Zinn-tetra-p-benzaldehyd-aethylenacetal | 106218-21-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: Zinn-tetra-p-benzaldehyd-aethylenacetal
• CAS: 106218-21-7
• 化学式: C₃₆H₃₆O₈Sn
• 分子量: 715.387
• InChiKey: MWXCVRPHKBDLFQ-UHFFFAOYSA-N

物化性质

• 沸点：
  740.8±70.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.48
• 重原子数：
  45
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  Zinn-tetra-p-benzaldehyd-aethylenacetal 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.6, page 169 - 176

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(4-溴苯基)-1,3-二氧戊环 、 四氯化锡 在 碘 、 magnesium 作用下， 以 四氢呋喃 、 苯 为溶剂， 以60%的产率得到Zinn-tetra-p-benzaldehyd-aethylenacetal
  参考文献：
  名称：

  Functionalised tetraarylstannanes Sn[C6H4-R]4 (R=–CH(CH2O)2, –CHO, –COOH, –CHN–NH–C6H3-2,4-(NO2)2, –CH2OH, –CO–NH–CH2–COO–CH3, –CH[N(C2H4)2O]2)

  摘要：

  Reaction of tin tetrachloride with the appropriate Grignard reagent gave Sn[C6H4-CH(OCH2)(2)](4) (2), which was transformed to Sn[C6H4-CHO](4) (3) and its hydrazido and amino derivatives Sn[C6H4-CH=N-NH-C6H3-2,4-(NO2)(2)](4) (5) and Sn{C6H4-CH[N(C2H4)(2)O](2)}(4) (8). Oxidation of (3) produced Sn[C6H4-COOH](4) (4) while reduction of (3) gave Sn[C6H4-CH2-OH](4) (6). From the acid 4, an amino acid Sn[C6H4-CO-NH-CH2-CO-OCH3](4) (7) could be obtained by reaction with the methyl ester of glycine. All compounds were isolated in pure form with yields of 40-64% and were characterised by spectroscopic means (heteronuclear NMR) or by X-ray structure determination (3). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.02.012

文献信息

• Drefahl, G.; Lorenz, D., Journal fur praktische Chemie (Leipzig 1954), 1964, vol. 24, p. 106 - 111
  作者：Drefahl, G.、Lorenz, D.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.6, page 169 - 176
  作者：

  DOI：——

  日期：——
• Functionalised tetraarylstannanes Sn[C6H4-R]4 (R=–CH(CH2O)2, –CHO, –COOH, –CHN–NH–C6H3-2,4-(NO2)2, –CH2OH, –CO–NH–CH2–COO–CH3, –CH[N(C2H4)2O]2)
  作者：Michael Veith、Andreas Rammo、Christian Kirsch,、Lucie Khemtémourian、Dominique Agustin

  DOI：10.1016/j.jorganchem.2004.02.012

  日期：2004.5

  Reaction of tin tetrachloride with the appropriate Grignard reagent gave Sn[C6H4-CH(OCH2)(2)](4) (2), which was transformed to Sn[C6H4-CHO](4) (3) and its hydrazido and amino derivatives Sn[C6H4-CH=N-NH-C6H3-2,4-(NO2)(2)](4) (5) and SnC6H4-CH[N(C2H4)(2)O](2)}(4) (8). Oxidation of (3) produced Sn[C6H4-COOH](4) (4) while reduction of (3) gave Sn[C6H4-CH2-OH](4) (6). From the acid 4, an amino acid Sn[C6H4-CO-NH-CH2-CO-OCH3](4) (7) could be obtained by reaction with the methyl ester of glycine. All compounds were isolated in pure form with yields of 40-64% and were characterised by spectroscopic means (heteronuclear NMR) or by X-ray structure determination (3). (C) 2004 Elsevier B.V. All rights reserved.