| 353291-80-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 353291-80-2
• 化学式: C₁₆H₂₈FeN₈O₇Pr
• 分子量: 641.202
• InChiKey: YZJIYXCRINDMDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  praseodymium(III) nitrate hexahydrate 、 盐酸甜菜碱 、 potassium hexacyanoferrate(III) 以 水 为溶剂， 生成
  参考文献：
  名称：

  Novel one-dimensional cyano-bridged chain complexes [Ln(bet)2(H2O)3Fe(CN)6]n (Ln=Nd, Pr, Sm, Gd; bet=betaine): synthesis, crystal structure and magnetochemistry

  摘要：

  Using betaine ((CH3)(3)N+CH3CO2-) as the hybrid ligand, some novel isomorphous cyano-bridged complexes [Ln(bet)(2)(H2O)(3)Fe(CN)(6)](n) (Ln = Pr, Sm, Eu, Gd, Tb, Dy; bet = betaine) (abbreviated as LnFe) have been synthesized, which possess a chain structure through two approximately parallel trans-cyano-bridges between Pr (and Gd) and Fe atoms and C-N . . .H-O hydrogen bonding. Variable temperature susceptibilities show that there exist weak antiferromagnetic interactions between rare earth ions (Pr, Nd, Sm, Gd) and the Fe atom mainly through CN bridges. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00725-2