4-[2-(2-hydroxybenzoyl)hydrazinyl]-4-oxobut-2-enoic acid | 1155353-57-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[2-(2-hydroxybenzoyl)hydrazinyl]-4-oxobut-2-enoic acid
• 英文别名: (E)-4-[2-(2-hydroxybenzoyl)hydrazinyl]-4-oxobut-2-enoic acid
• CAS: 1155353-57-3
• 化学式: C₁₁H₁₀N₂O₅
• 分子量: 250.211
• InChiKey: YFYDBSIHPGSBLF-AATRIKPKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  116
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-[2-(2-hydroxybenzoyl)hydrazinyl]-4-oxobut-2-enoic acid 、 二丁基二氯化锡 在 NaOEt 作用下， 以 乙醇 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  The first 1D tetranuclear organotin(IV) complex with N′-acylsalicylhydrazide: Synthesis, characterization and crystal structure

  摘要：

  The first diorganotin(IV) complex 1 with N'-acylsalicylhydrazide has been successfully synthesized and structurally characterized by elemental analysis, Fr-IR, NMR (H-1, C-13 and Sn-119) spectra and X-ray crystallography. The complex I is an infinite 1D polymer with tetranuclear organotin(IV) as secondary building units, which contains five- and seven-coordinated tin atoms. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.03.010

文献信息

• The first 1D tetranuclear organotin(IV) complex with N′-acylsalicylhydrazide: Synthesis, characterization and crystal structure
  作者：Handong Yin、Jichun Cui、Yanling Qiao

  DOI：10.1016/j.inoche.2008.03.010

  日期：2008.6

  The first diorganotin(IV) complex 1 with N'-acylsalicylhydrazide has been successfully synthesized and structurally characterized by elemental analysis, Fr-IR, NMR (H-1, C-13 and Sn-119) spectra and X-ray crystallography. The complex I is an infinite 1D polymer with tetranuclear organotin(IV) as secondary building units, which contains five- and seven-coordinated tin atoms. (C) 2008 Elsevier B.V. All rights reserved.