N-nitrosylhydroxylamine-N-sulfonate(2-) | 29285-09-4

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属有机物
• 英文名称: N-nitrosylhydroxylamine-N-sulfonate(2-)
• 英文别名: N-nitrosohydroxylaminemonosulfonate；N-nitroso-N-oxidosulfamate
• CAS: 29285-09-4
• 化学式: N₂O₅S
• 分子量: 140.076
• InChiKey: NHDNEXYDOIKALQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.07
• 重原子数：
  8.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112.93
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N-nitrosylhydroxylamine-N-sulfonate(2-) 在 水 作用下， 以 水 为溶剂， 生成 硫酸酯 、 一氧化二氮
  参考文献：
  名称：

  Kinetic evidence for the redox cycling of manganese(II,III) in the presence of^–ON(NO)SO₃^–in aqueous media

  摘要：

  Redox cycling of Mn-II/III in the presence of (ON)-O--(NO)SO3- in the absence and presence of oxygen was studied by following the increase and decrease of Mn-III spectrophotometrically as a function of [(ON)-O--(NO)SO3-], [Mn-III], [Mn-II] and pH. The autoxidation reaction exhibits typical autocatalytic behaviour in which the induction period depends on the concentrations of Mn-III and (ON)-O--(NO)SO3-. Under acidic conditions the reaction does not take place in the absence of Mn-III or O-2. The concentrations of O-2, Mn-II and (ON)-O--(NO)SO3- determine whether only oxidation of Mn-II to Mn-III, or reduction of Mn-III to Mn-II, or both in one or two redox cycles is observed. Preliminary simulations of some of the observed kinetic traces are presented.

  DOI：

  10.1039/dt9950000293
• 作为产物：
  描述：

  氧化亚氮 、 hydrogen sulfite 以 水 为溶剂， 生成 N-nitrosylhydroxylamine-N-sulfonate(2-)
  参考文献：
  名称：

  Littlejohn, David; Hu; Chang, Inorganic Chemistry, 1986, vol. 25, # 18, p. 3131 - 3135

  摘要：

  DOI：

文献信息

• Reaction of nitric oxide with sulfur(IV) oxides in the presence of iron(II) complexes in aqueous solution
  作者：Volker Zang、Rudi van Eldik

  DOI：10.1039/dt9930000111

  日期：——

  ethylenediaminetetraacetate, N-2-hydroxyethylethylenediaminetriacetate or nitrilotriacetate) can effectively bind NO in aqueous solution to produce FeL(NO) species which can react with sulfur(IV) oxides to produce FeIIIL, N2O, SO42– and various nitrogensulfur oxides. The kinetics of these reactions was studied as a function of [SIV]T and pH using stopped-flow and UV/VIS spectroscopic techniques. Depending

  Fe II L类型的络合物（L =二亚乙基三胺五乙酸酯，乙二胺四乙酸酯，N -2-羟乙基亚乙基二胺三乙酸酯或次氮基三乙酸酯）可以在水溶液中有效结合NO生成FeL（NO）物种，该物种可以与氧化硫（IV）反应生成Fe III L ，N 2 O，SO 4 2–和各种氮氧化物。使用停止流和UV / VIS光谱技术研究了这些反应的动力学与[S IV ] T和pH的关系。根据所选的实验条件，观察到了两个后续反应：第一个反应涉及未配位的NO与硫的反应（IV）氧化物主要生成– ON（NO）SO 3 –，而第二步涉及根据Boedeker工艺亚硫酸盐对配位的NO（大概是亚硝酰基）的攻击，从而生成Fe III L，N 2 O，SO 4 2 –和HON（SO 3）2 2–。还在流动反应器中研究了反应，在该反应器中，NO气体流通过Fe II在线监测L-亚硫酸盐溶液和反应产物。从这两种方法获得的信息被用于建议各个步骤
• Seel, F.; Wagner, M., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Seel, F.、Wagner, M.

  DOI：——

  日期：——
• Littlejohn, David; Hu; Chang, Inorganic Chemistry, 1986, vol. 25, # 18, p. 3131 - 3135
  作者：Littlejohn, David、Hu、Chang

  DOI：——

  日期：——
• Kinetic evidence for the redox cycling of manganese(<scp>II</scp>,<scp>III</scp>) in the presence of^–ON(NO)SO₃^–in aqueous media
  作者：Frans F. Prinsloo、Jakobus J. Pienaar、Rudi van Eldik

  DOI：10.1039/dt9950000293

  日期：——

  Redox cycling of Mn-II/III in the presence of (ON)-O--(NO)SO3- in the absence and presence of oxygen was studied by following the increase and decrease of Mn-III spectrophotometrically as a function of [(ON)-O--(NO)SO3-], [Mn-III], [Mn-II] and pH. The autoxidation reaction exhibits typical autocatalytic behaviour in which the induction period depends on the concentrations of Mn-III and (ON)-O--(NO)SO3-. Under acidic conditions the reaction does not take place in the absence of Mn-III or O-2. The concentrations of O-2, Mn-II and (ON)-O--(NO)SO3- determine whether only oxidation of Mn-II to Mn-III, or reduction of Mn-III to Mn-II, or both in one or two redox cycles is observed. Preliminary simulations of some of the observed kinetic traces are presented.