(E)-2-bromo-6-(4-bromostyryl)naphthalene

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (E)-2-bromo-6-(4-bromostyryl)naphthalene
• 英文别名: 2-bromo-6-[(E)-2-(4-bromophenyl)ethenyl]naphthalene
• 化学式: C₁₈H₁₂Br₂
• 分子量: 388.101
• InChiKey: BPLCLWCWHYWIRP-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-2-bromo-6-(4-bromostyryl)naphthalene 、 二苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 三叔丁基膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以88%的产率得到(E)-6-(4-(diphenylamino)styrenyl)-N,N-diphenylnaphthalen-2-amine
  参考文献：
  名称：

  WO2008/91130

  摘要：

  公开号：
• 作为产物：
  描述：

  4-溴苄基亚磷酸二乙酯 、 6-溴-2-萘甲醛 在 potassium tert-butylate 作用下， 以 二甲基亚砜 为溶剂， 反应 12.0h， 以91%的产率得到(E)-2-bromo-6-(4-bromostyryl)naphthalene
  参考文献：
  名称：

  WO2008/91130

  摘要：

  公开号：

文献信息

• ASYMMETRIC STYRYL DERIVATIVES AND ORGANIC LIGHT EMITTING DIODE PREPARED USING THE SAME
  申请人：Kim Tae-Hyung

  公开号：US20100081846A1

  公开（公告）日：2010-04-01

  Disclosed are asymmetric styryl derivatives and an organic light emitting diode prepared using the same. More particularly, there are provided asymmetric styryl derivatives that can provide a blue organic light emitting diode with superior thermal stability, as well as improved luminous efficiency, improved brightness, and extended lifetime, by synthesizing a novel thermally stable compound with a styryl structure represented by Formula 1, and using the compound as a dopant in an organic light emitting layer (EML) of a multilayered organic light emitting diode, and an organic light emitting diode prepared by the same.

  本发明涉及不对称的苯乙烯基衍生物及其制备的有机发光二极管。更具体地，本发明提供了一种不对称的苯乙烯基衍生物，通过合成具有式1所表示的苯乙烯结构的新型热稳定化合物，并将该化合物用作多层有机发光二极管的有机发光层（EML）中的掺杂剂，可以提供具有优越热稳定性、改善的发光效率、改善的亮度和延长寿命的蓝色有机发光二极管。同时本发明还提供了制备该有机发光二极管的方法。
• Asymmetric styryl derivatives and organic light emitting diode prepared using the same
  申请人：Kim Tae-Hyung

  公开号：US08476474B2

  公开（公告）日：2013-07-02

  Disclosed are asymmetric styryl derivatives and an organic light emitting diode prepared using the same. More particularly, there are provided asymmetric styryl derivatives that can provide a blue organic light emitting diode with superior thermal stability, as well as improved luminous efficiency, improved brightness, and extended lifetime, by synthesizing a novel thermally stable compound with a styryl structure represented by Formula 1, and using the compound as a dopant in an organic light emitting layer (EML) of a multilayered organic light emitting diode, and an organic light emitting diode prepared by the same.

  本发明公开了一种不对称的苯乙烯衍生物以及使用该衍生物制备的有机发光二极管。更具体地说，本发明提供了一种不对称的苯乙烯衍生物，通过合成一种具有式1所代表的苯乙烯结构的新型热稳定化合物，并将该化合物用作多层有机发光二极管的有机发光层（EML）中的掺杂剂，可以提供具有优越的热稳定性、改善的发光效率、改善的亮度和更长寿命的蓝色有机发光二极管，以及使用该衍生物制备的有机发光二极管。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Mizuki Yumiko

  公开号：US20130221331A1

  公开（公告）日：2013-08-29

  A compound is shown by the following formula (1). wherein l, m, and n are independently an integer from 1 to 3, Ar 1 to Ar 4 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 5 to 30 ring atoms, Ar 5 , Ar 6 , and Ar 7 are independently a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 5 to 30 ring atoms, and p is an integer from 0 to 2, and Ar 6 and N are bonded via a single bond when p is 0, provided that at least one of Ar 1 to Ar 4 is substituted with a substituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, and at least one of Ar 1 to Ar 4 is substituted with a cyano group.
• US8476474B2
  申请人：——

  公开号：US8476474B2

  公开（公告）日：2013-07-02
• [EN] ASYMMETRIC STYRYL DERIVATIVES AND ORGANIC LIGHT EMITTING DIODE PREPARED USING THE SAME<br/>[FR] DÉRIVÉS DE STYRYLE ASYMÉTRIQUE ET DIODE LUMINEUSE ORGANIQUE PRÉPARÉE SUR LEUR BASE
  申请人：DOOSAN CORP

  公开号：WO2008091130A1

  公开（公告）日：2008-07-31

  [EN] Disclosed are asymmetric styryl derivatives and an organic light emitting diode prepared using the same. More particularly, there are provided asymmetric styryl derivatives that can provide a blue organic light emitting diode with superior thermal stability, as well as improved luminous efficiency, improved brightness, and extended lifetime, by synthesizing a novel thermally stable compound with a styryl structure represented by Formula 1, and using the compound as a dopant in an organic light emitting layer (EML) of a multilayered organic light emitting diode, and an organic light emitting diode prepared by the same.
  [FR] L'invention concerne des dérivés de styryle asymétrique et une diode lumineuse organique préparée sur leur base. Elle concerne plus particulièrement des dérivés de styryle asymétrique qui permettent de former une diode organique émettant une lumière bleue à stabilité thermique améliorée ainsi qu'une efficace lumineuse améliorée, une luminance améliorée et une durée de vie plus élevée, grâce à la synthèse d'un nouveau composé thermiquement stable avec une structure de styryle représentée par la formule 1 et à l'utilisation du composant en tant que dopage dans une couche émettrice de lumière d'une diode lumineuse organique à couches multiples, et une diode lumineuse organique préparée au moyen de ce procédé.