1-[2-[Bis[2-(2-aminobenzimidazol-1-yl)ethyl]amino]ethyl]benzimidazol-2-amine | 1393369-87-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 1-[2-[Bis[2-(2-aminobenzimidazol-1-yl)ethyl]amino]ethyl]benzimidazol-2-amine
• 英文别名: 1-[2-[bis[2-(2-aminobenzimidazol-1-yl)ethyl]amino]ethyl]benzimidazol-2-amine
• CAS: 1393369-87-3
• 化学式: C₂₇H₃₀N₁₀
• 分子量: 494.602
• InChiKey: TWGYTNGLEWEKCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  37
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  135
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1-[2-[Bis[2-(2-aminobenzimidazol-1-yl)ethyl]amino]ethyl]benzimidazol-2-amine 、 四丁基碘化铵 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Benzimidazole functionalized tripodal receptor for selective recognition of iodide

  摘要：

  A novel tripodal fluorescent receptor with benzimidazole motifs as signaling unit is reported. The receptor can selectively bind iodide anion with drastic change in its fluorescence and UV/Vis spectra, while addition of other anions (F-, Cl-, Br-, H2PO4-, SO42-, CH3COO-, NO3- and CN-) does not show any significant change. The formation of receptor-iodide hydrogen bonded complex is proved by NMR titration of the receptor in the presence of iodide anion. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.06.120
• 作为产物：
  描述：

  在 sodium sulfide 作用下， 以 乙腈 为溶剂， 生成 1-[2-[Bis[2-(2-aminobenzimidazol-1-yl)ethyl]amino]ethyl]benzimidazol-2-amine
  参考文献：
  名称：

  A retrievable fluorescence “TURN ON” sensor for sulfide anions

  摘要：

  A benzimidazole based tripodal fluorescence derivative (L-1) is synthesized and characterized. Combining L-1 with Cu2+ shows excellent selectivity toward sulfide anions. The binding stoichiometry of L-1 with Cu2+ is established by jobs plot analysis and mass spectral evidence and the binding mode is established by synthesis of a control compound L-2. The initial fluorescence of L-1 is lost on complexation with Cu2+ and is regained in presence of sulfide. The "OFF-ON" behavior of L-1 is studied by Fluorescence, UV/vis and mass spectroscopic methods. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jphotochem.2012.10.024

文献信息

• A retrievable fluorescence “TURN ON” sensor for sulfide anions
  作者：Chirantan Kar、Gopal Das

  DOI：10.1016/j.jphotochem.2012.10.024

  日期：2013.1

  A benzimidazole based tripodal fluorescence derivative (L-1) is synthesized and characterized. Combining L-1 with Cu2+ shows excellent selectivity toward sulfide anions. The binding stoichiometry of L-1 with Cu2+ is established by jobs plot analysis and mass spectral evidence and the binding mode is established by synthesis of a control compound L-2. The initial fluorescence of L-1 is lost on complexation with Cu2+ and is regained in presence of sulfide. The "OFF-ON" behavior of L-1 is studied by Fluorescence, UV/vis and mass spectroscopic methods. (C) 2012 Elsevier B.V. All rights reserved.
• Benzimidazole functionalized tripodal receptor for selective recognition of iodide
  作者：Chirantan Kar、Arghya Basu、Gopal Das

  DOI：10.1016/j.tetlet.2012.06.120

  日期：2012.8

  A novel tripodal fluorescent receptor with benzimidazole motifs as signaling unit is reported. The receptor can selectively bind iodide anion with drastic change in its fluorescence and UV/Vis spectra, while addition of other anions (F-, Cl-, Br-, H2PO4-, SO42-, CH3COO-, NO3- and CN-) does not show any significant change. The formation of receptor-iodide hydrogen bonded complex is proved by NMR titration of the receptor in the presence of iodide anion. (c) 2012 Elsevier Ltd. All rights reserved.