10,16-Dithiahexacyclo[11.11.0.03,11.04,9.015,23.017,22]tetracosa-1,3(11),4,6,8,12,14,17,19,21,23-undecaene | 1366181-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 10,16-Dithiahexacyclo[11.11.0.03,11.04,9.015,23.017,22]tetracosa-1,3(11),4,6,8,12,14,17,19,21,23-undecaene
• 英文别名: 10,16-dithiahexacyclo[11.11.0.03,11.04,9.015,23.017,22]tetracosa-1,3(11),4,6,8,12,14,17,19,21,23-undecaene
• CAS: 1366181-40-9
• 化学式: C₂₂H₁₂S₂
• 分子量: 340.469
• InChiKey: XXMQWVROQDGCCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二苯并噻吩 在 aluminum (III) chloride 、 氯化亚砜 、 溶剂黄146 、 N,N-二甲基甲酰胺 、 锌 作用下， 以 二硫化碳 、 1,2-二氯乙烷 为溶剂， 反应 184.42h， 生成 10,16-Dithiahexacyclo[11.11.0.03,11.04,9.015,23.017,22]tetracosa-1,3(11),4,6,8,12,14,17,19,21,23-undecaene
  参考文献：
  名称：

  Synthesis and properties of naphthobisbenzo[b]thiophenes: structural curvature of higher acene frameworks for solubility enhancement and high-order orientation in crystalline states

  摘要：

  The syntheses of naphtho[2,3-b:7,6-b']- and naphtho[2,1-b:5,6-b']bisbenzo[b]thiophenes (NBBTs) are achieved via inter- and intramolecular stepwise Friedel-Crafts-type reactions. The structural curvature of these NBBTs are found to improve their solubility in organic solvents, and to form well-defined herringbone structures in single crystals, especially when the C-2v symmetrical naphtho[2,3-b:7,6-b']bisbenzo[b]thiophene takes the form of asymmetric space groups in a parallel direction with each other, and having exhibited OFET characteristics with a hole mobility of 7 x 10(-5) cm(2) V-1 s(-1). (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.01.114

文献信息

• ORGANIC COMPOUND, LIGHT-EMITTING DEVICE, OPTICAL DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210184130A1

  公开（公告）日：2021-06-17

  A novel organic compound with favorable thermophysical properties is provided. An organic compound represented by General Formula (G1) is provided. At least one of X 1 to X 5 is a secondary or tertiary alkyl group having 3 to 6 carbon atoms in which a carbon atom bonded to a phenyl group branches. Each of R 1 to R 7 is independently any of hydrogen, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, and an unsubstituted or alkyl-substituted aryl group having 6 to 13 carbon atoms. Ar 1 represents a substituted or unsubstituted condensed heteroaromatic ring skeleton having 8 to 60 carbon atoms and composed of two or more aromatic rings, and Ar 2 represents a substituted or unsubstituted aryl group having 6 to 25 carbon atoms. Furthermore, n is any of 1 to 3.
• ORGANIC COMPOUND, OPTICAL DEVICE, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210193930A1

  公开（公告）日：2021-06-24

  A novel organic compound represented by General Formula (G1) is provided. In General Formula (G1), X 1 and X 2 each independently represent a secondary or tertiary alkyl group having 3 to 6 carbon atoms and having a branched carbon atom which is bonded to a phenyl group. In addition, Ar 1 represents a substituted or unsubstituted condensed aromatic ring skeleton having 10 to 60 carbon atoms and composed of two or more rings or a substituted or unsubstituted condensed heteroaromatic ring skeleton having 8 to 60 carbon atoms and composed of two or more rings. Furthermore, Ar 2 represents a substituted or unsubstituted aryl group having 6 to 25 carbon atoms. Moreover, n represents any of 1 to 3, and in the case where n is 2 or more, two or more groups bonded to Ar 1 may be identical or different.