二乙基1-环己烯-1,2-二羧酸酯 | 92687-41-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 二乙基1-环己烯-1,2-二羧酸酯
• 英文名称: cyclohex-1-ene-1,2-dicarboxylic acid diethyl ester
• 英文别名: Cyclohex-1-en-1,2-dicarbonsaeure-diaethylester；Diethyl cyclohex-1-ene-1,2-dicarboxylate；diethyl cyclohexene-1,2-dicarboxylate
• CAS: 92687-41-7
• 化学式: C₁₂H₁₈O₄
• 分子量: 226.273
• InChiKey: NUJPHNDDJUTHKM-UHFFFAOYSA-N

物化性质

• 沸点：
  327.88°C (rough estimate)
• 密度：
  1.0803

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2917209090

反应信息

• 作为反应物：
  描述：

  二乙基1-环己烯-1,2-二羧酸酯 、 sodium dodecyl-sulfate 、 alkaline earth salt of/the/ methylsulfuric acid 生成 3,4,5,6-四氢邻苯二甲酸 、 环己-2-烯-1,2-二羧酸
  参考文献：
  名称：

  The Chlorination of cis- and trans-Diethyl Hexahydrophthalates¹

  摘要：

  DOI：

  10.1021/ja01868a001
• 作为产物：
  描述：

  顺-1,2-环己烷二羧酸二乙酯 在 四氯化碳 、 磺酰氯 、 过氧化苯甲酰 作用下， 生成 二乙基1-环己烯-1,2-二羧酸酯
  参考文献：
  名称：

  The Chlorination of cis- and trans-Diethyl Hexahydrophthalates¹

  摘要：

  DOI：

  10.1021/ja01868a001

文献信息

• OLEFIN POLYMERIZATION CATALYST, PROCESS FOR PRODUCING OLEFIN POLYMER, POLYPROPYLENE RESIN COMPOSITION AND ARTICLE COMPRISING THE SAME
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20130109789A1

  公开（公告）日：2013-05-02

  An olefin polymerization catalyst is obtained by bringing the following components (A), (B) and (C) into contact with one another: (A) a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom and a halogen atom; (B) an organoaluminum compound; and (C) a triether represented by formula (I). An olefin polymerization solid catalyst can be provided having a sufficiently high polymerization activity and an ability to produce an olefin polymer with a low content of low-molecular weight components and amorphous components.

  一种烯烃聚合催化剂是通过将以下组分（A）、（B）和（C）彼此接触而获得的：（A）用于烯烃聚合的固体催化剂组分，其中包含钛原子、镁原子和卤素原子；（B）有机铝化合物；以及（C）由式（I）表示的三醚。可以提供具有足够高的聚合活性和能够产生低分子量成分和非晶态成分含量低的烯烃聚合物的固体聚合催化剂。
• Catalyst composition for use in the polymerization of olefins
  申请人：MITSUI PETROCHEMICAL INDUSTRIES, LTD.

  公开号：EP0115195A1

  公开（公告）日：1984-08-08

  A catalyst composition composed of (A) a magnesium-containing solid titanium catalyst component, containing as essential ingredients, magnesium, titanium, a halogen and an electron donor selected from a cyclic mono- or poly-ester (a), (b), (c), (d), (e) and (f) as specified in the claims, (B) an organoaluminium compound catalyst component, and (C) an organic silicon compound catalyst component having an Si-O-C or Si-N-C bond is useful in the production of olefin polymers by the polymerization of at least one olefin and optionally at least one diolefin.

  一种催化剂组合物，其组成包括(A)含镁固体钛催化剂组分，其基本成分为镁、钛、卤素和电子供体，电子供体选自权利要求中所述的环状单酯或聚酯(a)、(b)、(c)、(d)、(e)和(f)、(C) 具有 Si-O-C 或 Si-N-C 键的有机硅化合物催化剂组分，用于通过聚合至少一种烯烃和任选至少一种二 烯烃生产烯烃聚合物。
• SOLID CATALYST COMPONENT AND CATALYST FOR POLYMERIZATION OF OLEFINS, AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING SAME
  申请人：Toho Titanium CO., LTD.

