1,3,5,2,4,6-三吖三磷英,2,4-二氯-2,2,4,4,6,6-六氢-2,4,6,6-四苯氧基- | 13699-14-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,3,5,2,4,6-三吖三磷英,2,4-二氯-2,2,4,4,6,6-六氢-2,4,6,6-四苯氧基-
• 英文名称: 1,1,3,5-tetraphenoxy-3,5-dichlorocyclotriphosphazatriene
• 英文别名: 2,4-Dichlor-2,4,6,6-tetraphenoxy-cyclotriphosphazatrien；2,4-Dichloro-2,4,6,6-tetraphenoxy-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene；2,4-dichloro-2,4,6,6-tetraphenoxy-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene
• CAS: 13699-14-4
• 化学式: C₂₄H₂₀Cl₂N₃O₄P₃
• 分子量: 578.268
• InChiKey: ZSJFIOHVUXQNND-UHFFFAOYSA-N

物化性质

• 密度：
  1.46±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  1,3,5,2,4,6-三吖三磷英,2,4-二氯-2,2,4,4,6,6-六氢-2,4,6,6-四苯氧基- 在 sodium azide 、 四丁基溴化铵 作用下， 以 甲苯 、 丁酮 为溶剂， 反应 18.0h， 生成 triphenyl-[[2,4,4,6-tetraphenoxy-6-[(triphenyl-λ5-phosphanylidene)amino]-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-trien-2-yl]imino]-λ5-phosphane
  参考文献：
  名称：

  Synthesis and Reactivity of Alkoxy, Aryloxy, and Dialkylamino Phosphazene Azides

  摘要：

  DOI：

  10.1021/ja983424q
• 作为产物：
  描述：

  六氯环三磷腈 、 苯酚 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 26.0h， 生成 1,3,5,2,4,6-三吖三磷英,2,4-二氯-2,2,4,4,6,6-六氢-2,4,6,6-四苯氧基-
  参考文献：
  名称：

  Preparation and Thermal Properties of Poly(phosphazene-aryl ester) Containing Cyclotriphosphazene Structures

  摘要：

  通过合成芳香族二醇：1,1,3,5-四苯氧基-3,5-双(4-羟基苯氧基)环三磷腈与对苯二甲酰二氯的缩聚反应制备了新型芳香族聚(磷腈芳基酯)。合成的二醇和聚苯酯的化学结构通过元素分析、1H和31P NMR和FTIR技术进行表征，而它们的热性能和结晶性能则通过DSC、TGA和XRD技术测定。与传统的对氧基苯甲酰基均聚酯相比，聚（磷腈芳基酯）在极性质子溶剂中表现出优异的热稳定性和溶解度。聚（磷腈芳基酯）在 150-600 °C 的温度范围内表现出两次热降解，而单体（从其结构来看）在 150-300 °C 温度左右表现出第一个最大热分解速率，这可能是由于P-O-C键的分解。

  DOI：

  10.14233/ajchem.2014.16439

文献信息

• Incorporation of Cyclic Phosphazene Trimers into Saturated and Unsaturated Ethylene-like Polymer Backbones
  作者：Harry R. Allcock、E. Clay Kellam

  DOI：10.1021/ma011012n

  日期：2002.1.1

  well-defined cyclolinear phosphazene polymers via acyclic diene metathesis (ADMET) has been demonstrated. This work extends the range of properties achievable in cyclolinear phosphazenes synthesized via ADMET and provides an assessment of the synthetic limitations. A series of tetraphenoxy and tetramethoxyethoxyethoxy functionalized phosphazene trimers have been synthesized that bear two alkene side chains

  已经证明了通过无环二烯复分解（ADMET）合成定义明确的环线性磷腈聚合物。这项工作扩展了通过ADMET合成的环线性磷腈所能达到的性能范围，并提供了对合成限制的评估。已经合成了一系列带有两个烯烃侧链的四苯氧基和四甲氧基乙氧基乙氧基官能化的磷腈三聚体，它们一起形成ADMET所需的二烯结构。烯烃链的长度在三个碳到11个碳之间变化。这使得可以检查负相邻基团效应的影响以及空间因素，因为它们适用于磷腈单体的复分解反应。而且，讨论了不同催化剂的作用以及非烯烃磷腈取代基对单体反应性的影响。通过与癸二烯的共聚研究，还讨论了每条平均聚合物链中掺入不同数量的环磷腈对本体聚合物性能的影响。
• Phosphazene Compound, Lubricant and Magentic Recording Medium Having Such Compound, Method of Preparation, and Method of Lubrication
  申请人：Xu Jianwei

