To provide an article having a water-repellent surface, which has excellent water repellency and abrasion resistance.
An article having a water-repellent layer comprising the following inner layer and the following surface layer, on a surface of a substrate, and characterized in that the surface of the water-repellent layer has (a) a surface area ratio (S ratio) of from 1.01 to 1.40, (b) an average surface roughness (Ra) of from 3 to 80 nm, (c) a root-mean-square surface roughness (RMS) of from 3 to 90 nm, (d) an absolute value of the difference between the average surface roughness (Ra) and the root-mean-square surface roughness (RMS) of at most 20 nm and (e) a maximum peak-valley difference (P-V) of from 40 to 600 nm:
Inner layer: A layer which is formed by sintering a mixture of metal oxide spherical fine particles (A) having a mean primary particle size of from 1 to 60 nm and metal oxide spherical fine particles (B) having a mean primary particle size of from 50 to 300 nm, provided that the difference in the mean primary particle size between the metal oxide spherical fine particles (A) and the metal oxide spherical fine particles (B) is at least 20 nm and the proportion of the metal oxide spherical fine particles (A) to the total of the metal oxide spherical fine particles (A) and the metal oxide spherical fine particles (B) is more than 30 mass% and at most 60 mass%, and which has a thickness of at most 5 times the mean primary particle size of the metal oxide spherical fine particles (B),
Surface layer: A layer which comprises hydrophobized metal oxide fine particles (C) whose mean primary particle size is from 1 to 20 nm and a metal oxide binder, provided that the metal oxide binder is made of a binder material containing a metal compound (D) which becomes a metal oxide by a hydrolytic condensation reaction or thermal decomposition, and in which the hydrophobized metal oxide fine particles (C) adhere to the surface of the spherical fine particles present on the upper side of the inner layer.
提供一种具有憎
水表面的物品,它具有优异的憎
水性和耐磨性。
一种在基底表面上具有由以下内层和以下表层组成的憎
水层的制品,其特征在于憎
水层的表面具有 (a) 1.01 至 1.40,(b)平均表面粗糙度(Ra)为 3 至 80 nm,(c)均方根表面粗糙度(RMS)为 3 至 90 nm,(d)平均表面粗糙度(Ra)与均方根表面粗糙度(RMS)之差的绝对值最多为 20 nm,(e)最大峰谷差(P-V)为 40 至 600 nm:
内层:烧结平均一次粒径为 1 至 60 纳米的金属氧化物球形微粒(A)和平均一次粒径为 50 至 300 纳米的金属氧化物球形微粒(B)的混合物而形成的层、条件是金属氧化物球形细颗粒(A)和金属氧化物球形细颗粒(B)之间的平均初级粒径之差至少为 20 nm,且金属氧化物球形细颗粒(A)占金属氧化物球形细颗粒(A)和金属氧化物球形细颗粒(B)总量的比例超过 30 质量%,最多不超过 60 质量%,且其厚度最多为金属氧化物球形细颗粒(B)平均初级粒径的 5 倍、
表面层:表层:由疏
水性金属氧化物细颗粒(C)和金属氧化物粘合剂组成,金属氧化物粘合剂由含有
金属化合物(D)的粘合剂材料制成,
金属化合物(D)通过
水解缩合反应或热分解成为金属氧化物,其中疏
水性金属氧化物细颗粒(C)粘附在内层上侧的球形细颗粒表面。