N,N'-二(1-萘)-N-苯基-4,4'联苯二胺 | 352359-43-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N'-二(1-萘)-N-苯基-4,4'联苯二胺
• 英文名称: N-phenyl-N,N'-di(1-naphthyl)benzidine
• 英文别名: 4-(N-phenyl-N-1-naphthylamino)-biphenyl-N'-naphthylamine；4-(N-phenyl-N-naphthylamino)-biphenyl-N'-naphthylamine；N4,N4'-Di(naphthalen-1-yl)-N4-phenyl-[1,1'-biphenyl]-4,4'-diamine；N-[4-[4-(N-naphthalen-1-ylanilino)phenyl]phenyl]naphthalen-1-amine
• CAS: 352359-43-4
• 化学式: C₃₈H₂₈N₂
• 分子量: 512.654
• InChiKey: ZBPZUTPSQSBTPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.8
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N'-二(1-萘)-N-苯基-4,4'联苯二胺 在 tris(dibenzylideneacetone)dipalladium (0) 三叔丁基膦 、 四丁基氟化铵 、 氢化钾 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 水 、 甲苯 为溶剂， 反应 30.0h， 生成 N,N'-di(1-naphthyl)-N-phenyl-N'-(4-((4-vinylphenyl)methoxymethyl)phenyl)benzidine
  参考文献：
  名称：

  Synthesis and Characterization of Photo-Cross-Linkable Hole-Conducting Polymers

  摘要：

  The synthesis and characterization of side-chain polymers functionalized with hole-transporting units and photo-cross-linkable groups, which can be used for solution-based preparation of multilayer organic light-emitting devices (OLEDs), are discussed. The concept deals with triarylamine and oxetane-functionalized styrenes, which are copolymerized by radical polymerization. Four different types of hole-transporting monomers were combined with one cross-linkable monomer in two different ratios, yielding two groups of each four polymers (P1A...P4A and P1B...P4B). The polymers were investigated by NMR spectroscopy, molecular weights were determined by GPC with light scattering, and the thermal properties were measured with differential scanning calorimetry (DSC). Optical characterization by UV-vis and fluorescence spectroscopy was performed. Electrochemical and cross-linking characteristics of the copolymers were investigated to proove this strategy's potential in application for modern multilayer polymer OLEDs. Finally, hole-only devices were prepared for evaluation of the semiconductive performance of the materials.

  DOI：

  10.1021/ma048365h
• 作为产物：
  描述：

  N-苯基-1-萘胺 在 tris(dibenzylideneacetone)dipalladium (0) 1,1'-双(二苯基膦)二茂铁 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 13.0h， 生成 N,N'-二(1-萘)-N-苯基-4,4'联苯二胺
  参考文献：
  名称：

  Synthesis and Characterization of Photo-Cross-Linkable Hole-Conducting Polymers

  摘要：

  The synthesis and characterization of side-chain polymers functionalized with hole-transporting units and photo-cross-linkable groups, which can be used for solution-based preparation of multilayer organic light-emitting devices (OLEDs), are discussed. The concept deals with triarylamine and oxetane-functionalized styrenes, which are copolymerized by radical polymerization. Four different types of hole-transporting monomers were combined with one cross-linkable monomer in two different ratios, yielding two groups of each four polymers (P1A...P4A and P1B...P4B). The polymers were investigated by NMR spectroscopy, molecular weights were determined by GPC with light scattering, and the thermal properties were measured with differential scanning calorimetry (DSC). Optical characterization by UV-vis and fluorescence spectroscopy was performed. Electrochemical and cross-linking characteristics of the copolymers were investigated to proove this strategy's potential in application for modern multilayer polymer OLEDs. Finally, hole-only devices were prepared for evaluation of the semiconductive performance of the materials.

  DOI：

  10.1021/ma048365h

文献信息

• COMPOUNDS AND ORGANIC LIGHT EMITTING DIODE USING THE SAME
  申请人：Jeon Byung-Sun

  公开号：US20100065827A1

  公开（公告）日：2010-03-18

  Disclosed are new compounds and an organic light emitting diode using the same. The organic light emitting diode using the new compound according to the present invention exhibits excellent characteristics in terms of actuating voltage, light efficiency, and lifespan.

