1,4-bis(4-phenoxy)benzenedicarboxylic acid | 13282-09-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(4-phenoxy)benzenedicarboxylic acid
• 英文别名: 1,4-Bis(4-carboxyphenoxy)benzene；4-[4-(4-carboxyphenoxy)phenoxy]benzoic acid
• CAS: 13282-09-2
• 化学式: C₂₀H₁₄O₆
• 分子量: 350.328
• InChiKey: QVLMBWTVLGOLHI-UHFFFAOYSA-N

物化性质

• 沸点：
  554.6±45.0 °C(Predicted)
• 密度：
  1.370±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.1
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  cobalt(II) nitrate hexahydrate 、 1,4-bis(4-phenoxy)benzenedicarboxylic acid 在 sodium hydroxide 作用下， 反应 72.0h， 以49%的产率得到[Co(1,4-bis(4-oxy-1-benzenecarboxylato)benzene)(H₂O)₂]
  参考文献：
  名称：

  基于长半刚性二羧酸配体的七种过渡金属配位聚合物的合成，结构和性能†

  摘要：

  在水热条件下已合成了与长二羧酸配体缔合的七种过渡金属配位聚合物，即[ZnL（H 2 O）] n（1），[CdL（H 2 O）2 ] n（2），[CoL （H 2 O）2 ] n（3），[MnL（phen）（H 2 O）] n（4），{[NiL（phen）]·H 2 O} n（5），[CuL（bpp）0.5 ] n（6a，6b），（H 2L ＝ 1，4-双（4-氧-1-苯羧酸）苯，phen ＝ 1，10-菲咯啉，bpp ＝ 1，2-二（4-吡啶基）乙烷。化合物1-6已通过元素分析，红外光谱，TGA，粉末X射线衍射（PXRD）和单晶X射线晶体学进行了表征。化合物1显示起伏的2D分层结构。同构2和3展示了包含一维通道的三维框架结构。化合物4和5具有相似的一维波状链结构。化合物6a和6b是四重互穿的三维超分子异构体，这是一个值得注意的事实，即H的半刚性2 L配体带来了6a和6b的多样化结构。的固态发光1级2的性能和磁性3进行了研究。

  DOI：

  10.1039/c5ra06012e

文献信息

• Three coordination polymers as a multi-responsive luminescent probe for the detection of Fe3+, Cr2O72− and antibiotic in aqueous media
  作者：Ji Ding、Ning Li、Dan-Lin Sun、Yue Zhu、Wei-Wei Cheng、Xuan-Rong Chen、Yun-Shan Xue

  DOI：10.1016/j.poly.2021.115575

  日期：2022.1

  transitions. Benefiting from its chemical stability and luminescent properties, compound 2 possesses multi-functional fluorescent responses toward the Fe3+ ion, the Cr2O72- ion and the NZF antibiotic in aqueous medium. The KSV values of compound 2 are 4.68 × 104 M-1 for the Fe3+ ion, 7.23 × 104 M-1 for the Cr2O72- anion, and 1.03 × 104 M-1 for the NZF antibiotic. Additionally, the possible mechanism for the

  三种配位聚合物（CPs），即[Co(L)(dpa)]·H 2 O} n ( 1 ), [Zn(L) 2 (dpb)]} n ( 2 ) 和[Zn(L) )(dpe)]} n ( 3 )，已通过半刚性二羧酸（H 2 L = 1,4-双（4-苯氧基）苯二羧酸）的双配体策略在不同的帮助下组装N-供体共配体 (dpa = di(pyridin-4-yl)amine, dpb = 1,4-di(pyridin-4-yl)benzo), dpe = trans-1,2-di(4-pyridyl)乙烯）。单晶 X 射线衍射分析表明化合物1是一个 4 倍互穿的二维sql网络和化合物2是一个2-fold互穿的2D sql网络，虽然最终的结构因层间堆叠方式不同而有所不同。化合物3是包含八面体笼的 8 倍互穿 3D直径框架。光致发光研究表明，化合物2和3表现出源自配体内电荷转移跃迁的强荧光。得益于其化学稳定性和发光特性，化合物2对水性介质中的
• Syntheses, crystal structures and properties of two coordination polymers derived from flexible dicarboxylate and N-donor ligands
  作者：Jianquan Hong、Lianguang Huo、Yazhao Wang、Ruixue Long、Changge Zheng

  DOI：10.1016/j.ica.2016.10.016

  日期：2017.1

  Abstract Two coordination polymers, namely [Zn3(PBDC)3(4,4′-bipy)]n (1) and [Co(PBDC)(4,4′-bipy)0.5]n (2) have been prepared via hydrothermal reactions of metal(II) nitrates with 1,4-bis(4-phenoxy)benzenedicarboxylic acid (H2PBDC) and 4,4′-bipyridine. Both complexes were characterized by elemental analyses, FT-IR, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction

