4-(2-(4-(2-hydroxyethoxy)phenyl)propan-2-yl)phenol | 2065-16-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(2-(4-(2-hydroxyethoxy)phenyl)propan-2-yl)phenol
• 英文别名: monoether of 2,2-di(p-hydroxyphenyl)propane；bisphenol A monohydroxyethyl ether；BPA-1EO；4-{2-[4-(2-Hydroxyethoxy)phenyl]propan-2-yl}phenol；4-[2-[4-(2-hydroxyethoxy)phenyl]propan-2-yl]phenol
• CAS: 2065-16-9
• 化学式: C₁₇H₂₀O₃
• 分子量: 272.344
• InChiKey: XOHLXZYRRUGMCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

安全信息

• 海关编码：
  2909500000

反应信息

• 作为反应物：
  描述：

  4-(2-(4-(2-hydroxyethoxy)phenyl)propan-2-yl)phenol 、 1-溴-3-氯丙烷 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 20.08h， 以89%的产率得到2-[4-[2-[4-(3-Chloropropoxy)phenyl]propan-2-yl]phenoxy]ethanol
  参考文献：
  名称：

  [EN] BISPHENOL DERIVATIVES AND THEIR USE AS ANDROGEN RECEPTOR ACTIVITY MODULATORS
  [FR] DÉRIVÉS DU BISPHÉNOL ET LEUR UTILISATION EN TANT QUE MODULATEURS DE L'ACTIVITÉ DU RÉCEPTEUR DES ANDROGÈNES

  摘要：

  公开号：

  WO2011082487A8
• 作为产物：
  描述：

  双酚A 在 sodium hydride 、 caesium carbonate 作用下， 以 甲醇 、 水 、 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 7.0h， 生成 4-(2-(4-(2-hydroxyethoxy)phenyl)propan-2-yl)phenol
  参考文献：
  名称：

  [EN] BISPHENOL DERIVATIVES AND THEIR USE AS ANDROGEN RECEPTOR ACTIVITY MODULATORS
  [FR] DÉRIVÉS DU BISPHÉNOL ET LEUR UTILISATION EN TANT QUE MODULATEURS DE L'ACTIVITÉ DU RÉCEPTEUR DES ANDROGÈNES

  摘要：

  公开号：

  WO2011082487A8

文献信息

• Aromatic ethers and process for producing aromatic ethers
  申请人：——

  公开号：US20040181099A1

  公开（公告）日：2004-09-16

  According to a production process, aromatic ethers are producible by reacting phenols with an oxirane compound with use of an anion exchange resin as a catalyst. According to another production process, aromatic ethers having an alcoholic hydroxyl group are producible by a crystallization-purification step of using a solvent having a solubility parameter ranging from 7.5 to 12.5 for purification by crystallization. Further, according to still another production process, producible are aromatic ethers having an alcoholic hydroxyl group, wherein the content of a metal in the aromatic ethers is less than 100 ppm by mass, and the content of a halogen element in the aromatic ethers is less than 100 ppm by mass.

  根据一个生产过程，芳香醚可通过将酚与环氧化合物反应，并使用阴离子交换树脂作为催化剂来生产。根据另一个生产过程，具有醇羟基的芳香醚可通过结晶纯化步骤，使用溶剂进行结晶纯化，其溶解度参数范围为7.5至12.5进行生产。此外，根据另一个生产过程，可生产具有醇羟基的芳香醚，其中芳香醚中金属的含量小于100ppm，卤素元素的含量小于100ppm。
• Process for producing bis-alkoxylated diols of bisphenol a from spent polycarbonate discs(PC) or PC waste
  申请人：Dai Shenghong A.

  公开号：US20080255395A1

  公开（公告）日：2008-10-16

  This invention provides one-pot reaction for digesting polycarbonate waste with alkylene glycol in the presence of a basic catalyst at 180° C. under normal atmospheric pressure. The digested product mixture was found to consist of bisphenol A (BPA) and monoalkoxylated and bisalkoxylated diols of BPA. Alkoxylation of BPA and monoalkoxylated diols of BPA is performed by adding urea or urea derivative (or carbonic acid ester or amine ester) to the digested product mixture at a high temperature under normal atmospheric pressure to obtain the final product, i.e., bisalkoxylated diols of BPA in high yield. The bisalkoxylated diols of BPA may be used as raw materials to synthesize polymer such as polyurethane (PU) or polyester.

