8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-b]吲哚 | 1251503-35-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-b]吲哚
• 中文别名: 8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-B]吲哚
• 英文名称: 8-[2-(2-Pyridyl)phenyl]-5H-pyrido[3,2-b]indole
• 英文别名: 8-(2-pyridin-2-ylphenyl)-5H-pyrido[3,2-b]indole
• CAS: 1251503-35-1
• 化学式: C₂₂H₁₅N₃
• 分子量: 321.381
• InChiKey: ROQWGQBJRGUPAG-UHFFFAOYSA-N

物化性质

• 沸点：
  544.7±40.0 °C(Predicted)
• 密度：
  1.270±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.6
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 储存条件：
  室温

制备方法与用途

电池材料和离子液体

反应信息

• 作为反应物：
  描述：

  2,8 - 二溴二苯并呋喃 、 8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-b]吲哚 在 potassium phosphate 、 6-甲基-2-吡啶甲酸 、 copper(l) iodide 作用下， 以 二甲基亚砜 为溶剂， 反应 7.17h， 以71%的产率得到8-(2-Pyridin-2-ylphenyl)-5-[8-[8-(2-pyridin-2-ylphenyl)pyrido[3,2-b]indol-5-yl]dibenzofuran-2-yl]pyrido[3,2-b]indole
  参考文献：
  名称：

  Organic photoelectric conversion element and solar cell using the same

  摘要：

  本发明提供了一种具有简单制造工艺、高透明度、高光电转换效率和优异耐久性的透明导电膜，以及使用该透明导电膜的有机光电转换元件。本发明的透明导电膜是通过层叠含有氮含有机化合物的基层和含有周期表第11族金属元素的金属薄膜层形成的，金属薄膜层的厚度为2到10纳米。此外，本发明的有机光电转换元件具有第一电极、第二电极和位于第一电极和第二电极之间的光电转换层，有机光电转换元件的第一电极和第二电极中至少有一个是通过层叠含有氮含有机化合物的基层和含有周期表第11族金属元素的金属薄膜层形成的透明导电膜，金属薄膜层的厚度为2到10纳米。

  公开号：

  US09941422B2
• 作为产物：
  描述：

  2-苯基吡啶 、 8-bromo-5H-pyrido[3,2-b]indole 在 potassium carbonate 、 [RuCl2(benzene)]2 、 三苯基膦 作用下， 以 乙二醇二乙醚 为溶剂， 反应 3.33h， 以81%的产率得到8-[2-(2-吡啶基)苯基]-5H-吡啶并[3,2-b]吲哚
  参考文献：
  名称：

  JP5741091

  摘要：

  公开号：

文献信息

• PRODUCING METHOD OF NITROGEN CONTAINING CONDENSED HETEROCYCLIC COMPOUND
  申请人：SUGITA Shuichi

  公开号：US20110184176A1

  公开（公告）日：2011-07-28

  Provided is a method for producing a nitrogen-containing condensed heterocyclic compound containing the step of: reacting a compound represented by Formula (1a) or Formula (1b) with a compound represented by Formula (2) under existence of cupper or a cupper ion, and a ligand to produce a nitrogen-containing condensed heterocyclic compound represented by Formula (3a) or Formula (3b):

  提供一种制备含氮紧缩杂环化合物的方法，其中包括以下步骤：在铜或铜离子和配体的存在下，将公式（1a）或公式（1b）所代表的化合物与公式（2）所代表的化合物反应，以制得公式（3a）或公式（3b）所代表的含氮紧缩杂环化合物。
• Π(PI)-conjugated compound, organic electroluminescence element material, light-emitting material, light-emitting thin film, organic electroluminescence element, display device, and illumination device
  申请人：Konica Minolta, Inc.

