bis<6-(5,6-dihydrosanguinarinyl)> ether

分子结构分类

有机化合物 - 生物碱及其衍生物 - 苯并菲啶生物碱

中文名称

——

中文别名

——

英文名称

bis<6-(5,6-dihydrosanguinarinyl)> ether

英文别名

bis(dihydrosanguinarinyl) ether；13,13'-dimethyl-13,14,13',14'-tetrahydro-14,14'-oxy-bis-[1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridine；13,13'-Dimethyl-13,14,13',14'-tetrahydro-14,14'-oxy-bis-[1,3]dioxolo[4',5':4,5]benzo[1,2-c]phenanthridin；24-Methyl-23-[(24-methyl-5,7,18,20-tetraoxa-24-azahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-1(13),2,4(8),9,11,14(22),15,17(21)-octaen-23-yl)oxy]-5,7,18,20-tetraoxa-24-azahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-1(13),2,4(8),9,11,14(22),15,17(21)-octaene

bis<6-(5,6-dihydrosanguinarinyl)> ether化学式

CAS

——

化学式

C₄₀H₂₈N₂O₉

mdl

——

分子量

680.67

InChiKey

SMYVOGFWVPCZDE-UHFFFAOYSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

8.1
重原子数：

51
可旋转键数：

2
环数：

12.0
sp3杂化的碳原子比例：

0.2
拓扑面积：

89.6
氢给体数：

0
氢受体数：

11

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	8-hydroxydihydosanguinarine	4070-41-1	C₂₀H₁₅NO₅	349.343

反应信息

作为产物：

描述：

血根碱在 sodium carbonate 作用下，以水为溶剂，生成 bis<6-(5,6-dihydrosanguinarinyl)> ether

参考文献：

名称：

Sanguinarine pseudobase: re-examination of NMR assignments using gradient-enhanced spectroscopy

摘要：

The formation of sanguinarine pseudobase (6-hydroxydihydrosanguinarine) was studied by 1D and 2D NMR spectroscopy. The unequivocal evidence of a hemiaminal OH group and unambiguous H-1, C-13 and N-15 NMR assignments of this compound are discussed. (C) 1998 John Wiley & Sons, Ltd.

DOI：

10.1002/(sici)1097-458x(1998110)36:11<869::aid-omr380>3.0.co;2-8

点击查看最新优质反应信息

文献信息

Beke et al., Magyar Kemiai Folyoirat, 1958, vol. 64, p. 125,129

作者：Beke et al.

DOI：——

日期：——
Sanguinarine pseudobase: re-examination of NMR assignments using gradient-enhanced spectroscopy

作者：Jiří Dostál、Radek Marek、Jiří Slavík、Eva Táborská、Milan Potáček、Vladimír Sklenář

DOI：10.1002/(sici)1097-458x(1998110)36:11<869::aid-omr380>3.0.co;2-8

日期：1998.11

The formation of sanguinarine pseudobase (6-hydroxydihydrosanguinarine) was studied by 1D and 2D NMR spectroscopy. The unequivocal evidence of a hemiaminal OH group and unambiguous H-1, C-13 and N-15 NMR assignments of this compound are discussed. (C) 1998 John Wiley & Sons, Ltd.

同类化合物

血根黄碱血根碱血根碱血根樹鹼硝酸鹽紫堇灵紫堇洛星碱白屈菜默碱白屈菜赤碱白屈菜红碱氯化物白屈菜红碱白屈菜红碱白屈菜碱白屈菜宾氯化血根碱水合物博落回醇碱博落回提取物二氢白屈菜红碱乙酰紫堇灵乙氧基血根碱丙酮基白屈菜赤碱 β-高白屈菜碱 N-[7-(6-羟基-1,3-苯并二氧戊环-5-基)苯并[f][1,3]苯并二氧戊环-8-基]-N-甲基甲酰胺 N-[6-(2-羟基-3,4-二甲氧基苯基)萘并[2,3-d][1,3]二氧杂环戊烯-5-基]-N-甲基甲酰胺 6-丙酮基二氢血根碱 4,9,10-三甲氧基-5b,12-二甲基-5b,6,7,11b,12,13-六氢苯并[c][1,3]二噁唑并[4,5-i]5-氮杂菲-6-醇 13,14-二氢血根碱 (5bR,6S,12bS,5b'R,6'S,12b'S,5b''R,6''S,12b''S)-13,13',13''-[硫代磷酰三(亚氨基乙烷-2,1-二基)]三(6-羟基-13-甲基-5b,6,7,12b,13,14-六氢[1,3]苯并二噁唑并[5,6-c][1,3]二噁唑并[4,5-i]5-氮杂菲-13-正离子)三氢氧化 (-)-白屈菜碱 (+)-白屈菜碱盐酸盐 6-(dibutylphosphonyl)-5,6-dihydrochelerythrine chelidonyl-ethyl-oxalic acid diester chelidonyl-phenylalanyl ester N-(3-trifluoromethylphenyl)-chelidonyl-urethane 6-(1′-nitropropyl)-5,6-dihydrochelerythrine 7-hydroxynitidine 6-(diethylmalonyl)-5,6-dihydrochelerythrine 6-(1'-nitroethyl)-5,6-dihydrochelerythrine 2,8-dimethoxy-3,7-dihydroxy-5-methyl-benzo[c]phenanthridinium chloride bis<6-(5,6-dihydrosanguinarinyl)> ether (+)-chelidonine (±)-maclekarpine B bis(dihydrochelirubunyl) ether 13-ethoxy-2,3-dimethoxy-12-methyl-1-phenylmethoxy-13H-[1,3]benzodioxolo[5,6-c]phenanthridine 7-hydroxynitidine hydrogen sulfate (1S,12S,13R,24R)-24-[2-[bis[2-[(1S,12S,13R,24R)-12-hydroxy-24-methyl-5,7,18,20-tetraoxa-24-azoniahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-2,4(8),9,14(22),15,17(21)-hexaen-24-yl]ethylamino]phosphinothioylamino]ethyl]-24-methyl-5,7,18,20-tetraoxa-24-azoniahexacyclo[11.11.0.02,10.04,8.014,22.017,21]tetracosa-2,4(8),9,14(22),15,17(21)-hexaen-12-ol;trihydroxide Ukrain cation 4-Pyridinecarbonitrile, 2-(1-(12,13-dihydro-1,2-dimethoxy-12-methyl(1,3)benzodioxolo(5,6-c)phenanthridin-13-yl)ethyl)-, (R*,S*)- (1,3)Benzodioxolo(5,6-c)phenanthridine-13-methanol, 12,13-dihydro-1-hydroxy-2-methoxy-12-methyl- 2-methoxy-12-methyl-12H-[1,3]benzodioxolo[5,6-c]phenanthridin-12-ium-1-one Nitrotyrasanguinarine

bis<6-(5,6-dihydrosanguinarinyl)> ether

分子结构分类

计算性质

上下游信息

反应信息

文献信息

同类化合物

相关结构分类

热门分子