3-tert-butylphenyl mesylate | 1071592-74-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-tert-butylphenyl mesylate
• 英文别名: 3-tert-butylphenyl methanesulfonate；(3-tert-butylphenyl) methanesulfonate
• CAS: 1071592-74-9
• 化学式: C₁₁H₁₆O₃S
• 分子量: 228.312
• InChiKey: MRQSRAVLXYHTKY-UHFFFAOYSA-N

物化性质

• 沸点：
  327.3±25.0 °C(Predicted)
• 密度：
  1.134±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,3-二氢呋喃 、 3-tert-butylphenyl mesylate 在 C₁₈H₂₈Cl₂N₂NiP₂ 、 锌 作用下， 以 二甲基亚砜 为溶剂， 反应 48.0h， 以68%的产率得到(R)-2-(3-t-butylphenyl)-2,3-dihydrofuran
  参考文献：
  名称：

  镍催化的芳基三氟甲磺酸酯，甲磺酸酯和甲苯磺酸酯的对映选择性分子间Heck和还原Heck反应

  摘要：

  镍催化的环烯烃的分子间Heck反应与芳基三氟甲磺酸酯，甲磺酸酯和甲苯磺酸酯的对映体比率极好。不对称的还原性Heck反应也适用于2-环戊烯酮缩酮，这相当于烯酮本身的共轭芳基化。

  DOI：

  10.1002/anie.202011036
• 作为产物：
  描述：

  3-叔丁基苯酚 、 甲基磺酰氯 在 三乙胺 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以88%的产率得到3-tert-butylphenyl mesylate
  参考文献：
  名称：

  EP2133327

  摘要：

  公开号：

文献信息

• [EN] INHIBITORS OF HEPATITIS C VIRUS RNA-DEPENDENT RNA POLYMERASE, AND COMPOSITIONS AND TREATMENTS USING THE SAME<br/>[FR] INHIBITEURS DE L'ARN POLYMERASE ARN-DEPENDANTE DU VIRUS DE L'HEPATITE C ET COMPOSITIONS ET TRAITEMENTS UTILISANT CETTE POLYMERASE
  申请人：PFIZER

  公开号：WO2003095441A1

  公开（公告）日：2003-11-20

  Compounds of formula (I) are hepatitis C virus (HCV) RNA-dependent RNA polymerase (RdRp) inhibitors, and are useful in therapeutic and prophylactic treatment of persons infected with hepatitis C virus.

  化合物的化学式（I）是丙型肝炎病毒（HCV）RNA依赖性RNA聚合酶（RdRp）抑制剂，对感染丙型肝炎病毒的人进行治疗和预防性治疗具有用处。
• Oxadiazole Derivative as Dgat Inhibitors
  申请人：Birch Martin Alan

  公开号：US20080096874A1

  公开（公告）日：2008-04-24

  Compounds of formula (I), and salts and pro-drugs thereof: Formula (I) wherein for example R 1 is optionally substituted aryl or heteroaryl; Y is a linking group selected from, for example, a direct bond, and a (substituted) alkyl chain; R 2 is an optionally substituted aryl, an optionally substituted cycloalkyl or an optionally substituted heterocyclic group; are described. Processes to make such compounds and their use as DGAT inhibitors, for example in the treatment of obesity, are also described.

  式（I）的化合物，以及其盐和前药：其中，例如R1是可选取代芳基或杂环芳基；Y是选择自直接键和（取代）烷基链等的连接基；R2是可选取代芳基、可选取代环烷基或可选取代杂环基团。还描述了制备此类化合物的方法及其作为DGAT抑制剂的用途，例如在肥胖症的治疗中。
• tert-BUTYLPHENYL SULFONATE COMPOUND, NONAQUEOUS ELECTROLYTE SOLUTION FOR LITHIUM SECONDARY BATTERY USING THE SAME, AND LITHIUM SECONDARY BATTERY USING THE SAME
  申请人：Abe Koji

  公开号：US20100055576A1

  公开（公告）日：2010-03-04

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  所披露的主题涉及一种二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，作为制药、农业化学品、电子材料或聚合物材料等的中间原料，或作为电池材料，并且提供了一种非水电解质溶液，通过使用它具有卓越的循环性能和其他电池性能的锂二次电池，以及一种锂二次电池。所披露的实施例还涉及一种用作锂二次电池中的非水电解质溶液，其中电解质盐溶解在非水溶剂中，0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，并且涉及一种锂二次电池和一种化合物。
• TERT-BUTYLPHENYL SULFONATE COMPOUND, NONAQUEOUS ELECTROLYTE SOLUTION FOR LITHIUM SECONDARY BATTERY USING THE SAME, AND LITHIUM SECONDARY BATTERY USING THE SAME
  申请人：UBE INDUSTRIES, LTD.

  公开号：US20140011097A1

  公开（公告）日：2014-01-09

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tertbutylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tertbutylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, ditert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  公开的主题涉及一种二叔丁基苯基烷基磺酸酯化合物，叔丁基苯基烷基磺酸酯化合物，二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，可用作制药、农业化学品、电子材料或聚合物材料等的中间原料，或作为电池材料，并且通过使用它们提供了一种具有优异循环性能和其他电池性能的锂二次电池的非水电解质溶液，以及锂二次电池。所公开的实施例还涉及用作锂二次电池中的非水电解质溶液的一种非水电解质溶液，其中在非水溶剂中溶解电解质盐，含有0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物，叔丁基苯基烷基磺酸酯化合物，二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，以及锂二次电池和化合物。
• Tert-butylphenyl sulfonate compound, nonaqueous electrolyte solution for lithium secondary battery using the same, and lithium secondary battery using the same
  申请人：Abe Koji

  公开号：US08546599B2

  公开（公告）日：2013-10-01

  The disclosed subject matter relate to a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound useful as an intermediate raw material of a pharmaceutical, agricultural chemical, electronic material or polymer material and the like, or as a battery material, and also provides a nonaqueous electrolytic solution for a lithium secondary battery having superior cycle performance and other battery properties through the use thereof, and a lithium secondary battery. The disclosed embodiments further relate to a nonaqueous electrolytic solution for use as in a lithium secondary battery containing, in a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, 0.01 to 10% by weight of a di-tert-butylphenyl alkylsulfonate compound, tert-butylphenyl alkylsulfonate compound, di-tert-butylphenyl arylsulfonate compound or tert-butylphenyl arylsulfonate compound, and to a lithium secondary battery and a compound.

  公开的主题涉及一种二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，可用作制药、农药、电子材料或聚合物材料等中间原料，或用作电池材料，并且通过使用它们提供了一种具有优异循环性能和其他电池性能的锂二次电池的非水电解质溶液，以及一种锂二次电池。公开实施例进一步涉及一种非水电解质溶液，用于锂二次电池中，其中在非水电解质溶液中溶解了电解质盐的非水溶剂中含有0.01至10重量％的二叔丁基苯基烷基磺酸酯化合物、叔丁基苯基烷基磺酸酯化合物、二叔丁基苯基芳基磺酸酯化合物或叔丁基苯基芳基磺酸酯化合物，以及一种锂二次电池和化合物。