  公开号：US20090291325A1

  公开（公告）日：2009-11-26

  A compound of the formula: (I) is provided, where R is selected from CF 3 , F, and H, and m is an integer from 1 to 22. The compound may be prepared by reacting a first reactant with a second reactant in a solution, where the first reactant is a 2,4-dichloro-2,4,6,6-tetra(aryloxy)-1,3,5-triaza-2,4,6-triphosphorine, and the second reactant is a perfluoropolyether of the formula CF 3 CF 2 CF 2 O(CF 2 CF 2 CF 2 O) m CF 2 CF 2 CH 2 OH. The aryloxy is selected from 4-(trifluoromethyl)phenoxy (p-CF 3 —C 6 H 4 O), 4-fluorophenoxy (p-F—C 6 H 4 O), and phenoxy (C 6 H 5 O). The first reactant may be prepared by reacting 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine with a phenoxide. The compound may be used in a lubricant for lubricating a surface. The lubricant may be applied to a recording surface in a magnetic recording device including a recording medium.

  提供了公式（I）的化合物，其中R从CF3，F和H中选择，m是1至22的整数。可以通过在溶液中反应第一反应物和第二反应物来制备化合物，其中第一反应物是2,4-二氯-2,4,6,6-四（芳氧基）-1,3,5-三氮杂-2,4,6-三磷环，第二反应物是公式CF3CF2CF2O（CF2CF2CF2O）mCF2CF2CH2OH的全氟聚醚。芳氧基从4-（三氟甲基）苯氧基（p-CF3—C6H4O），4-氟苯氧基（p-F—C6H4O）和苯氧基（C6H5O）中选择。第一反应物可以通过将2,2,4,4,6,6-六氯-1,3,5-三氮杂-2,4,6-三磷环与苯氧基反应来制备。该化合物可以用作润滑剂，润滑表面。润滑剂可以涂覆在包括记录介质的磁记录装置中的记录表面上。
• Sulkowski, W.; Volodin, A. A.; Brandt, K., Journal of general chemistry of the USSR, 1981, vol. 51, # 6, p. 1033 - 1037
  作者：Sulkowski, W.、Volodin, A. A.、Brandt, K.、Kireev, V. V.、Korshak, V. V.

  DOI：——

  日期：——
• Synthesis, thermal and photophysical properties of phenoxy-substituted dendrimeric cyclic phosphazenes
  作者：Bünyemin Çoşut、Mahmut Durmuş、Adem Kılıç、Serkan Yeşilot

  DOI：10.1016/j.ica.2010.10.031

  日期：2011.1

  In the present study, we describe the synthesis of a hydroxyl substituted bridged phenoxycyclotriphosphazene (5), [N3P3(OPh)(5)OPhO(OPh)(5)N3P3OPhOH], as a side group and its use for preparation of dendrimeric cyclic phosphazenes. For this purposes, compound 5 is synthesised in five steps from the reactions of cyclotriphosphazene with phenol derivatives. The dendrimeric compounds 6 and 7 have been prepared by the reactions of compound 5 with hexachlorocyclotriphosphazene, N3P3Cl6, or octachlorocyclotetraphosphazene, N4P4Cl8, respectively. Newly synthesized compounds have been fully characterized by elemental analysis, MALDI-TOF mass spectrometry, FT-IR, H-1, C-13 and P-31 NMR spectroscopy. The thermal stability and fluorescence spectral properties of dendrimeric compounds 6 and 7 are investigated and compared with that of the previously reported cyclic compounds (I-II). Fluorescence quantum yields and lifetimes of dendrimeric compounds and their quenching behaviour by 1,4-benzoquinone are studied in dichloromethane. (C) 2010 Elsevier B.V. All rights reserved.
• PHOSPHAZENE COMPOUND, LUBRICANT AND MAGNETIC RECORDING MEDIUM HAVING SUCH COMPOUND, METHOD OF PREPARATION, AND METHOD OF LUBRICATION
  申请人：Agency for Science, Technology and Research

  公开号：EP2044094A1

  公开（公告）日：2009-04-08