably with the substituents R. Electron-withdrawing substituents give yields between 35 and 45 % while electron-donating substituents give very small yields. In the case of 1,8-cyclotetradecadiyne (2) such a dependence on R is much less pronounced. The reaction between 1 and 2 and the indenyl complex (eta5-C9H7)Co(cod) is also reported.

  DOI：

  10.1021/om00029a051
• 作为产物：
  描述：

  、 1,5-环辛二烯 在 lithium 作用下， 以 四氢呋喃 为溶剂， 以45.6%的产率得到(η-1,5-Cyclooctadien)(η-1'-phenyl-2',4'-cyclopentadienyl)cobalt
  参考文献：
  名称：

  A correlation between 13C and 59Co NMR data and the catalytic activity of organocobalt complexes in the synthesis of pyridine derivatives

  摘要：

  DOI：

  10.1016/0022-328x(84)80468-4

文献信息

• The preparation of finely divided metal powders and transition metal complexes using “organically solvated” magnesium
  作者：Helmut Bönnemann、Borislav Bogdanović、Rainer Brinkmann、Bernd Spliethoff、Da-Wei He

  DOI：10.1016/0022-328x(93)83004-f

  日期：1993.6

  Mg★ is an excellent in situ reducing agent for transition metal salts, giving highly reactive metal powders of Groups 8–12. In the presence of electron donor ligands, this reduction provides a useful one-step route to organotransition metal complexes. The application of 35 kHz ultrasound during the reaction improves the dispersity of the metal powders and enhances the yields of the complexes.

  用少量蒽在THF中处理市售镁粉会生成高活性形式的镁（Mg★）。Mg★是一种出色的过渡金属盐原位还原剂，可产生8-12组的高反应性金属粉末。在电子给体配体的存在下，这种还原为有机过渡金属配合物提供了有用的一步法。反应过程中施加35 kHz超声波可改善金属粉末的分散性，并提高配合物的收率。
• Steuerung der katalytischen Pyridinsynthese aus Alkien and Nitrilien durch (η⁶-Borinato)-Liganden am Cobalt
  作者：Helmut Bönnemann、Werner Brijoux、Rainer Brinkmann、Willi Meurers

  DOI：10.1002/hlca.19840670630

  日期：1984.9.26

  Control of the Catalytic Synthesis of Pyridine from Alkynes and Nitriles by the (η6-Borinato)-Nigands at Cobalt

  吡啶的从炔烃和腈的催化合成的控制由（η 6 -Borinato）-Nigands在钴
• Reaction of 1,6-cyclodecadiyne and 1,8-cyclotetradecadiyne with substituted CpCo(cod)
  作者：Rolf Gleiter、Georg Pflaesterer

  DOI：10.1021/om00029a051

  日期：1993.5

  The yields of CpCo-capped cyclobutadiene superphane from 1,6-cyclodecadiyne (1) and (R-C5H4)Co(cod) varies considerably with the substituents R. Electron-withdrawing substituents give yields between 35 and 45 % while electron-donating substituents give very small yields. In the case of 1,8-cyclotetradecadiyne (2) such a dependence on R is much less pronounced. The reaction between 1 and 2 and the indenyl complex (eta5-C9H7)Co(cod) is also reported.
• A correlation between 13C and 59Co NMR data and the catalytic activity of organocobalt complexes in the synthesis of pyridine derivatives
  作者：Helmut Bönnemann、Werner Brijoux、Rainer Brinkmann、Willi Meurers、Richard Mynott、Wolfgang Von Philipsborn、Thomas Egolf

  DOI：10.1016/0022-328x(84)80468-4

  日期：1984.9