  公开号：EP2360190A1

  公开（公告）日：2011-08-24

  A solid catalyst component for olefin polymerization is produced by causing (a) a solid component that includes magnesium, titanium, a halogen, and an electron donor, (b) an aminosilane compound shown by the following general formula (1), and (c) at least one organosilicon compound selected from an organosilicon compound shown by the following general formula (2-A) and an organosilicon compound shown by the following general formula (2-B) to come in contact with each other. A polymer having high stereoregularity is produced in high yield while achieving a high melt flow rate due to hydrogen by polymerizing an olefin in the presence of a catalyst that includes the solid catalyst component.         R1nSi(NR2R3)4-n     (1)         [CH2=CH-(CH2)1]qSiR44-q     (2-A)         R5Si(OR6)4-s     (2-B)

  一种用于烯烃聚合的固体催化剂组分是通过使(a)一种包括镁、钛、卤素和电子供体的固体组分，(b)如下通式(1)所示的氨基硅烷化合物，和(c)至少一种选自如下通式(2-A)所示的有机硅化合物和如下通式(2-B)所示的有机硅化合物的有机硅化合物相互接触而制得的。在含有固体催化剂组分的催化剂存在下，通过聚合烯烃，可以高产率地生产出具有高立体规整度的聚合物，同时由于氢气的存在，可以达到较高的熔体流动速率。 R1nSi(NR2R3)4-n (1) [CH2=CH-(CH2)1]qSiR44-q (2-A) R5Si(OR6)4-s (2-B)
• METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION, AND OLEFIN POLYMERS
  申请人：Toho Titanium Co., Ltd.

  公开号：EP2636688A1

  公开（公告）日：2013-09-11

  An environmentally-friendly solid catalyst component for olefin polymerization exhibits high hydrogen activity and high polymerization activity, can produce a polymer that exhibits a high MFR and high stereoregularity in high yield using a small amount of hydrogen, and exhibits high copolymerization activity and excellent copolymerization properties (e.g., block ratio). The solid catalyst component for olefin polymerization is produced by bringing (a) a magnesium compound, (b) an internal electron donor, and (c) a tetravalent-element halogen compound into contact with each other in an inert organic solvent, the internal electron donor (b) being represented by R12C(COOCH3)2 (wherein R1 is selected from a branched alkyl group having 3 to 20 carbon atoms, a halogen atom, a linear or branched halogen-substituted alkyl group having 2 to 20 carbon atoms, a linear alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a vinyl group, and an allyl group).

  一种用于烯烃聚合的环境友好型固体催化剂组分具有高氢活性和高聚合活 性，可使用少量氢气生产出高 MFR 和高立体规整度的聚合物，并具有高共聚活 性和优异的共聚特性（如嵌段比）。用于烯烃聚合的固体催化剂组分是通过在惰性有机溶剂中使(a)镁化合物、(b)内部电子供体和(c)四价元素卤素化合物相互接触而制得的、内部电子供体 (b) 由 R12C(COOCH3)2 表示（其中 R1 选自具有 3 至 20 个碳原子的支链烷基、卤原子、具有 2 至 20 个碳原子的直链或支链卤代烷基、具有 1 至 20 个碳原子的直链烷基、具有 3 至 20 个碳原子的环烷基、乙烯基和烯丙基）。
• METHOD FOR PRODUCING SOLID CATALYST COMPONENT FOR USE IN POLYMERIZATION OF OLEFIN, CATALYST FOR USE IN POLYMERIZATION OF OLEFIN, AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：Toho Titanium CO., LTD.

  公开号：EP2876118A1

  公开（公告）日：2015-05-27

  A method for producing a solid catalyst component for olefin polymerization produces a novel solid catalyst component for olefin polymerization that achieves excellent olefin polymerization activity and activity with respect to hydrogen during polymerization, and can produce an olefin polymer that exhibits a high MFR, high stereoregularity, and excellent rigidity. The method includes a first step that brings a magnesium compound, a tetravalent titanium halide compound, and one or more first internal electron donor compounds selected from specific aromatic dicarboxylic diesters into contact with each other to effect a reaction, followed by washing, a second step that brings a tetravalent titanium halide compound and one or more second internal electron donor compounds into contact with a product obtained by the first step to effect a reaction, followed by washing, and a third step that brings one or more third internal electron donor compounds into contact with a product obtained by the second step to effect a reaction.

  一种生产烯烃聚合用固体催化剂组分的方法可生产出一种新型的烯烃聚合用固体催化剂组分，该组分具有优异的烯烃聚合活性和聚合过程中对氢的活性，并可生产出具有高MFR、高立体规整度和优异刚性的烯烃聚合物。该方法包括第一步，使镁化合物、四价卤化钛化合物和一种或多种选自特定芳香族二羧酸二酯的第一内部电子供体化合物相互接触以发生反应，然后进行洗涤、第二步：使四价卤化钛化合物和一种或多种第二内部电子供体化合物与第一步得到的产物接触，以发生反应，然后进行洗涤；第三步：使一种或多种第三内部电子供体化合物与第二步得到的产物接触，以发生反应。

表征谱图