Cd(SePh)2 | 120138-29-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cd(SePh)2
• 英文别名: cadmium bis(phenylselenolate)
• CAS: 120138-29-6
• 化学式: 2C₆H₅Se*Cd
• 分子量: 424.541
• InChiKey: QBDVIQZNYHMEFO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.48
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Cd(SePh)2 在 Na₂S or NaSH 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Lee, Garry S.H.; Fisher, Keith J.; Craig, Don C., Journal of the American Chemical Society, 1990, vol. 112, # 17, p. 6435 - 6437

  摘要：

  DOI：
• 作为产物：
  描述：

  苯硒酚 、 高纯二甲基镉 以 甲苯 为溶剂， 以80%的产率得到Cd(SePh)2
  参考文献：
  名称：

  The preparation of large semiconductor clusters via the pyrolysis of a molecular precursor

  摘要：

  DOI：

  10.1021/ja00193a079

文献信息

• Interlinking supertetrahedral chalcogenolate clusters with bipyridines to form two-dimensional coordination polymers for photocatalytic degradation of organic dye
  作者：Chao Xu、Ming-Ming Sheng、Hua-Tian Shi、Maria Strømme、Qian-Feng Zhang

  DOI：10.1039/c9dt00480g

  日期：——

  Chalcogenolate clusters Cd6Ag4(EPh)16(DMF)3(CH3OH) (E = S, Se) with supertetrahedral structures are isolated. Further interlinking the clusters with organic linker 4,4′-trimethylenedipiperidine in the stepwise assembly approach forms two-dimensional coordination polymers. The clusters and the coordination polymers show tunable band gaps and efficient photocatalytic activities for the degradation of

  分离出具有超四面体结构的硫属元素簇Cd 6 Ag 4（EPh）16（DMF）3（CH 3 OH）（E = S，Se）。以逐步组装的方式将簇与有机连接基4,4'-三亚甲基二哌啶进一步互连形成二维配位聚合物。团簇和配位聚合物显示出可调节的带隙和对染料水溶液降解的有效光催化活性。这项研究表明硫属元素酸酯簇及其配位聚合物在光催化应用中具有巨大的潜力。
• Dean, Philip A. W.; Payne, Nicholas C.; Vittal, Jagadese J., Inorganic Chemistry, 1993, vol. 32, # 21, p. 4632 - 4639
  作者：Dean, Philip A. W.、Payne, Nicholas C.、Vittal, Jagadese J.、Wu, Yuyang

  DOI：——

  日期：——
• Stuczynski; Brennan; Steigerwald, Inorganic Chemistry, 1989, vol. 28, # 25, p. 4431 - 4432
  作者：Stuczynski、Brennan、Steigerwald

  DOI：——

  日期：——
• Kumar, Rajesh; Tuck, Dennis G., Canadian Journal of Chemistry, 1989, vol. 67, p. 127 - 129
  作者：Kumar, Rajesh、Tuck, Dennis G.

  DOI：——

  日期：——
• Cadmium bis(phenylselenolate) as a precursor for the synthesis of polymeric Cd(μ-Se)clusters: Crystal and molecular structures of [Cd4(SePh)7(PPh3)X] (X = Cl, Br)
  作者：Ernesto Schulz Lang、Robert A. Burrow、Rafael Stieler、Marcos Antonio Villetti

  DOI：10.1016/j.jorganchem.2009.04.027

  日期：2009.8

  The reaction of Cd(SePh)(2) with CdX2 (X = Cl (1), Br (2)) in MeOH in the presence of PPh3 at 130 degrees C under solvothermal conditions affords the products [Cd-4(SePh)(7)(PPh3)X](n), a one-dimensional assembly of adamantanoid [Cd-4(SePh)(6)(PPh3)X] clusters joined into a polymeric chain by mu-SePh bridges. Compounds 1 and 2 represent examples of extended one-dimensional chains of closed ME (M = metal, E = S, Se, Te) systems, whose importance is based not only on their properties, but by their possible use as precursor materials for design and development of new methodologies via a "bottom up" strategy to obtain different clusters from single components. (C) 2009 Elsevier B. V. All rights reserved.