[Pd(diethyldithiocarbamate)₂] | 15170-78-2

• 分子结构分类: 有机化合物
• 英文名称: [Pd(diethyldithiocarbamate)₂]
• 英文别名: [Pd(dedtc)₂]；[Pd(S₂CNEt₂)₂]；[Pd(κ²-diethyl dithiocarbamate)₂]；[Pd(κ²-Et₂DT)₂]；palladium(II) bis(diethyldithiocarbamate)；bis(diethyldithiocarbamate)palladium(II)；Pd(N,N-diethyldithiocarbamate)2；Pd(II) diethyldithiocarbamate；Pd(detc)2；bis(diethyldithiocabamato)palladium(II)；[Pd(diethylthiocarbamate)]；Palladium(II) diethyldithiocarbamate；N,N-diethylcarbamodithioate;palladium(2+)
• CAS: 15170-78-2
• 化学式: C₁₀H₂₀N₂PdS₄
• 分子量: 402.966
• InChiKey: DFOAWZQWPBCJKW-UHFFFAOYSA-L

物化性质

• 熔点：
  225-226 °C

计算性质

• 辛醇/水分配系数(LogP)：
  2.32
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  72.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [Pd(diethyldithiocarbamate)₂] 在 氰化钠 作用下， 以 甲醇 为溶剂， 生成 tetracyanopalladate(II)
  参考文献：
  名称：

  方形三平面镍中三方形镍的二硫代氨基甲酸酯和二硫代磷酸酯络合物的取代反应速率和机理

  摘要：

  对于镍的正方形平面二硫代二硫代氨基甲酸和复合物的取代反应速率常数II，钯II，和Pt II，与乙二胺和氰化物离子作为亲核体，都在甲醇中测量了在0.1摩尔分米的离子强度-3高氯酸钠。提出了一种通用机制来解释动力学数据。复合物的反应活性的次序是大约镍：钯：PT = 10 5：10 3：1将其结果与在以前的调查获得的那些比较，在五共纵轴物种的稳定性方面被解释在取代之前形成的。

  DOI：

  10.1039/dt9770002281
• 作为产物：
  描述：

  chlro(di(1-naphthyl)methylarsine)(diethyldithiocarbamate)palladium(II) 以 not given 为溶剂， 生成 [Pd(diethyldithiocarbamate)₂]
  参考文献：
  名称：

  Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)

  摘要：

  Dinaphthylmethylarsine complexes of palladium(II) and platinum(II) with the formulae [MX2L2] (M = Pd, Pt; L = di(I-naphthyl)methylarsine = NaP2AsMe and X = Cl, Br, I), [M2Cl2(mu-Cl)(2)L-2], [PdCl(S2CNEt2)L], [Pd2Cl2(mu-OAc)(2)L-2] and [MCl2(PR3)L] (PR3 = PEt3, PPr3, PBu3, PMePh2) have been prepared. These complexes have been characterized by elemental analyses, IR, Raman, NMR (H-1, C-13, P-31) and UV-vis spectroscopy. The stereochemistry of the complexes has been deduced from the spectroscopic data. The crystal structures of trans-[PdCl2(PEt3)(NaP2AsMe)] and of [Pd(S2CNEt2)(2)], a follow-up product, were determined. The UV-vis spectra of [MX2L2] complexes show a red shift on going from X = Cl to X = L The complexes [PdX2L2] and [PtX2L2] are strongly luminescent in fluid solution and in the solid at ambient temperature. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.03.026
• 作为试剂：
  描述：

  7,8-苯并喹啉 、 异丙醇 在 [Pd(diethyldithiocarbamate)₂] 、 碘苯二乙酸 作用下， 以 溶剂黄146 为溶剂， 反应 24.0h， 以99%的产率得到10-isopropoxybenzo[h]quinoline
  参考文献：
  名称：

  从回收的金属废料到高性能的钯催化剂

  摘要：

  描述了基于二硫代氨基甲酸酯和二硫代草酰胺S，S-给体配体的一系列中性和阳离子，均配和杂配，单金属和双金属钯（II）化合物的催化活性。在苯并[的区域选择性和化学选择性的C-H官能化，观察到高活性ħ ]喹啉〜10 alkoxybenzo [ ħ ]喹啉和8-甲基喹啉以8-（甲氧基甲基）在氧化剂是Phl的存在喹啉（OAC ）2。发现[Pd（Me 2 dazdt）2 ] I 6（Me 2 dazdt = N，N'-二甲基-过氢二氮杂-2,3-二硫酮），[PdI 2（Me2 dazdt）]和[Pd（Cy 2 DTO） 2 ] I 8（Cy 2 DTO = N， N'-（二环己基-二硫代草酰胺），都是作为可持续Pd-金属浸出过程的产品直接获得的，该浸出过程用于从废金属中回收钯。这些化合物在较温和的条件（50°C，1-3 mol％Pd负载）下提供了几乎定量的产率，并且反应时间（1-3 h）比以前报道的要