  这项发明提供了一种单锅反应，通过在常规大气压下，在碱性催化剂的存在下，用烷基二醇消化聚碳酸酯废料，在180°C下进行。发现消化产物混合物由双酚A（BPA）和BPA的单烷氧基化和双烷氧基化二元醇组成。通过在高温下，在常规大气压下向消化产物混合物中添加尿素或尿素衍生物（或碳酸酯或胺酯），进行BPA和单烷氧基化二元醇的烷氧基化，以获得最终产物，即高收率的BPA的双烷氧基化二元醇。BPA的双烷氧基化二元醇可用作合成聚氨酯（PU）或聚酯等聚合物的原材料。
• Fiber-reinforced composite material and process for the production thereof
  申请人：TEIJIN LIMITED

  公开号：EP0505139A1

  公开（公告）日：1992-09-23

  A process for the production of a fiber-reinforced composite material, which comprises the steps of (1) preparing a polymeric composition containing a substantially linear aromatic oligomer having a terminal aliphatic hydroxyl group, bis(acylcaprolactam) and a catalyst which promotes a ring opening-addition reaction of a hydroxyl group and a caprolactam ring, (2) melting the polymeric composition and impregnating it into a fibrous reinforcing material to form a impregnated product, and (3) heating the impregnated product up to a temperature sufficient to open the caprolactam ring while inhibiting elimination of caprolactam thereby to form, as a matrix resin, a thermoplastic copolymer having an ester group and an amide group in its main chain; and a fiber-reinforced composition material produced by the above-mentioned process.

  一种生产纤维增强复合材料的工艺，包括以下步骤 (1) 制备一种聚合物组合物，该组合物含有一种具有末端脂肪族羟基的基本线性芳香族低聚物、双（酰基己内酰胺）和一种催化剂，该催化剂可促进羟基和己内酰胺环的开环加成反应、 (2) 熔化聚合物组合物并将其浸渍到纤维增强材料中，形成浸渍产品，以及 (3) 将浸渍产品加热到足以打开己内酰胺环的温度，同时抑制己内酰胺的消除，从而形成主链上具有酯基和酰胺基的热塑性共聚物，作为基体树脂； 以及由上述工艺生产的纤维增强组合材料。
• RESIN COMPOSITION FOR LASER-ENGRAVABLE FLEXOGRAPHIC PRINTING PLATE, ORIGINAL PLATE FOR LASER-ENGRAVABLE FLEXOGRAPHIC PRINTING PLATE AND METHOD FOR PRODUCTION THEREOF, AND FLEXOGRAPHIC PRINTING PLATE AND METHOD FOR PRODUCTION THEREOF
  申请人：Fujifilm Corporation

  公开号：EP2810784A1

  公开（公告）日：2014-12-10

  To provide a resin composition for a laser-engravable flexographic printing plate that has excellent removability for engraving residue generated when laser-engraving a printing plate precursor and that can give a flexographic printing plate that is excellent in terms of non-tackiness, hardness, printing durability, and halftone shape. A resin composition for a laser-engravable flexographic printing plate, the resin composition that comprises (Component A) a polyurethane resin having a group represented by Formula (1), (Component B) an ethylenically unsaturated compound, and (Component C) a polymerization initiator wherein in the Formula, R and R" independently denote a hydrogen atom or an alkyl group, R' denotes an alkyl group, R and R' may be linked to form a ring, and the wavy line portion denotes the position of bonding.

  提供一种用于激光雕刻柔性版印刷版的树脂组合物，该树脂组合物对激光雕刻印刷版前体时产生的雕刻残留物具有极佳的去除性，并能获得在不粘性、硬度、印刷耐久性和半色调形状方面都很出色的柔性版印刷版。 一种用于激光雕刻柔性版印刷版的树脂组合物，该树脂组合物包括（成分 A）具有式（1）所代表基团的聚氨酯树脂、（成分 B）乙烯基不饱和化合物和（成分 C）聚合引发剂。 式中，R 和 R "分别表示氢原子或烷基，R'表示烷基，R 和 R'可连接成环，波浪线部分表示键合位置。
• Curable benzoxazine compositions with improved thermal stability
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US10023698B2

  公开（公告）日：2018-07-17

  A curable benzoxazine composition is described wherein the benzoxazine is derived from an aryl amine having a b.p.>200° C. The curable compositions are more thermally stable and have reduced weight loss and by-products upon cure.

  描述了一种可固化的苯并恶嗪组合物，其中的苯并恶嗪由芳基胺衍生而来，其 b.p.>200° C。