4-hydroxybutyl methacrylate glycidyl ether

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4-hydroxybutyl methacrylate glycidyl ether
• 英文别名: 4-glycidyloxybutyl methacrylate；4-(Oxiran-2-ylmethoxy)butyl 2-methylprop-2-enoate
• 化学式: C₁₁H₁₈O₄
• 分子量: 214.262
• InChiKey: MRAQBFWDESAIMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  15
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  48.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-(环氧乙烷-2-基甲氧基)-1-丁醇 、 甲基丙烯酸甲酯 在 tetrabutoxytitanium 、 4-甲氧基苯酚 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以53.4%的产率得到4-hydroxybutyl methacrylate glycidyl ether
  参考文献：
  名称：

  JP5709083

  摘要：

  公开号：

文献信息

• Phosphorus containing materials, their preparation and use
  申请人：——

  公开号：US20040026671A1

  公开（公告）日：2004-02-12

  There is described a co-polymerisable phosphorus containing polymer precursor which comprises: a) a polymerisable unsaturated bond; b) a oxycarbonyl or iminocarbony group; and c) a free hydroxy group or a functional group obtainable by reaction of a free hydroxy group with a suitable electrophile; and d) a terminal phosphorus and oxygen containing group located at the end of a carbon chain and comprising at least one group selected from: hydroxy phosphorus and an optionally substituted hydrocarbyl group attached to a phosphorus atom through an oxy group; where the polymer precursor: is substantially free of halo comprising species; has a molecular weight (Mn if a polymer) of from about 200 to about 5,000 daltons; and optionally, has a Hoppler viscosity measured at 25° C. of less than about 14,000 mPa.s. These polymer precursors are obtainable as the product of a reaction between an optionally substituted terminal phosphate or H-phosphonate ester and compound comprising at least one oxiranyl, preferably epoxy, ring adjacent an alkylidenylcarbonyloxy group. The polymer precursors can be copolymerised with other monomers to produce copolymers such as phosphorus containing polyurethanes which for example have use as flame retardants, anti-corrosives, pigment dispersants and/or adhesion promoters.

  描述了一种共聚磷含量聚合物前体，其包括：a）可聚合不饱和键；b）氧羰基或亚氨基羰基团；c）自由羟基或可通过与适当电子亲合剂反应获得的功能基团；以及d）位于碳链末端的含磷氧基团，包括至少一种从羟基磷和可选取代的烃基团通过氧基连接到磷原子的团；其中，聚合物前体：基本上不含卤素物种；分子量（如果是聚合物，则为Mn）为约200至约5,000道尔顿；可选地，在25℃下测得的霍普勒黏度小于约14,000mPa.s。这些聚合物前体可作为可选取代的末端磷酸盐或H-膦酸酯与至少一个邻接烷基烯基羰酰氧基团的化合物之间反应的产物获得。聚合物前体可以与其他单体共聚，以产生诸如含磷聚氨酯等共聚物，例如用作阻燃剂、防腐剂、颜料分散剂和/或粘接剂。
• PHOTOCHROMIC COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：US20160222285A1

  公开（公告）日：2016-08-04

  A photochromic composition comprising (A) a polyrotaxane having a composite molecular structure composed of an axial molecule and a plurality of cyclic molecules clathrating the axial molecule and (B) a photochromic compound.

  一种光致变色组合物，包括(A)聚轮烷，其具有由轴向分子和多个环状分子组成的复合分子结构，并且(B)光致变色化合物。
• PHOTOCHROMIC CURABLE COMPOSITION, CURED PRODUCT THEREOF AND LAMINATE INCLUDING THE CURED PRODUCT
  申请人：TOKUYAMA CORPORATION

  公开号：US20160002524A1

  公开（公告）日：2016-01-07

  A curable composition which comprises a carbonate-based polymerizable monomer represented by the following formula, other polymerizable monomers and a photochromic compound, can be used even under high-temperature and high-humidity conditions without any problems and provides a cured product having excellent photochromic properties. wherein A and A′ are each a linear or branched alkylene group having 2 to 15 carbon atoms, “a” is an average value of 1 to 20, when there are a plurality of A's, A's may be the same or different, R 1 is a hydrogen atom or methyl group, and R 2 is a (meth)acryloyloxy group or hydroxyl group.

  可治愈组合物包括以下化学式所表示的碳酸酯基可聚合单体、其他可聚合单体和光致变色化合物，即使在高温高湿环境下也可以使用，而且提供具有出色光致变色性能的固化产物。其中，A和A'是具有2至15个碳原子的线性或支链烷基，"a"是1至20的平均值，当有多个A时，A可以相同或不同，R1是氢原子或甲基基团，R2是（甲基）丙烯酰氧基团或羟基。
• Photochromic composition
  申请人：TOKUYAMA CORPORATION

  公开号：EP0559439A2

  公开（公告）日：1993-09-08

  A photochromic composition comprises (A) 100 parts by weight of a compound having at least one epoxy group in the molecule and (B) 0.0001 to 10,000 parts by weight of a photochromic compound. The compound (A) is of formula wherein A is a residue of an n-valent alcoholic hydroxyl-containing compound, a residue of an n-valent phenolic-hydroxyl-containing compound, or a residue of an n-valent carboxylic acid, R1 is hydrogen or methyl and n is an integer of 1 to 4. The photochromic compounds (B) include fulgide compounds, spirooxazine compounds and chromene compounds. A polymer obtained by polymerizing the above photochromic composition of the invention by a radical polymerization method has a good durability of photochromic properties, and also possesses a dark color-forming density, a fast color fading speed, is transparent, and has a high surface hardness. Thus, especially, the polymer is suitable for use as a photochromic lens.

  一种光致变色组合物包括(A) 100 份（按重量计）分子中至少有一个环氧基团的化合物和(B) 0.0001 至 10,000 份（按重量计）光致变色化合物。化合物(A)为式 其中 A 是正价含醇羟基化合物的残余物、正价含酚羟基化合物的残余物或正价羧酸的残余物，R1 是氢或甲基，n 是 1 至 4 的整数。 光致变色化合物（B）包括富尔格化合物、螺嗪化合物和色烯化合物。通过自由基聚合法聚合上述本发明的光致变色组合物得到的聚合物具有良好的光致变色持久性，同时还具有深色成色密度、快速褪色速度、透明性和高表面硬度。因此，该聚合物尤其适合用作光致变色镜片。
• PHOTOCHROMIC CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：EP0773272A1

  公开（公告）日：1997-05-14

  A photochromic curable composition obtained by adding (E) an α-methylstyrene dimer and (F) a photochromic compound to polymerizable monomers comprising (A) a compound having at least one epoxy group in the molecule, such as glycidyl methacrylate or the like, (B) a polypropylene glycol di(meth)acrylate monomer, (C) a polyethylene glycol di(meth)acrylate monomer and (D) a (meth)acrylate monomer and/or a styryl monomer. This composition is superior in moldability when cured and gives a cured product of excellent durability in photochromism.

  如甲基丙烯酸缩水甘油酯或类似物，(B) 聚丙二醇二（甲基）丙烯酸酯单体，(C) 聚乙二醇二（甲基）丙烯酸酯单体和 (D) （甲基）丙烯酸酯单体和/或苯乙烯基单体。这种组合物在固化时具有优异的成型性，固化后的产品具有极佳的光致变色耐久性。