  摘要通过水热法制备了两种配位聚合物[Zn3（PBDC）3（4,4'-bipy）] n（1）和[Co（PBDC）（4,4'-bipy）0.5] n（2）。硝酸金属（II）与1,4-双（4-苯氧基）苯二甲酸（H2PBDC）和4,4'-联吡啶的反应。两种配合物均通过元素分析，FT-IR，热重分析（TGA），粉末X射线衍射和单晶X射线衍射进行表征。结构分析表明，复合物1具有（3,4,6）连接的3D拓扑，其点符号为4·92} 2 42·68·8·92·102} 95·10}，而复合物2具有点符号为412·63}的3D 4倍互穿框架。另外，还研究了配合物1的发光性质和配合物2的磁性。
• Fluorine-Containing Polymerizable Monomer And Polymer Compound Using Same
  申请人：Central Glass Company, Limited

  公开号：US20140148548A1

  公开（公告）日：2014-05-29

  The present invention provides a fluorine-containing fluorenediamine of the formula (2): where R 1 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a C 1 -C 4 alkyl group, a C 1 -C 4 fluoroalkyl group in which any number of hydrogen atoms can be substituted by a fluorine atom, a phenyl group, a methoxy group and a nitro group; R 2 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a phenyl group, a naphthyl group, a biphenyl group, a sulfonic acid group, a —C≡C—C(CH 3 ) 2 OH group, a —C≡C—C 6 H 5 group and a —C≡C—Si(CH 3 ) 3 group; HFIP represents a —C(CF 3 ) 2 OH group; and m and n each independently represent an integer of 0 to 2 and satisfy a condition of 1≦m+n≦4.

  本发明提供了一种具有如下公式（2）的含氟芴二胺：其中R1代表从氢原子、氟原子、氯原子、溴原子、C1-C4烷基、C1-C4氟烷基（其中任意数量的氢原子可被氟原子取代）、苯基、甲氧基和硝基等组成的一种取代基；R2代表从氢原子、氟原子、氯原子、溴原子、碘原子、苯基、萘基、联苯基、磺酸基、—C≡C—C(CH3)2OH基、—C≡C—C6H5基和—C≡C—Si(CH3)3基等组成的一种取代基；HFIP代表—C(CF3)2OH基；m和n分别独立地表示0到2的整数，并满足1≦m+n≦4的条件。
• NOVEL COMPOUND, POLYIMIDE RESIN AND METHOD OF PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITION, PATTERNING METHOD AND METHOD OF FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC COMPONENT
  申请人：International Business Machines Corporation

  公开号：US20210317270A1

  公开（公告）日：2021-10-14

  Provided is a compound that can be used as a base resin for a photosensitive resin composition. The photosensitive resin can form a fine pattern and can achieve high resolution without impairing mechanical strength and solubility. The compound is represented by the general formula (1): wherein Z represents a linear, branched or cyclic divalent hydrocarbon group having 2 to 30 carbon atoms; X 1 to X 3 represent any of —CO 2 —, —CONR X1 —, —O—, —NR X1 —, —S—, —SO 2 —, —SO 3 — and —SO 2 NR X1 — and may be the same as or different from each other, provided that R X1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 30 carbon atoms; Ar represents a divalent aromatic group having 2 to 30 carbon atoms; L 1 and L 2 independently represent a divalent hydrocarbon group having 1 to 30 carbon atoms; and x and y are each independently 0 or 1.

  提供的是一种可以用作光敏树脂组合物的基树脂的化合物。这种光敏树脂可以形成精细图案，并且可以在不影响机械强度和溶解性的情况下实现高分辨率。该化合物由通式（1）表示：其中Z代表具有2到30个碳原子的线性、支链或环状二价碳氢基团；X1到X3代表任何一种—CO2—、—CONRX1—、—O—、—NRX1—、—S—、—SO2—、—SO3—和—SO2NRX1—中的一种，并且它们可以相同也可以不同，只要RX1是氢原子或具有1到30个碳原子的一价碳氢基团；Ar代表具有2到30个碳原子的二价芳香基团；L1和L2分别代表具有1到30个碳原子的二价碳氢基团；x和y分别独立地为0或1。
• Compound, Photopolymerization Initiator Containing Said Compound, and Photosensitive Resin Composition Containing Said Photopolymerization Initiator
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：US20200392079A1

  公开（公告）日：2020-12-17

  This compound which has excellent solvent solubility and compatibility with a resin, and which can generate bases and radicals with high efficiency by being irradiated with active energy rays, is represented by formula (1), where, in formula (1), R 1 , R 2 , R 3 , R 5 and R 6 represent a hydroxy group or an alkoxy group; the R 4 's independently represent an organic group containing a thioether bond; R 7 and R 9 independently represent a hydrogen atom or an alkyl group with 1 to 4 carbons; R 8 represents an alkylene group or an arylene group; and X represents an oxygen atom or a sulfur atom. A photopolymerization initiator can include said novel compound; and a photosensitive resin composition can include said photopolymerization initiator, from which a cured product can be obtained that has high sensitivity and no metal corrosion.

  这种化合物具有优异的溶剂溶解性和与树脂的兼容性，可以通过受到活性能量辐射而高效地产生碱基和自由基。该化合物由公式（1）表示，其中在公式（1）中，R1、R2、R3、R5和R6代表羟基或烷氧基；R4分别表示含硫醚键的有机基团；R7和R9分别代表氢原子或1至4个碳的烷基基团；R8代表烷基或芳基；X代表氧原子或硫原子。一种光聚合引发剂可以包括上述新化合物；一种光敏树脂组合物可以包括上述光聚合引发剂，从中可以得到高灵敏度且无金属腐蚀的固化产物。