9-[10-(9-Hydroxyfluoren-9-yl)anthracen-9-yl]fluoren-9-ol | 1414773-45-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-[10-(9-Hydroxyfluoren-9-yl)anthracen-9-yl]fluoren-9-ol
• 英文别名: 9-[10-(9-hydroxyfluoren-9-yl)anthracen-9-yl]fluoren-9-ol
• CAS: 1414773-45-7
• 化学式: C₄₀H₂₆O₂
• 分子量: 538.645
• InChiKey: YGDAZAVIJRHHJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  42
• 可旋转键数：
  2
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-[10-(9-Hydroxyfluoren-9-yl)anthracen-9-yl]fluoren-9-ol 在 tin(ll) chloride 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  意外的机械变色双三环芳烃的合成与表征

  摘要：

  摘要在氯化锡（II）介导的还原性芳构化反应中合成了意想不到的双三环芳烃AF。如X射线晶体学所揭示的，所获得的AF显示出高度拥挤的结构构象。有趣的是，AF在浅色和红色之间表现出可逆的高对比度机械变色和热变色。明显的色差很可能归因于刺激后构象转变和痕量双自由基种类的形成。

  DOI：

  10.1016/j.cclet.2020.02.010
• 作为产物：
  描述：

  9-芴酮 、 9,10-二溴蒽 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 49.0h， 以31%的产率得到9-[10-(9-Hydroxyfluoren-9-yl)anthracen-9-yl]fluoren-9-ol
  参考文献：
  名称：

  具有蒽和 9-芴醇单元组合的新型二醇主体的结晶包合物

  摘要：

  已经合成了二醇主体化合物 2，并与类似的乙炔间隔主体化合物 1 进行了比较，讨论了其形成结晶包合物的行为。溶液 NMR 光谱表明，围绕 2 中芴醇 - 蒽键的旋转受到高度限制。力学和半经验计算。2 与 1-BuOH (2a)、吗啉/H2O (2b) 和 DMSO (2c) 的包合物的单晶 X 射线结构与计算建议的蒽环系统的弯曲几何形状一致。这些结构表现出特定的氢键相互作用模式。

  DOI：

  10.1080/10610278.2012.701301

文献信息

• METHOD FOR CONTROLLING CROSS-LINKING REACTION RATE AND OF A CROSS-LINKING COMPOUND
  申请人：Delsper LP

  公开号：EP3916035A1

  公开（公告）日：2021-12-01

  The invention includes a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive oligomer intermediate, which is capable of cross-linking an organic polymer. Also included is an organic polymer composition for use in forming a crosslinked organic polymer, comprising a cross-linking compound of Formula (IV), a cross-linking reaction additive and at least one organic polymer. In one embodiment, the at least one organic polymer has at least one halogen-containing reactive group and is dehalogenated by reacting with an alkali metal compound. Methods for making such compositions as well as articles of manufacture formed from such methods and organic polymer compositions, wherein the compositions and methods control the cross-linking reaction rate of a crosslinking compound for use in cross-linking an organic polymer are also included.

  本发明包括一种交联组合物，该组合物包含一种交联化合物和一种交联反应添加剂，交联反应添加剂选自有机酸和/或醋酸盐化合物，其中交联化合物具有式（IV）所述结构： 其中交联反应添加剂能与交联化合物反应形成反应性低聚物中间体，该中间体能交联有机聚合物。还包括一种用于形成交联有机聚合物的有机聚合物组合物，该组合物由式（IV）的交联化合物、交联反应添加剂和至少一种有机聚合物组成。在一个实施方案中，至少一种有机聚合物具有至少一个含卤反应基团，并通过与碱金属化合物反应脱卤。还包括制造这种组合物的方法以及由这种方法和有机聚合物组合物形成的制造品，其中组合物和方法控制用于交联有机聚合物的交联化合物的交联反应速率。
• CROSSLINKING COMPOUNDS FOR HIGH GLASS TRANSITION TEMPERATURE POLYMERS
  申请人：Greene, Tweed & Co.

  公开号：EP2780392B1

  公开（公告）日：2016-06-29
• CROSS-LINKED ORGANIC POLYMER COMPOSITIONS
  申请人：Delsper LP

  公开号：EP2909253B1

  公开（公告）日：2021-11-10
• Anti-Extrusion Compositions for Sealing and Wear Components
  申请人：Delsper LP

  公开号：US20140213742A1

  公开（公告）日：2014-07-31

  A method and compositions are described which improve extrusion- and creep-resistance of components for use in a high temperature applications including sealing elements and seal connectors among others. The method includes providing a composition having an aromatic polymer and a crosslinking compound, and subjecting the composition to a heat molding process to form the component and crosslink the aromatic polymer.
• Cross-Linked Organic Polymer Compositions and Methods for Controlling Cross-Linking Reaction Rate and of Modifying Same to Enhance Processability
  申请人：Delsper LP

  公开号：US20140284850A1

  公开（公告）日：2014-09-25

  The invention includes a cross-linking composition comprising a cross-linking compound and a cross-linking reaction additive selected from an organic acid and/or an acetate compound, wherein the cross-linking compound has the structure according to formula (IV): wherein the cross-linking reaction additive is capable of reacting with the cross-linking compound to form a reactive oligomer intermediate, which is capable of cross-linking an organic polymer. Also included is an organic polymer composition for use in forming a cross-linked organic polymer, comprising a cross-linking compound of Formula (IV), a cross-linking reaction additive and at least one organic polymer. In one embodiment, the at least one organic polymer has at least one halogen-containing reactive group and is dehalogenated by reacting with an alkali metal compound. Methods for making such compositions as well as articles of manufacture formed from such methods and organic polymer compositions, wherein the compositions and methods control the cross-linking reaction rate of a crosslinking compound for use in cross-linking an organic polymer are also included.