  公开号：US11358951B2

  公开（公告）日：2022-06-14

  In order to provide a novel π-conjugated compound capable of increasing the light-emission efficiency of an organic electroluminescence element, for example, this π-conjugated compound has a structure indicated by general formula (1). (In general formula (1): Z1-Z6 each independently indicate a hydrogen atom, a deuterium atom, an electron-donating group D, or an electron-withdrawing group A; at least out of two among Z1-Z6 is an electron-donating group D and the other is an electron-withdrawing group A; and at least one ortho position combination Z1 and Z2, Z2 and Z3, Z3 and Z4, Z4 and Z5, Z5 and Z6, or Z6 and Z1 among Z1-Z6 is one combination out of an electron-donating group D and an electron-donating group D, an electron-withdrawing group A and an electron-withdrawing group A, or an electron-donating group D and an electron-withdrawing group A.)

  为了提供一种新型π共轭化合物，该化合物能够提高有机电致发光元件的发光效率，例如，该π共轭化合物具有通式（1）所示的结构。 (在通式（1）中：Z1-Z6各自独立地表示一个氢原子、一个氘原子、一个电子供能基团D或一个电子取能基团A；Z1-Z6中至少有两个是电子供能基团D，另一个是电子取能基团A；Z1-Z6 中至少有一个正位组合 Z1 和 Z2、Z2 和 Z3、Z3 和 Z4、Z4 和 Z5、Z5 和 Z6 或 Z6 和 Z1 是一个电子供能基团 D 和一个电子供能基团 D、一个电子取能基团 A 和一个电子取能基团 A 或一个电子供能基团 D 和一个电子取能基团 A 中的一个组合。)
• ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, ILLUMINATING DEVICE AND CONDENSED POLYCYCLIC HETEROCYCLIC COMPOUND
  申请人：Sugita Shuichi

  公开号：US20120085997A1

  公开（公告）日：2012-04-12

  Disclosed is an organic electroluminescent element which is characterized in that constituent layers including at least a phosphorescent light-emitting layer are provided between a pair of electrodes, and at least one of the constituent layers contains a compound represented by general formula (1). (In the formula, A 1 , A 2 and A 3 each represents a substituent; n1 and n2 each represents an integer of 0-3; X 1 and X 2 each represents an oxygen atom, a sulfur atom, an alkylene group, an imino group, a carbonyl group, a sulfoxide group or a sulfonyl group, or alternatively X 2 represents a bonding hand; and Z 1 , Z 2 , Z 3 and Z 4 each represents an optionally substituted aromatic heterocyclic ring or an aromatic hydrocarbon ring, provided that all of the Z 1 , Z 2 , Z 3 and Z 4 are not aromatic hydrocarbon rings at the same time.)
• ORGANIC PHOTOELECTRIC CONVERSION ELEMENT AND SOLAR CELL USING THE SAME
  申请人：Konica Minolta, Inc.

  公开号：US20150096610A1

  公开（公告）日：2015-04-09

  Provided are a transparent conductive film having a simple manufacturing process and high transparency, high photoelectric conversion efficiency, and excellent durability and an organic photoelectric conversion element using this transparent conductive film. The transparent conductive film of the present invention is formed by laminating a ground layer which contains a nitrogen-containing organic compound and a metal thin film layer which contains a metal element of Group 11 of the periodic table and has a thickness of from 2 to 10 nm. In addition, the organic photoelectric conversion element of the present invention has a first electrode, a second electrode, and a photoelectric conversion layer present between the first electrode and the second electrode, and at least one of the first electrode and the second electrode of the organic photoelectric conversion element is a transparent conductive film formed by laminating the ground layer which contains the nitrogen-containing organic compound and the metal thin film layer which contains a metal element of Group 11 of the periodic table and has a thickness of from 2 to 10 nm.
• ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE
  申请人：KONICA MINOLTA, INC.

  公开号：US20160285008A1

  公开（公告）日：2016-09-29

  An object of the present invention is to provide an organic electroluminescent element which has a high luminous efficiency and an excellent driving voltage and exhibits excellent stability, and a display device and a lighting device that are equipped with the organic electroluminescent element. The organic electroluminescent element of the present invention is an organic electroluminescent element which includes at least an electron injection layer, an electron transport layer, and a luminous layer between a positive electrode and a negative electrode and in which the electron injection layer contains an electride, the electron transport layer contains an organic compound having a nitrogen atom, at least one of the nitrogen atoms has a lone pair of electrons that does not participate in aromaticity, and the lone pair of electrons does not coordinate a metal.