  本发明公开了新化合物及其所使用的有机发光二极管。根据本发明所使用的新化合物的有机发光二极管在驱动电压、光效率和寿命方面表现出优异的特性。
• [EN] 2,2'-BIBENZO[D]IMIDAZOLIDENE COMPOUND HAVING HETEROMONOCYCLIC GROUPS AT THE 1-, 1'-, 3- AND 3'-POSITIONS, AND ORGANIC LIGHT-EMITTING ELEMENT AND DISPLAY DEVICE CONTAINING THE SAME<br/>[FR] COMPOSÉ DE 2,2'-BIBENZO[D]IMIDAZOLIDÈNE AYANT DES GROUPES HÉTÉROMONOCYCLIQUES AU NIVEAU DES POSITIONS 1, 1', 3 ET 3', ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF D'AFFICHAGE LE CONTENANT
  申请人：CANON KK

  公开号：WO2016174813A1

  公开（公告）日：2016-11-03

  The present invention provides a 2,2'-bibenzo[d]imidazolidene compound expressed by the following general formula (1). In general formula (1), Ar1 to Ar4 each represent a substituted or unsubstituted heteromonocyclic group. R1 to R8 each represent a hydrogen atom or a substituent.

  本发明提供了一种由下列一般式（1）表示的2,2'-bibenzo[d]imidazolidene化合物。在一般式（1）中，Ar1到Ar4分别表示取代或未取代的杂环单环基团。R1到R8分别表示氢原子或取代基。
• [EN] 2,2'-BIBENZO[D]IMIDAZOLIDENE COMPOUND HAVING CONDENSED RINGS AT THE 1-, 1'-, 3- AND 3'-POSITIONS, AND ORGANIC LIGHT-EMITTING ELEMENT, DISPLAY DEVICE, IMAGE INFORMATION PROCESSING APPARATUS, LIGHTING DEVICE, IMAGE FORMING APPARATUS AND EXPOSURE UNIT, EACH CONTAINING THE SAME<br/>[FR] COMPOSÉ 2,2'-BIBENZO[D]IMIDAZOLIDÈNE AYANT DES CYCLES CONDENSÉS AUX POSITIONS 1, 1', 3 ET 3' ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE, DISPOSITIF D'AFFICHAGE, APPAREIL DE TRAITEMENT D'INFORMATIONS IMAGES, DISPOSITIF D'ÉCLAIRAGE, APPAREIL DE FORMATION D'IMAGES ET UNITÉ D'EXPOSITION, CHACUN LE CONTENANT
  申请人：CANON KK

  公开号：WO2016084303A1

  公开（公告）日：2016-06-02

  A stable 2,2'-bibenzo[d]imidazolidene compound is provided. The 2,2'-bibenzo[d]imidazolidene compound is expressed by the following General Formula (1). In General Formula (1), Ar1 to Ar8 each represent a substituted or unsubstituted condensed ring. R1 to R8 each represent a hydrogen atom or a substituent.

  提供了一种稳定的2,2'-联苯[d]咪唑烷化合物。该2,2'-联苯[d]咪唑烷化合物由以下通式（1）表示。在通式（1）中，Ar1到Ar8分别表示取代或未取代的缩合环。R1到R8分别表示氢原子或取代基。
• Heterocyclic compound and organic light emitting element comprising same
  申请人：LG Chem, Ltd.

  公开号：US10800969B2

  公开（公告）日：2020-10-13

  The present specification relates to a hetero-cyclic compound and an organic light emitting device including the same.

  本说明书涉及一种杂环化合物和包括其在内的有机发光器件。
• Organic electroluminescent element material, organic electroluminescent element and production method for organic electroluminescent element
  申请人：Yonekuta Yasunori

  公开号：US10840461B2

  公开（公告）日：2020-11-17

  Provided is an organic electroluminescence device material, which, in its production, is free from formation of impurities that worsen the performance of organic EL devices, which, in forming an upper layer by coating, does not cause dissolution mixing or swelling mixing, which forms a film of good quality and which contributes toward improving the performance (high durability, and low driving voltage) of organic EL devices. The organic electroluminescence device material is a siloxane compound having a recurring unit represented by the following general formula (1):

  本发明提供了一种有机电致发光器件材料，该材料在生产过程中不会形成使有机电致发光器件性能恶化的杂质，在通过涂层形成上层时不会引起溶解混合或膨胀混合，可形成质量良好的薄膜，有助于提高有机电致发光器件的性能（高耐用性和低驱动电压）。有机电致发光器件材料是一种硅氧烷化合物，其复性单元由以下通式（1）表示：