3-methylsulfanylbiphenyl | 31477-46-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-methylsulfanylbiphenyl
• 英文别名: 3-(methylthio)biphenyl；3-methylthiobiphenyl；3-Biphenylmethylsulfid；1,1'-Biphenyl, 3-(methylthio)-；1-methylsulfanyl-3-phenylbenzene
• CAS: 31477-46-0
• 化学式: C₁₃H₁₂S
• 分子量: 200.304
• InChiKey: PLVZFEDCBAPFKS-UHFFFAOYSA-N

物化性质

• 沸点：
  332.3±21.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-methylsulfanylbiphenyl 在 三乙基硅烷 、 palladium dichloride 作用下， 以 四氢呋喃 为溶剂， 反应 1.33h， 以99%的产率得到联苯
  参考文献：
  名称：

  Pd-catalyzed reductive cleavage of alkyl aryl sulfides with triethylsilane that is accelerated by trialkylsilyl chloride

  摘要：

  The palladium-catalyzed reductive cleavage of alkyl aryl sulfides to afford the corresponding arenes in high yield, which is both accelerated and exhibits increased functional group selectivity in the presence of TMSCI, is described. This ligand-free reaction features mild conditions, easy operation, use of readily available reagents, and high functional group selectivity. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.06.002
• 作为产物：
  描述：

  1,1-Bis-methylsulfanyl-3-phenyl-hexa-1,5-dien-3-ol 在 三氟化硼乙醚 作用下， 以 苯 为溶剂， 反应 0.5h， 以45%的产率得到3-methylsulfanylbiphenyl
  参考文献：
  名称：

  Cationic benzoannelation of active methylene ketones via oxoketendithioacetals

  摘要：

  DOI：

  10.1016/s0040-4039(01)91128-1

文献信息

• Yttrium-Catalyzed Regioselective α-C–H Silylation of Methyl Sulfides with Hydrosilanes
  作者：Yong Luo、Huai-Long Teng、Can Xue、Masayoshi Nishiura、Zhaomin Hou

  DOI：10.1021/acscatal.8b02405

  日期：2018.9.7

  The catalytic C–H silylation of sulfides with hydrosilanes is of much interest and importance but has remained unexplored to date. We report here the C–H silylation of methyl sulfides with hydrosilanes by an yttrium metallocene catalyst. The reaction took place regioselectively at the α-methyl C–H bond, affording the corresponding silylated sulfide derivatives that are difficult to make by other means

  硫化氢与氢硅烷的催化C–H甲硅烷基化是非常令人感兴趣和重要的，但迄今为止尚未开发。我们在这里报告了钇金属茂催化剂将甲基硫化物与氢硅烷的C–H甲硅烷基化反应。该反应在α-甲基CH键上进行区域选择性反应，得到相应的甲硅烷基化的硫化物衍生物，很难用其他方法制备。
• Biphenyl series—I
  作者：C. Dell'Erba、G. Garbarino、G. Guanti

  DOI：10.1016/s0040-4020(01)92402-0

  日期：——

  The synthesis of a range of 2′-, 3′- and 4′-substituted 3-nitro-4-bromobiphenyls and of their intermediates is described.

  描述了一系列2'-，3'-和4'-取代的3-硝基-4-溴代二苯及其中间体的合成。
• Pd‐Catalyzed Synthesis of Biphenyls with Methylthio Group
  作者：Zhiqiang Zhang、Zhizhi Hu、Zhixiao Yu、Haijun Chi、Peng Lei、Yue Wang、Ren He

  DOI：10.1080/00397910601131049

  日期：2007.3

  Abstract The synthesis of unsymmetrical biaryls with a methylthio group is achieved using the air‐stable palladium–phosphinous acid complexes, [(t‐Bu)2P(OH)]2 PdCl2 (POPd), as the catalyst. A great variety of substituted bromobenzenes having electron‐withdrawing and electron‐donating functional groups in para and meta positions have been successfully coupled with 3‐methylthiophenylboronic acid.

  摘要 使用空气稳定的钯-次膦酸络合物 [(t-Bu)2P(OH)]2 PdCl2 (POPd) 作为催化剂，合成了具有甲硫基的不对称联芳基化合物。多种在对位和间位具有吸电子和给电子官能团的取代溴苯已成功与 3-甲基硫代苯基硼酸偶联。
• [EN] NOVEL MICROBIOCIDAL DIOXIME ETHER DERIVATIVES<br/>[FR] NOUVEAUX DÉRIVÉS MICROBICIDES D'ÉTHER DE DIOXIME
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2012001040A1

  公开（公告）日：2012-01-05

  The present invention provides compounds of formula (I) wherein R1, A1, X, Y6, Y7, Y8, G1, G2, G3 and p are as defined in the claims. The invention further provides intermediates used in the preparation of these compounds, to compositions which comprise these compounds and to their use in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.

  本发明提供了以下式（I）的化合物，其中R1、A1、X、Y6、Y7、Y8、G1、G2、G3和p如权利要求中所定义。本发明还提供了用于制备这些化合物的中间体，以及包含这些化合物的组合物，并将其用于农业或园艺中，以控制或预防植物受植物病原微生物，尤其是真菌的侵害。
• 3-ARYLPHENYL SULFIDE DERIVATIVE AND INSECTICIDE AND MITICIDE
  申请人：Toriyabe Keiji

  公开号：US20050107383A1

  公开（公告）日：2005-05-19

  3-Arylphenyl sulfide derivatives represented by general formula (I): (wherein R is a C 2 -C 6 alkyl group, a C 2 -C 6 alkenyl group, a C 2 -C 6 alkynyl group or the like, B 0 to B 2 and B 3 are hydrogen atoms, halogen atoms, cyano groups, C 1 -C 4 haloalkyl groups or the like, n is 0, 1 or 2, and Ar is a phenyl ring, a pyridine ring, a thiophene ring, a pyrazole ring or the like), and insecticides and miticides containing the 3-arylphenyl sulfide derivatives as an active ingredient.

  一般式（I）所代表的3-芳基苯基硫醚衍生物：（其中R是C2-C6烷基，C2-C6烯基，C2-C6炔基或类似物，B0至B2和B3是氢原子，卤素原子，氰基，C1-C4卤代烷基或类似物，n为0、1或2，Ar为苯环，吡啶环，噻吩环，吡唑环或类似物），以及含有3-芳基苯基硫醚衍生物作为活性成分的杀虫剂和杀螨剂。