  DOI：

  10.1039/c7gc02678a

文献信息

• Cytotoxicity, anti‐microbial studies of M( <scp>II</scp> )‐dithiocarbamate complexes, and molecular docking study against <scp>SARS COV2 RNA</scp> ‐dependent <scp>RNA</scp> polymerase
  作者：Ahmed S. M. Al‐Janabi、Abdulrahman M. Saleh、Mohammad R. Hatshan

  DOI：10.1002/jccs.202000504

  日期：——

  typhimurium bacteria. The cytotoxicity of the Pd(II) and Pt(II) complexes was screened against the MCF-7 breast cancer cell line and the complexes showed moderate activity compared with the cis-platin. The results indicated that the MCF7 cells treated with 500 μg\ml of ligands and Pd(II) and Pt(II) complexes after 24 hr exposure showed intercellular space and dead cells. Finally, molecular docking studies were

  十种类型为 [M( κ 2 -Et 2 DT) 2 ] ( 1–5 ) 和 [M( κ 2 -PyDT) 2 ] ( 6–10 ) 的过渡金属二硫代氨基甲酸盐 (DTC) 配合物（其中 M = Co 、Ni、Cu、Pd 和 Pt；Et 2 DT = 二乙基二硫代氨基甲酸酯；PyDT = 吡咯烷二硫代氨基甲酸酯）通过不同的方法进行合成和表征。二硫代氨基甲酸盐充当双齿螯合配体，与Co(II)离子形成四面体络合物，并与其他过渡金属离子形成方形平面络合物。二硫代氨基甲酸盐复合物对病原体细菌表现出良好的活性。结果表明，Pt-二硫代氨基甲酸盐复合物对所有测试细菌的活性均高于 Pd-二硫代氨基甲酸盐复合物。二硫代氨基甲酸盐复合物对大肠杆菌表现出最大的抑制区，而二硫代氨基甲酸盐对鼠伤寒沙门氏菌的活性最低。Pd(II) 和 Pt(II) 复合物针对 MCF-7 乳腺癌细胞系的细胞毒性进行了筛选，与顺铂相比，
• Metal complexes of sulphur ligands. Part 14. Reaction of palladium(II) and platinum(II) dithioacid complexes with tertiary phosphinites, and the crystal and molecular structure of dimethylphosphinodithioato(diphenylphosphinito)(diphenylphosphinous acid)palladium(II)
  作者：Margaret C. Cornock、Robert O. Gould、C. Lynn Jones、T. Anthony Stephenson

  DOI：10.1039/dt9770001307

  日期：——

  groups with O ⋯ O 2.41 Å. Similar complexes [M(S–S)(PPh2O)PPh2(OH)}](M = Pd, S–S–=[S2PPh2]– or [S2CNEt2]–; M = Pt, S–S–=[S2PMe2]– or [S2CNEt2]–) have been prepared by reaction of [M(S–S)2] with PPh2(OR) or, for M = Pd, by reaction of [PdCl(PPh2O)[PPh2(OH)]}2] with the appropriate dithioacid anion (1 : 2 molar ratio). A careful study of the [Pt(S2CNEt2)2]–PPh2(OMe) reaction has resulted in the isolation

  [Pd（S 2 PMe 2）2 ]与过量的PPh 2（OR）（R = Me或Et）在二氯甲烷或苯中的长时间反应，得到四配位络合物[Pd（S 2 PMe 2）（光谱证据和X射线结构分析表明，PPh 2 O）PPh 2（OH）}]（1a）含有对称氢键合的Ph 2 POHOPPh 2配体。（1a）的晶体是单斜晶体，空间群P 2 1 / m，a = 6.86（1），b = 22.12（2），c＝ 9.69（1）,，β＝ 111.5（2）°。酸性氢原子用O di O 2.41Å连接两个等效的二苯基亚膦酸酯基团。相似的配合物[M（S–S）（PPh 2 O）PPh 2（OH）}] [M = Pd，S–S – = [S 2 PPh 2 ] –或[S 2 CNEt 2 ] – ; M = Pt，S–S – = [S 2 PMe 2 ] –或[S 2 CNEt 2 ] –）是通过[M（S–S）2 ]与PPh
• Kinetic Studies of Fast Equilibrium by Means of High-performance Liquid Chromatography. IV. Separation of Rotamers of Palladium(II) Dithiocarbamates
  作者：Masataka Moriyasu、Yohei Hashimoto、Masaru Endo

