2,7-Dibromo-9-(4-methylphenyl)-9-naphthalen-1-ylfluorene | 357645-39-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,7-Dibromo-9-(4-methylphenyl)-9-naphthalen-1-ylfluorene
• 英文别名: 2,7-dibromo-9-(4-methylphenyl)-9-naphthalen-1-ylfluorene
• CAS: 357645-39-7
• 化学式: C₃₀H₂₀Br₂
• 分子量: 540.297
• InChiKey: SZFMAGDLLDIMSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  N-苯基-1-萘胺 、 2,7-Dibromo-9-(4-methylphenyl)-9-naphthalen-1-ylfluorene 在 palladium diacetate 、 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以92%的产率得到9-(4-methylphenyl)-2-N,7-N,9-trinaphthalen-1-yl-2-N,7-N-diphenylfluorene-2,7-diamine
  参考文献：
  名称：

  Synthesis and Properties of 9,9-Diarylfluorene-Based Triaryldiamines

  摘要：

  [GRAPHICS]9,9-Diaryl-2,7-dibromofluorene was synthesized by a triflic acid promoted Friedel-Crafts reaction. Introduction of diarylamino groups at its C2 and C7 positions by a Pd-catalyzed amination results in the formation of a novel class of triaryldiamines. The 9,9 diaryl substituents at the central linkage play a less important role in the photophyscial properties but affect the oxidation potential and improve the morphological stability of these new triarylamines.

  DOI：

  10.1021/ol016051y
• 作为产物：
  描述：

  2,7-二溴-9-芴酮 在 三氟甲磺酸 作用下， 以 乙醚 为溶剂， 反应 0.17h， 生成 2,7-Dibromo-9-(4-methylphenyl)-9-naphthalen-1-ylfluorene
  参考文献：
  名称：

  Synthesis and Properties of 9,9-Diarylfluorene-Based Triaryldiamines

  摘要：

  [GRAPHICS]9,9-Diaryl-2,7-dibromofluorene was synthesized by a triflic acid promoted Friedel-Crafts reaction. Introduction of diarylamino groups at its C2 and C7 positions by a Pd-catalyzed amination results in the formation of a novel class of triaryldiamines. The 9,9 diaryl substituents at the central linkage play a less important role in the photophyscial properties but affect the oxidation potential and improve the morphological stability of these new triarylamines.

  DOI：

  10.1021/ol016051y

文献信息

• Synthesis and Properties of 9,9-Diarylfluorene-Based Triaryldiamines
  作者：Ken-Tsung Wong、Zi-Jien Wang、Yuh-Yih Chien、Chien-Lung Wang

  DOI：10.1021/ol016051y

  日期：2001.7.1

  [GRAPHICS]9,9-Diaryl-2,7-dibromofluorene was synthesized by a triflic acid promoted Friedel-Crafts reaction. Introduction of diarylamino groups at its C2 and C7 positions by a Pd-catalyzed amination results in the formation of a novel class of triaryldiamines. The 9,9 diaryl substituents at the central linkage play a less important role in the photophyscial properties but affect the oxidation potential and improve the morphological stability of these new triarylamines.