3-(methylthio)-4-bromomethyl-2,5-diphenyl-furan

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 呋喃
• 英文名称: 3-(methylthio)-4-bromomethyl-2,5-diphenyl-furan
• 英文别名: 3-(Bromomethyl)-4-methylsulfanyl-2,5-diphenylfuran；3-(bromomethyl)-4-methylsulfanyl-2,5-diphenylfuran
• 化学式: C₁₈H₁₅BrOS
• 分子量: 359.286
• InChiKey: NAFOFWOFJHANBX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  38.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(methylthio)-4-bromomethyl-2,5-diphenyl-furan 在 potassium carbonate 作用下， 以 二甲基亚砜 、 乙腈 为溶剂， 反应 3.0h， 生成
  参考文献：
  名称：

  A new fluorescence chemosensor for selective detection of copper ion in aqueous solution

  摘要：

  A new fluorescent chemosensor based upon 2,5-diphenylfuran and di(2-picolyl)amine (DPA) was designed and synthesized. Its structure was confirmed by single crystal X-ray diffraction and its photo physical properties were studied by absorption and fluorescence spectra. This compound can be used to determine Cu2+ ion with high selectivity among a series of cations in aqueous DMSO. This sensor forms a 1:1 complex with Cu2+ and displays fluorescent quenching. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2016.04.025
• 作为产物：
  描述：

  2-(methylthio)-1,4-diphenylbut-2-ene-1,4-dione 在 盐酸 、 氢溴酸 、 溶剂黄146 、 tin(ll) chloride 作用下， 以 水 为溶剂， 生成 3-(methylthio)-4-bromomethyl-2,5-diphenyl-furan
  参考文献：
  名称：

  A Highly Selective Fluorescent Sensor for Al³⁺ based on an Aza-18-Crown-6 Derivative

  摘要：

  我们合成了一种由 2,5-二苯基呋喃和氮杂-18-冠醚-6 衍生的新型荧光传感器。它能在乙醇溶液中选择性地结合 Al3+，并能增强荧光。

  DOI：

  10.3184/174751915x14425101743684

文献信息

• A new fluorescent chemosensor for Fe3+ based upon 2,5-diphenylfuran and 8-hydroxyquinoline
  作者：Shengli Hu、Gongying Wu、Caihua Xu、Jinghua Dong、Qing Gao

  DOI：10.1016/j.jphotochem.2013.07.009

  日期：2013.10

  A new fluorescent chemosensor based upon 2,5-diphenylfuran and 8-hydroxyquinoline was designed and synthesized. Its structure was confirmed by single crystal X-ray diffraction and its photophysical properties were studied by absorption and fluorescence spectra. This compound can be used to determine Fe3+ ion with high selectivity among a series of cations in aqueous DMF. This sensor forms a 1:1 complex

  设计并合成了一种基于2，5-二苯呋喃和8-羟基喹啉的新型荧光化学传感器。通过单晶X射线衍射证实了其结构，并通过吸收和荧光光谱研究了其光物理性质。该化合物可用于在DMF水溶液中的一系列阳离子中以高选择性测定Fe 3+离子。该传感器与Fe 3+形成1：1的络合物并显示荧光猝灭。
• A Highly Selective Fluorescent Sensor for Al³⁺ based on an Aza-18-Crown-6 Derivative
  作者：Song Jingjing、Hu Yang、Zhao Fang、Hu Shengli

  DOI：10.3184/174751915x14425101743684

  日期：2015.10

  A new fluorescent sensor derived from 2,5-diphenyl-furan and aza-18-crown-6 has been synthesised. It can selectively bind Al³⁺ in aqeuous ethanol solution with fluorescence enhancement.

  我们合成了一种由 2,5-二苯基呋喃和氮杂-18-冠醚-6 衍生的新型荧光传感器。它能在乙醇溶液中选择性地结合 Al3+，并能增强荧光。
• A new fluorescence chemosensor for selective detection of copper ion in aqueous solution
  作者：Yang Hu、Qian Ke、Chang Yan、Cai-Hua Xu、Xiao-Huan Huang、Sheng-li Hu

  DOI：10.1016/j.tetlet.2016.04.025

  日期：2016.5

  A new fluorescent chemosensor based upon 2,5-diphenylfuran and di(2-picolyl)amine (DPA) was designed and synthesized. Its structure was confirmed by single crystal X-ray diffraction and its photo physical properties were studied by absorption and fluorescence spectra. This compound can be used to determine Cu2+ ion with high selectivity among a series of cations in aqueous DMSO. This sensor forms a 1:1 complex with Cu2+ and displays fluorescent quenching. (C) 2016 Elsevier Ltd. All rights reserved.