1,3,5-triphenyl-1,3,5-diazaphosphorinane | 72897-05-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3,5-triphenyl-1,3,5-diazaphosphorinane
• 英文别名: 1,3,5-triphenyl-1,3,5-dioxaphosphorinane；1,3,5-triphenyl-[1,3,5]diazaphosphinane；1,3,5-Triphenyl-1,3,5-diazaphosphorinan；1,3,5-Triphenyl-1,3,5-diazaphosphinane
• CAS: 72897-05-3
• 化学式: C₂₁H₂₁N₂P
• 分子量: 332.385
• InChiKey: FAPRNLDOPGDKHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3,5-triphenyl-1,3,5-diazaphosphorinane 在 溶剂黄146 、 diborane(6) 作用下， 生成 1,3,5,7-tetraphenyl-1,5-diaza-3,7-diphosphacyclooctane
  参考文献：
  名称：

  Reaction of 1,3,5-diazaphosphorinanes with borane

  摘要：

  DOI：

  10.1007/bf00957164
• 作为产物：
  描述：

  双(羟甲基)苯膦 以 甲醇 为溶剂， 反应 3.0h， 生成 1,3,5-triphenyl-1,3,5-diazaphosphorinane
  参考文献：
  名称：

  1.2-二氮杂-4-磷酸-环戊烷-1.5-二氮杂-3.7-二磷酸双环-[3.3.0]辛烷N.N'-[双膦基亚甲基] -N.N'-二甲基肼1.3-二氮杂-5-磷酸-环己烷

  摘要：

  NN'-二烷基肼和肼本身与羟甲基膦反应生成标题化合物，双（苯胺基亚甲基）膦与甲醛形成环己烷衍生物。

  DOI：

  10.1016/0040-4039(81)80062-7

文献信息

• Complexes of cyclic aminomethylphosphines with Pt(II), Pd(II), Cu(I), and Ag(I) salts
  作者：B. A. Arbuzov、A. A. Karasik、G. N. Nikonov、E. V. Malova、R. Sh. Khadiullin、A. Kh. Plyamovatyi、K. M. Enikeev

  DOI：10.1007/bf00869510

  日期：1992.2

  1,3,5-Diazaphosphorinanes and 1,5,3,7-diazadiphosphacyclooctanes form complexes with Pt(II), Pd(II), Cu(I), and Ag(I) salts. Platinum and palladium are coordinated through phosphorous atoms. In the case of 1,3-diphenyl-5-p-toluidenomethyl-1,3,5-diazaphosphorinane complex formation with platinum and palladium is accompanied by formation of a new polydentate ligand, p-tolylbis-(1,3-di-p-tolyl-1,3,5-diazaphosphorinane-5-yl)methylamine, where the metal is also bonded to phosphorus atoms.
• Karasik; Bobrov; Nikonov, Russian Journal of Coordination Chemistry, 1996, vol. 22, # 1, p. 35 - 41
  作者：Karasik、Bobrov、Nikonov、Litvinov、Dokuchaev

  DOI：——

  日期：——
• Synthesis and properties of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane
  作者：G. N. Nikonov、A. A. Karasik、B. A. Arbuzov

  DOI：10.1007/bf00866594

  日期：1992.6

  The reaction of bis(hydroxymethyl)phenylphosphine with isobutyl diphenylborate in the presence of triethylamine leads to the formation of triethylammonium 2,2,5-triphenyl-1,3,2,5-dioxaborataphosphorinane (1). The reaction of compound 1 with electrophilic reagents (O, S, Se, CH2O, RHal) leads to quaternization of the phosphorus atom, giving the corresponding phosphine oxides, sulfides, and selenides and PB-containing betaines. In the reactions of compound 1 with amines aminoniethylphosphines of the diazaphosphorinane and diazadiphosphacyclooctane series are formed. Ammonium 1,3,2,5-dioxaborataphosphorinanes dissociate in solutions and enter into ion exchange with phosphonium iodides, leading to phosphonium 1,3,2,5-dioxaborataphosphorinanes. The latter. in the case of the aminomethylphosphonium cation, undergo intramolecular rearrangement with the formation of PB-containing betaines and aminomethylphosphines.
• Complexes of 2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane and 1,3,5-triphenyl-1,3,5-diazaphosphorinane with molybdenum hexacarbonyl
  作者：A. A. Karasik、G. N. Nikonov、R. Z. Musin、Yu. Ya. Efremov

  DOI：10.1007/bf00863937

  日期：1992.1

  The reaction of 2,5-diphenyl-1,3,2,5-dioxaboraphosphorinane (L) and 1,3,5-triphenyl-1,3,5-diazaphosphorinane (L') with molybdenum hexacarbonyl gave, respectively, Mo(CO)4L2 and Mo(CO)5L' complexes.
• Orientation of phenyl group attached to phosphorus atom in 5-phenyl-1,3-di-R-1,3,5-diazaphosphorinanes
  作者：B. A. Arbuzov、O. A. Erastov、G. N. Nikonov、T. A. Zyablikova、R. P. Arshinova、R. A. Kadyrov

  DOI：10.1007/bf00949165

  日期：1980.7