  DOI：10.1246/bcsj.56.1972

  日期：1983.7

  unsymmetrical palladium(II) dithiocarbamate chelates has been investigated by high-performance liquid chromatography. At higher temperatures, the rotation is so rapid that two rotamers have not been distinguished, and a single sharp peak has appeared on chromatograms, whereas at lower temperatures, they have been separated. The activation energy of the rotation of palladium(II) dithiocarbamate (ΔH\eweq=83±5

  通过高效液相色谱研究了不对称二硫代氨基甲酸钯 (II) 螯合物的碳氮键旋转受限。在较高温度下，旋转速度非常快，以至于无法区分两个旋转异构体，色谱图上出现了一个尖峰，而在较低温度下，它们已被分离。二硫代氨基甲酸钯 (II) 旋转的活化能 (ΔH\eweq=83±5 kJ mol-1 for Pd(C6H5CH2CH2NHCSS)2) 小于通常的双键旋转能垒值，但大于那些旋转单键。
• Emitting-state properties of square-planar dithiocarbamate complexes of palladium(II) and platinum(II) probed by pressure-dependent luminescence spectroscopy
  作者：Caroline Genre、Geneviève Levasseur-Thériault、Christian Reber

  DOI：10.1139/v09-132

  日期：2009.11

  Temperature- and pressure-dependent Raman and luminescence spectra of four crystalline complexes of palladium(II) and platinum(II) with chelating diethyldithiocarbamate (EDTC) and pyrrolidine-N-dithiocarbamate (PDTC) ligands are reported. The crystal structure of [Pd(PDTC)₂] was resolved at 120 K. Luminescence band maxima are observed at approximately 14 500 cm^–1and 16 000 cm^–1for the palladium(II) and platinum(II) complexes, respectively. Pressure leads to blue shifts of the band maxima by +9 and +13 cm^–1/kbar for [Pd(EDTC)₂] and [Pd(PDTC)₂], and +15 cm^–1/kbar for [Pt(EDTC)₂]. These spin-forbidden d–d luminescence transitions have lifetimes of approximately 600 µs at temperatures below 20 K. Luminescence intensities at room temperature are low, but they increase significantly with external pressure. The experimental results show that strong increases of luminescence intensities caused by pressure are not limited to complexes with monodentate ligands, a result providing insight on the coordinates with emitting-state distortions responsible for this effect.

  报告了钯(II)和铂(II)与螯合二乙基二硫代氨基甲酸乙酯(EDTC)和吡咯烷-N-二硫代氨基甲酸乙酯(PDTC)配体的四种晶体配合物的温度和压力依赖性拉曼光谱和发光光谱。钯（II）和铂（II）配合物的发光带最大值分别约为 14 500 cm-1 和 16 000 cm-1。压力导致[Pd(EDTC)2]和[Pd(PDTC)2]的发光带最大值发生了+9 和 +13 cm-1/kbar 的蓝移，[Pt(EDTC)2]的发光带最大值发生了+15 cm-1/kbar 的蓝移。这些自旋禁止的 d-d 发光转变在温度低于 20 K 时的寿命约为 600 µs。实验结果表明，由压力引起的发光强度的强烈增加并不局限于具有单齿配体的配合物，这一结果为我们了解造成这种效应的发射态畸变坐标提供了启示。
• Structures of a novel trinuclear palladium(II) dithiocarbamate complex and of bis(diethyldithiocarbamato)dibromopalladium(IV)
  作者：Alexander J Blake、Poopathy Kathirgamanathan、Michael J Toohey

  DOI：10.1016/s0020-1693(99)00521-6

  日期：2000.5

  Abstract Determination of the crystal structure of bis(diethyldithiocarbamato)dibromopalladium(IV) ( I ), shows it to have a distorted octahedral geometry, with the bromide ligands mutually cis . We also report the structure of a new palladium(II) complex, obtained as a decomposition product in the crystallisation of I , which has three palladium centres coordinated by bridging and terminal dithiocarbamates

  摘要测定双（二乙基二硫代氨基甲酸酯）二溴钯（IV）的晶体结构（I），表明其具有扭曲的八面体几何形状，且溴化物配体互为顺式。我们还报告了一种新的钯（II）配合物的结构，该配合物是I的结晶中的分解产物，该配合物具有通过桥接和末端二硫代氨基甲酸酯配位的三个钯中心。