CF3(CF2)3(CH2CF2)(CF2CF2)2(CH2CH2)OCOCH=CH2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: CF3(CF2)3(CH2CF2)(CF2CF2)2(CH2CH2)OCOCH=CH2
• 英文别名: Acrylic acid 3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluorododecyl ester；3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluorododecyl prop-2-enoate
• 化学式: C₁₅H₉F₁₉O₂
• 分子量: 582.205
• InChiKey: WUQRQABDZOBXDA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  36
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为产物：
  描述：

  3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluorododecanol 、 丙烯酸 在 对甲苯磺酸 、 对苯二酚 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以86.4%的产率得到CF3(CF2)3(CH2CF2)(CF2CF2)2(CH2CH2)OCOCH=CH2
  参考文献：
  名称：

  POLYFLUOROALKYL ALCOHOL OR (METH)ACRYLIC ACID DERIVATIVE THEREOF, AND THEIR PRODUCTION METHODS

  摘要：

  公开号：

  EP1995228B1

文献信息

• FLUORINATED MACROINITIATOR AND METHOD FOR PRODUCING SAME
  申请人：Unimatec Co., Ltd.

  公开号：EP3088425A1

  公开（公告）日：2016-11-02

  The object of the present invention is to provide a fluorine-containing macroinitiator, particularly a fluorine-containing macroinitiator that enables production of a fluorine-containing block copolymer containing a non-fluorine vinyl-based monomer having a long side chain. The fluorine-containing macroinitiator of the present invention comprises a polymer represented by the following formula (1) and having a number-average molecular weight of 3, 000 to 100,000. In the following formula (1), R2, R3 and R4 are each a specific group, and Q is a polymer segment composed of a structural unit represented by the following formula (2). In the following formula (2), R1 is a hydrogen atom or a methyl group, Rf is a fluoroalkyl group having a specific structure, and k is an appropriate integer that is not 0.

  本发明的目的是提供一种含氟大引发剂，特别是一种能够生产含有具有长侧链的非氟乙烯基单体的含氟嵌段共聚物的含氟大引发剂。本发明的含氟大引发剂包括由下式（1）表示的聚合物，其数均分子量为 3,000 至 100,000。在下式（1）中，R2、R3 和 R4 各为一个特定基团，Q 是由下式（2）所代表的结构单元组成的聚合物段。在下式（2）中，R1 是氢原子或甲基，Rf 是具有特定结构的氟烷基，k 是不为 0 的适当整数。
• Fluorine-containing diblock copolymer
  申请人：Unimatec Co., Ltd.

  公开号：US10196473B2

  公开（公告）日：2019-02-05

  Provided is a fluorine-containing diblock copolymer having good water and oil repellency by using, as a raw material, a fluorine-containing (meth)acrylic ester having low bioaccumulation potential. The fluorine-containing diblock copolymer is produced by: process (A) a process for producing a fluorine-containing diblock copolymer by polymerizing a fluorine-containing (meth)acrylic ester represented by the following formula (1) in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a non-fluorine vinyl-based monomer, or process (B) a process for producing a fluorine-containing diblock copolymer by polymerizing a non-fluorine vinyl-based monomer in the presence of a trithiocarbonic ester compound and a radical polymerization initiator and then polymerizing a fluorine-containing (meth)acrylic ester represented by the following formula (1).

  本发明提供了一种含氟二嵌段共聚物，它以生物蓄积性低的含氟（甲基）丙烯酸酯为原料，具有良好的拒水拒油性能。含氟二嵌段共聚物是通过以下方法生产的：工艺 (A) 在三硫代碳酸酯化合物和自由基聚合引发剂存在下，通过聚合下式 (1) 所代表的含氟（甲基）丙烯酸酯，然后聚合无氟乙烯基单体，生产含氟二嵌段共聚物的工艺、或工艺 (B) 在三硫代甲酸酯化合物和自由基聚合引发剂存在下，聚合无氟乙烯基单体，然后聚合下式 (1) 所代表的含氟（甲基）丙烯酸酯，从而生产含氟二嵌段共聚物的工艺。
• COMPOSITION FOR LITHOGRAPHIC PRINTING PLATE AND LITHOGRAPHIC PRINTING PLATE PRECURSOR
  申请人：EASTMAN KODAK COMPANY

  公开号：US20150198884A1

  公开（公告）日：2015-07-16

  The present invention has an objective of providing a composition for a lithographic printing plate, which provides an image-forming layer exhibiting superior ink receptivity and uniformity, and in which a coating solution containing the composition possesses a good defoaming property and can effectively form an image-forming layer at high speed. In addition, the present invention has another objective of providing a lithographic printing plate precursor or a dummy plate which can be produced at high speed with superior production efficacy. The present invention provides a composition for a lithographic printing plate containing a fluoroaliphatic group-containing copolymer having a specific chemical structure, the lithographic printing plate precursor or a dummy plate containing a layer having the aforementioned composition.
• Fluorine-Containing Macroinitiator and Production Process for the Same
  申请人：UNIMATEC CO., LTD.

  公开号：US20160340448A1

  公开（公告）日：2016-11-24

  Provided is a fluorine-containing macroinitiator, particularly a fluorine-containing macroinitiator that enables production of a fluorine-containing block copolymer containing a non-fluorine vinyl-based monomer having a long side chain. The fluorine-containing macroinitiator includes a polymer represented by the following formula (1) and having a number-average molecular weight of 3,000 to 100,000. In the following formula (1), R 2 , R 3 and R 4 are each a specific group, and Q is a polymer segment composed of a structural unit represented by the following formula (2). In the following formula (2), R 1 is a hydrogen atom or a methyl group, Rf is a fluoroalkyl group having a specific structure, and k is an appropriate integer that is not 0.
• US9470977B2
  申请人：——

  公开号：US9470977B2

  公开（公告）日：2016-10-18