7-bromo-9,9-dimethyl-N-(naphthalen-1-yl)-N-phenyl-9H-fluoren-2-amine | 302579-20-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 7-bromo-9,9-dimethyl-N-(naphthalen-1-yl)-N-phenyl-9H-fluoren-2-amine
• 英文别名: 2-bromo-N-phenyl-N-(1'-naphthyl)-7-amino-9,9-dimethyl-9H-fluorene；7-bromo-9,9-dimethyl-N-(1-naphthyl)-N-phenyl-2-fluorenamine；7-bromo-9,9-dimethyl-N-naphthalen-1-yl-N-phenylfluoren-2-amine
• CAS: 302579-20-0
• 化学式: C₃₁H₂₄BrN
• 分子量: 490.442
• InChiKey: MJMFPEIQXSLDAI-UHFFFAOYSA-N

物化性质

• 沸点：
  627.7±48.0 °C(predicted)
• 密度：
  1.331±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-苯基-3-咔唑硼酸 、 7-bromo-9,9-dimethyl-N-(naphthalen-1-yl)-N-phenyl-9H-fluoren-2-amine 在 四(三苯基膦)钯 sodium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 4.0h， 生成 9,9-dimethyl-N-naphthalen-1-yl-N-phenyl-7-(9-phenylcarbazol-3-yl)fluoren-2-amine
  参考文献：
  名称：

  AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING THE SAME

  摘要：

  公开号：

  EP2085382B1
• 作为产物：
  描述：

  2-溴-7-碘-9,9-二甲基芴 、 N-苯基-1-萘胺 在 copper(l) iodide sodium t-butanolate 、 N,N'-二甲基乙二胺 作用下， 以 xylene 为溶剂， 反应 8.0h， 生成 7-bromo-9,9-dimethyl-N-(naphthalen-1-yl)-N-phenyl-9H-fluoren-2-amine
  参考文献：
  名称：

  AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT ELEMENT USING THE SAME

  摘要：

  公开号：

  EP2085382B1

文献信息

• Compound, organic electric element using the same, and an electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US10026905B2

  公开（公告）日：2018-07-17

  A compound represented by Formula 1. An organic electric element includes a first electrode, a second electrode, and an organic material layer including the compound of Formula 1. The organic material layer include a light emitting layer, a hole transport layer including a compound represented by Formula 2, and an emission-auxiliary layer including the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, color purity, and life span can be improved.

  由公式1表示的化合物。一种有机电元件包括第一电极、第二电极和包括公式1所表示的化合物的有机材料层。有机材料层包括发光层、包括公式2所表示的化合物的空穴传输层，以及包括公式1所表示的化合物的发射辅助层。当有机电元件包括有机材料层中的该化合物时，可以改善发光效率、色彩纯度和寿命。
• Aromatic amine derivative and organic electroluminescent element using the same
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2518045A1

  公开（公告）日：2012-10-31

  An aromatic amine derivative with a specific structure having a carbazole skeleton to which a diarylamino group bonds via a bonding group. An organic electroluminescence device which is composed of one or more organic thin film layers including at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the organic thin film layers contains the aromatic amine derivative singly or as its mixture component. Organic electroluminescence devices with enhanced efficiency of light emission and a compound realizing the devices are provided.

  一种具有特定结构的芳香胺衍生物，其骨架为咔唑，二芳基氨基通过键合基团与之键合。一种有机电致发光器件，它由一个或多个有机薄膜层组成，包括至少一个夹在阴极和阳极之间的发光层，其中至少一个有机薄膜层含有单个或作为其混合物成分的芳香族胺衍生物。提供了发光效率更高的有机电致发光器件和实现该器件的化合物。
• Organic compound and organic electroluminescent device comprising the same
  申请人：DOOSAN CORPORATION

  公开号：US10756277B2

  公开（公告）日：2020-08-25

  The present disclosure relates to a novel organic compound and an organic electroluminescent device comprising the same, and the organic compound of the present disclosure may be used for an organic material layer of the organic electroluminescent device, thereby improving the light emitting efficiency, driving voltage, lifetime, and the like of the organic electroluminescent device.

  本公开涉及一种新型有机化合物和包含该化合物的有机电致发光器件，本公开的有机化合物可用于有机电致发光器件的有机材料层，从而提高有机电致发光器件的发光效率、驱动电压、使用寿命等。
• Heterocyclic compound, organic light-emitting diode comprising the heterocyclic compound, and flat panel display device comprising the organic light-emitting diode
  申请人：Samsung Display Co., Ltd.

  公开号：EP2581365B1

  公开（公告）日：2019-10-16
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Mizuki Yumiko

  公开号：US20080124572A1

  公开（公告）日：2008-05-29

  An aromatic amine derivative with a specific structure having a carbazole skeleton to which a diarylamino group bonds via a bonding group. An organic electroluminescence device which is composed of one or more organic thin film layers including at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the organic thin film layers contains the aromatic amine derivative singly or as its mixture component. Organic electroluminescence devices with enhanced efficiency of light emission and a compound realizing the devices are provided.