bis(2,2-dimethylpropyl)cadmium(II) | 130312-36-6

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: bis(2,2-dimethylpropyl)cadmium(II)
• 英文别名: dineopentylcadmium
• CAS: 130312-36-6
• 化学式: C₁₀H₂₂Cd
• 分子量: 254.695
• InChiKey: AGIIGJFMSSMXOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.73
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(2,2-dimethylpropyl)cadmium(II) 、 cadmium(II) bis-N,N'-diethyldithiocarbamate 以 甲苯 为溶剂， 以89%的产率得到neopentylcadmium-N,N-diethyldithiocarbamate
  参考文献：
  名称：

  新戊基镉物种与二硫代和二硒代氨基甲酸酯的某些配合物：镉的新戊基/二乙基二硒代氨基甲酸酯混合体的合成，表征和单晶X射线结构：[（CH 3）3 CCH 2 CdSe 2 CNEt 2 ] 2

  摘要：

  镉的新戊基络合物的合成和表征（CH 3）3 CH 2 CCDE 2 CNET 2（ES或Se）和相关的混合金属物种（CH 3）3 CH 2 CZN 0.5镉0.5硒2 CNET 2是报告。（CH 3）3 CH 2 CCdSe 2 CNEt 2的单晶X射线结构测定；该化合物是二聚体。所有的配合物分解，得到相应的二元或三元金属硫属化物。

  DOI：

  10.1016/0022-328x(94)87038-1
• 作为产物：
  描述：

  bis(neopentyl)magnesium 、 cadmium(II) chloride 以 乙醚 为溶剂， 生成 bis(2,2-dimethylpropyl)cadmium(II)
  参考文献：
  名称：

  Reactions of Diorganocadmium Compounds with Other Dialkylmetal Compounds and Macrocycles:  Synthesis of Organocadmate Anions¹

  摘要：

  Combining R2Cd (R an alkyl or Ph group), the corresponding R2Mg compound, and 1,4,8,- 11-tetramethyl-1,4,8,11-tetraazatetradecane, 2,1,1-cryptand, or 2,2,1-cryptand in solution quantitatively produces R3Cd- and RMg(macrocycle)(+) ions. Solutions obtained by combining the same macrocycles with R2Cd alone or with R2Cd plus the corresponding R2Zn compound do not contain significant amounts of ions; rapid exchange of R groups in these solutions, however, may be due to formation of trace amounts of R3Cd- ions.

  DOI：

  10.1021/om001020c

文献信息

• The preparation and characterization of bis(2,2-dimethylpropyl)cadmium(II) and its 2,2′-bipyridyl adduct
  作者：Paul O'Brien、John R. Walsh、Anthony C. Jones、Simon A. Rushworth

  DOI：10.1016/s0277-5387(00)86754-6

  日期：1990.1

  Abstract The synthesis and characterization of the compound bis(2,2-dimethylpropyl)cadmium(II), bis(neopentyl)cadmium(II)} and its 1:1 adduct with 2,2′-bipyridyl are reported. The alkyl is moderately volatile (vapour pressure ca 3 torr, 52°C) and may find application as a precursor for the deposition of cadmium-containing films by MOCVD.

  摘要报道了双（2,2-二甲基丙基）镉（II），双（新戊基）镉（II）}及其与2,2'-联吡啶的1：1加合物的合成与表征。烷基具有中等挥发性（蒸气压约为3 torr，52°C），可以用作通过MOCVD沉积含镉薄膜的前体。
• Reactions of Diorganocadmium Compounds with Other Dialkylmetal Compounds and Macrocycles:  Synthesis of Organocadmate Anions¹
  作者：Hui Tang、Herman G. Richey

  DOI：10.1021/om001020c

  日期：2001.4.1

  Combining R2Cd (R an alkyl or Ph group), the corresponding R2Mg compound, and 1,4,8,- 11-tetramethyl-1,4,8,11-tetraazatetradecane, 2,1,1-cryptand, or 2,2,1-cryptand in solution quantitatively produces R3Cd- and RMg(macrocycle)(+) ions. Solutions obtained by combining the same macrocycles with R2Cd alone or with R2Cd plus the corresponding R2Zn compound do not contain significant amounts of ions; rapid exchange of R groups in these solutions, however, may be due to formation of trace amounts of R3Cd- ions.
• Some complexes of neopentylcadmium species with dithio-and di-selenocarbamates: The synthesis, characterization and single crystal X-ray structure of a mixed neopentyl/diethyldiselenocarbamate of cadmium: [(CH3)3CCH2CdSe2CNEt2]2
  作者：Isaac Abrahams、Azad Malik、M. Motevalli、Paul O'Brien

  DOI：10.1016/0022-328x(94)87038-1

  日期：1994.2

  The synthesis and characterization of the neopentyl complexes of cadmium (CH3)3CH2CCdE2CNEt2 (E  S or Se) and the related mixed metal species (CH3)3CH2CZn0.5Cd0.5Se2CNEt2 are reported. A single crystal X-ray structure determination on for (CH3)3CH2CCdSe2CNEt2; the compound is dimeric. All of the complexes decompose to give the corresponding binary or ternary metal chalcogenides.

  镉的新戊基络合物的合成和表征（CH 3）3 CH 2 CCDE 2 CNET 2（ES或Se）和相关的混合金属物种（CH 3）3 CH 2 CZN 0.5镉0.5硒2 CNET 2是报告。（CH 3）3 CH 2 CCdSe 2 CNEt 2的单晶X射线结构测定；该化合物是二聚体。所有的配合物分解，得到相应的二元或三元金属硫属化物。