2-((4-(tertbutyl)phenyl)thio)ethan-1-amine | 14289-06-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-((4-(tertbutyl)phenyl)thio)ethan-1-amine
• 英文别名: 2-(4-tert.-Butyl-phenylmercapto)-aethylamin；2-(4-tert-butylphenylthio)ethylamine；2-(4-tert-butyl-phenylsulfanyl)-ethylamine；2-(4-t-Butylphenylthio)ethylamine；2-(4-tert-butylphenyl)sulfanylethanamine
• CAS: 14289-06-6
• 化学式: C₁₂H₁₉NS
• 分子量: 209.356
• InChiKey: XOUBEITULJPUBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-((4-(tertbutyl)phenyl)thio)ethan-1-amine 在 硫酸 作用下， 以 四氢呋喃 为溶剂， 生成 3-[2-(4-tert-butyl-phenylsulfanyl)-ethyl]-4-carboxymethyl-sydnone
  参考文献：
  名称：

  抗炎性sydnones。2。

  摘要：

  DOI：

  10.1021/jm00235a011
• 作为产物：
  描述：

  2-氯乙胺盐酸盐 、 以 乙醇 为溶剂， 生成 2-((4-(tertbutyl)phenyl)thio)ethan-1-amine
  参考文献：
  名称：

  Pagani; Borgna; Baruffini, Farmaco, Edizione Scientifica, 1967, vol. 22, # 7, p. 519 - 527

  摘要：

  DOI：

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Thioether Ligand-Enabled Cationic Palladium(II)-Catalyzed Electrophilic C–H Arylation of α,β-Unsaturated Oxime Ethers
  作者：Takahiro Yamada、Yoshimitsu Hashimoto、Kosaku Tanaka、Nobuyoshi Morita、Osamu Tamura

  DOI：10.1021/acs.joc.0c01570

  日期：2020.10.2

  The use of the cationic palladium(II) catalyst realized electrophilic C–H arylation of α,β-unsaturated O-SEM oximes with arylboronic acids. This Pd-catalyzed electrophilic C–H arylation is facilitated by employing alkyl aryl thioether ligands, and optimization of the ligand structure greatly improves the yield. The resulting α,β-unsaturated oximes would provide access to multisubstituted heterocyclic

  阳离子钯（II）催化剂的使用实现了α，β-不饱和O - SEM肟与芳基硼酸的亲电C–H芳基化。通过使用烷基芳基硫醚配体可以促进这种Pd催化的亲电C–H芳基化，配体结构的优化大大提高了收率。所得的α，β-不饱和肟将提供多取代杂环化合物的获得。
• Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
  申请人：Small L. Brooke

  公开号：US20070112150A1

  公开（公告）日：2007-05-17

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明揭示了一种具有苯基硫醇或取代苯基硫醇金属配位基团的新型α-二亚胺金属配合物，特别是铁配合物。该α-二亚胺金属配合物具有苯基硫醇或取代苯基硫醇金属配位基团，是通过在金属盐或α-酰基亚胺金属配合物存在下形成α-二亚胺金属配合物亚胺键之一来制备的。具有苯基硫醇或取代苯基硫醇金属配位基团的α-二亚胺金属配合物对于聚合或寡聚烯烃非常有用。
• Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
  申请人：Chevron Phillips Chemical Company LP

  公开号：US07977269B2

  公开（公告）日：2011-07-12

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明公开了一种具有苯基硫醇或取代苯基硫醇金属配位基团的α-二亚胺金属配合物，特别是铁配合物。通过在金属盐或α-酰基亚胺金属配合物存在下形成α-二亚胺金属配合物亚胺键之一，可以制备具有苯基硫醇或取代苯基硫醇金属配位基团的α-二亚胺金属配合物。具有苯基硫醇或取代苯基硫醇金属配位基团的α-二亚胺金属配合物可用于聚合或寡聚烯烃。
• Diimine Metal Complexes, Methods of Synthesis, and Methods of Using in Oligomerization and Polymerization
  申请人：Small Brooke L.

  公开号：US20100222577A1

  公开（公告）日：2010-09-02

  Novel α-diimine metal complexes, particularly iron complexes, having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are disclosed. The α-diimine metal complexes having a phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are produced by forming one of the α-diimine metal complex imine bonds in the presence of a metal salt or an α-acylimine metal complex. The α-diimine metal complexes having phenyl sulfidyl or substituted phenyl sulfidyl metal complexing group are useful for polymerizing or oligomerizing olefins.

  本发明揭示了一种具有苯基硫醇或取代苯基硫醇金属配合基的 Novel α-二亚胺金属配合物，特别是铁配合物。通过在金属盐或α-酰亚胺金属配合物的存在下形成α-二亚胺金属配合物之一的亚胺键来制备具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物。具有苯基硫醇或取代苯基硫醇金属配合基的α-二亚胺金属配合物可用于聚合或寡聚烯烃。