N-[[(1S,2R,6R,8R,9S)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-8-yl]methyl]hydroxylamine | 78699-90-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧吡喃
• 英文名称: N-[[(1S,2R,6R,8R,9S)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-8-yl]methyl]hydroxylamine
• CAS: 78699-90-8
• 化学式: C₁₂H₂₁NO₆
• 分子量: 275.302
• InChiKey: QIKCZOPJTLOEJD-SOYHJAILSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  78.4
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  N-[[(1S,2R,6R,8R,9S)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-8-yl]methyl]hydroxylamine 生成 [acetyl-[[(1S,2R,6R,8R,9S)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-8-yl]methyl]amino] acetate
  参考文献：
  名称：

  TRONCHET, JEAN M. J.;ZOSIMO-LANDOLFO, GUIDO;BIZZOZERO, NICOLETTA;CABRINI,+, J. CARBOHYDR. CHEM., 7,(1988) N 1, 169-186

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-6-deoxy-6-(N-hydroxyimino)-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 生成 N-[[(1S,2R,6R,8R,9S)-4,4,11,11-tetramethyl-3,5,7,10,12-pentaoxatricyclo[7.3.0.02,6]dodecan-8-yl]methyl]hydroxylamine
  参考文献：
  名称：

  TRONCHET, JEAN M. J.;ZOSIMO-LANDOLFO, GUIDO;BIZZOZERO, NICOLETTA;CABRINI,+, J. CARBOHYDR. CHEM., 7,(1988) N 1, 169-186

  摘要：

  DOI：

文献信息

• Dérivés de désoxy-hydroxylamino-sucres et radicaux libres diglycosylnitroxydes correspondants. Communication préliminaire
  作者：Jean M. J. Tronchet、Eva Winter-Mihaly、Ford Habashi、Dominique Schwarzenbach、Ubavka Likić、Michel Geoffroy

  DOI：10.1002/hlca.19810640225

  日期：1981.3.18

  Deoxy-hydroxylamino-sugar Derivatives and Corresponding Diglycosylnitroxides Radicals

  脱氧羟氨基糖衍生物和相应的二糖基硝基氧自由基
• Spacer arms bearing two N-hydroxyimino groups and nitroxyl free radicals thereof
  作者：Jean M.J. Tronchet、Maria Koufaki、Guido Zosimo-Landolfo

  DOI：10.1016/0008-6215(91)80167-l

  日期：1991.1

  Synthesis and e.s.r. study of model compounds in which two blocked sugar units are connected by a spacer arm that includes two N-hydroxyimino groups, with the aim of testing the feasibility of generating diradical species from such precursors

  通过两个包括两个N-羟基亚氨基的间隔臂连接两个封闭的糖单元的模型化合物的合成和esr研究，目的是测试从此类前体生成双自由基物质的可行性
• Tronchet, Jean M. J.; Bizzozero, Nicoletta; Koufaki, Maria, Journal of Chemical Research, Miniprint, 1989, # 11, p. 2601 - 2619
  作者：Tronchet, Jean M. J.、Bizzozero, Nicoletta、Koufaki, Maria、Habashi, Ford、Geoffroy, Michel

  DOI：——

  日期：——
• Hydroxyamino sugar derivatives: sugar nitrones
  作者：G Zosimo-Landolfo、J.M.J Tronchet、N Bizzozero、F Habashi、A Kamatari

  DOI：10.1016/s0014-827x(98)00069-x

  日期：1998.8

  We describe in this paper the preparation of 46 new sugar nitrone derivatives and their antibacterial activity against Escherichia coli and Bacillus subtilis. (C) 1998 Elsevier Science S.A. All rights reserved.
• Tronchet, Jean M. J.; Jean, Evelyne; Galland-Barrera, Griselda, Journal of Chemical Research, Miniprint, 1991, # 9, p. 2439 - 2452
  作者：Tronchet, Jean M. J.、Jean, Evelyne、Galland-Barrera, Griselda

  DOI：——

  日期：——