geranyl methacrylate | 94070-95-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: geranyl methacrylate
• 英文别名: 3,7-Dimethylocta-2,6-dienyl methacrylate；[(2E)-3,7-dimethylocta-2,6-dienyl] 2-methylprop-2-enoate
• CAS: 94070-95-8
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: DWJIEXRXQKFNAB-UKTHLTGXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916140000

反应信息

• 作为产物：
  描述：

  香叶醇 、 2,3-Butanedione monooxime methacrylate 在 porcine pancreatic lipase 作用下， 以 异丙醚 为溶剂， 反应 16.0h， 生成 geranyl methacrylate
  参考文献：
  名称：

  Lipase-catalyzed synthesis of geranyl methacrylate by transesterification: study of reaction parameters

  摘要：

  The methacrylate ester or geraniol was synthesized using various lipases, such as porcine pancreatic lipase (PPL). Candida rugosu lipase (CRL) and Pseudomonas cepacia lipase (Arnano-PS) as catalysts. The effects of reaction parameters such as type and amount of lipase, solvent. temperature and acylating agent on the conversion of geraniol to geranyl methacrylate was studied. The monomer obtained Could be used in the synthesis of controlled release pet-fume. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)00926-7

文献信息

• Photochromic composition
  申请人：——

  公开号：US20040173782A1

  公开（公告）日：2004-09-09

  A photochromic composition and a coating composition comprising a molecular compound of a chromene compound and an aromatic compound. The photochromic composition provides a photochromic optical material as a cured product and the coating composition is applied to a lens substrate and cured to provide a photochromic optical material. The above molecular compound is also provided.

  一种光致变色组合物和涂层组合物，包括一种色素化合物和一种芳香化合物的分子化合物。光致变色组合物提供一种光致变色光学材料作为固化产品，涂层组合物被应用于镜片基底并固化以提供光致变色光学材料。上述分子化合物也被提供。
• [EN] BIO-BASED MONOMERS AND POLYMERS MADE THEREFROM<br/>[FR] MONOMÈRES BIOLOGIQUES ET POLYMÈRES FABRIQUÉS À PARTIR DE CEUX-CI
  申请人：MOORE BENJAMIN & CO

  公开号：WO2022035801A1

  公开（公告）日：2022-02-17

  Disclosed herein is a frambinone methacrylate (FMA) or raspberry ketone methacrylate (RKMA) monomer having the following structure: (I), and a zingerone methacrylate (ZMA) having the following structure (II). Also disclosed are homopolymers and co-polymers utilizing same monomer. Also disclosed is a class of methacrylate monomers comprising a bio-based moiety and a reactive ketone moiety. Also disclosed are paint compositions made with a copolymer including FMA and/or ZMA.

  本文披露了一种具有以下结构的水莓酮丙烯酸甲酯（FMA）或树莓酮丙烯酸甲酯（RKMA）单体（I），以及一种具有以下结构的生姜酮丙烯酸甲酯（ZMA）（II）。还披露了利用相同单体的均聚物和共聚物。还披露了一类包含生物基团和反应性酮基团的丙烯酸甲酯单体。还披露了由包括FMA和/或ZMA的共聚物制成的涂料组合物。
• ENZYMATIC SYNTHESIS OF (METH)ACRYLIC ESTERS OF HYDROXY-FUNCTIONAL AROMAS
  申请人：Haering Dietmar

  公开号：US20100240923A1

  公开（公告）日：2010-09-23

  A process for preparing (meth)acrylic esters (F) of hydroxy-functional aromas (A), in which at least one hydroxy-functional aroma (A) in the presence of at least one enzyme (E) is esterified with (meth)acrylic acid (S), or transesterified with at least one (meth)acrylic ester (D), the reaction in the case of the transesterification being effected in the absence of solvents.

  一种制备羟基官能香气物质（A）的（甲基）丙烯酸酯（F）的过程，其中至少一种羟基官能香气物质（A）在至少一种酶（E）的存在下与（甲基）丙烯酸（S）酯化，或者与至少一种（甲基）丙烯酸酯（D）发生酯交换反应，酯交换反应在无溶剂的情况下进行。
• ADHESIVES COMPRISING CROSSLINKER WITH (METH)ACRYLATE GROUP AND OLEFIN GROUP AND METHODS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20150037526A1

  公开（公告）日：2015-02-05

  There is provided an article having a release liner and a pressure sensitive adhesive composition disposed along a major surface of the release liner, where the pressure sensitive adhesive composition has at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C 6 -C 20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl(meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C 6 -C 20 olefin group, the olefin group being optionally substituted.

  提供了一种具有放置脱离层和压敏粘合剂组成物的文章，其中压敏粘合剂组成物在脱离层的一个主要表面上具有至少50重量％的来自烷基甲基（丙烯酸酯）单体的聚合单元;以及0.2至15重量％的至少一种交联单体，包括一个（甲）丙烯酸酯基团和一个C6-C20烯烃基团，烯烃基团可选择性地被取代。在另一种实施方式中，描述了一种粘合剂组成物，其中包括糖浆，其中i）自由基聚合性溶剂单体;和ii）溶质（甲）丙烯酸聚合物，其中包括来自一个或多个烷基（甲）丙烯酸酯单体的聚合单元;其中糖浆包含至少一种交联单体或（甲）丙烯酸溶质聚合物包含来自至少一种交联单体的聚合单元，所述交联单体包括一个（甲）丙烯酸酯基团和一个C6-C20烯烃基团，烯烃基团可选择性地被取代。
• Dienyl methacrylates
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0041396A2

  公开（公告）日：1981-12-09

  Compound of the formula CH2 =C(CH3)CO2R wherein R is an alkadienyl or cycloalkadienyl group which contains the 1,3- or 1,4-diene carbon skeleton, homopolymers and copolymers of the compound, and curablefinishes containing the homopolymer and/or copolymer.

  式 CH2 =C(CH3)CO2R 其中 R 为含有 1,3- 或 1,4- 二烯碳骨架的烷二烯基或环烷二烯基的化合物、该化合物的均聚物和共聚物，以及含有该均聚物和/或共聚物的可固化面漆。