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6-O-myristoyl L-ascorbate | 33425-76-2

中文名称
——
中文别名
——
英文名称
6-O-myristoyl L-ascorbate
英文别名
6-O-tetradecanoyl ascorbic acid;vitamin C myristate;vitamin C tetradecanoic acid ester;6-O-myristoyl-L-ascorbic acid;Lg-threo-2,3,4,5-tetrahydroxy-6-myristoyloxy-hex-2c-enoic acid-4-lactone;Lg-threo-2,3,4,5-Tetrahydroxy-6-myristoyloxy-hex-2c-ensaeure-4-lacton;L-ascorbyl myristate;ascorbyl myristate;[(2S)-2-[(2R)-3,4-dihydroxy-5-oxo-2H-furan-2-yl]-2-hydroxyethyl] tetradecanoate
6-O-myristoyl L-ascorbate化学式
CAS
33425-76-2
化学式
C20H34O7
mdl
——
分子量
386.486
InChiKey
MSKSZMDNKAEBSG-HNAYVOBHSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 熔点:
    110.5-111.5 °C
  • 沸点:
    488.9±45.0 °C(Predicted)
  • 密度:
    1.181±0.06 g/cm3(Predicted)

计算性质

  • 辛醇/水分配系数(LogP):
    5.2
  • 重原子数:
    27
  • 可旋转键数:
    16
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    0.8
  • 拓扑面积:
    113
  • 氢给体数:
    3
  • 氢受体数:
    7

SDS

SDS:6b916e6907dadc441b3d6bbc9d456e73
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上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为产物:
    描述:
    五甲基呋喃溴酸酯维生素 C 在 Bulkholderia multivorans lipase-loaded alumina 作用下, 反应 0.75h, 以76%的产率得到6-O-myristoyl L-ascorbate
    参考文献:
    名称:
    Green Enzymatic Synthesis of L-Ascorbyl Fatty Acid Ester: An Antioxidant
    摘要:
    In green chemistry, biocatalysis using microwaves is a very attractive tool for various regioselective syntheses. L-Ascorbyl fatty acid esters were synthesized by an immobilized lipase from Bulkholderia multivorans using microwaves, with a dynamically enhanced rate of reaction and appreciable yield of around 80%. Microwave radiation had no effect on enzymic inactivation, however, synergism between microwaves and biocatalyst was observed.
    DOI:
    10.1080/00397910802513045
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文献信息

  • Cyclopentanone derivatives, method of synthesis and uses thereof
    申请人:Neuropharma S.A.
    公开号:EP1939192A1
    公开(公告)日:2008-07-02
    The present invention relates to cyclopentanone derivatives of formula (I), their method of synthesis and uses thereof. Concretely, the compounds disclosed have proved to be inhibitors of glycogen synthase kinase 3β, GSK-3 β, which is known to be involved in different disease and conditions, such as Alzheimer's disease or non-insulin dependent diabetes mellitus. The present invention also relates to pharmaceutical compositions comprising the same. Further, the present invention is directed to the use of the compounds in the manufacture of a medicament for the treatment and/or prevention of a GSK-3 mediated disease or condition.
    本发明涉及公式(I)的环戊酮衍生物,其合成方法及用途。具体来说,所披露的化合物已被证明是糖原合成酶激酶3β(GSK-3β)的抑制剂,GSK-3β已知参与不同疾病和病况,如阿尔茨海默病或非胰岛素依赖型糖尿病。本发明还涉及包含这些化合物的药物组合物。此外,本发明旨在将这些化合物用于制造治疗和/或预防GSK-3介导的疾病或病况的药物。
  • 一种维生素C高级脂肪酸酯的绿色合成方法
    申请人:上虞新和成生物化工有限公司
    公开号:CN112480046B
    公开(公告)日:2022-09-02
    本发明公开了一种维生素C高级脂肪酸酯的绿色合成方法,包括:在酰化反应催化剂催化下,维生素C与高级脂肪酸酐在无溶剂条件下发生酯化反应,经过后处理得到所述的维生素C高级脂肪酸酯。该合成方法对环境友好,反应温度较低,能耗小,成本低,原辅料的分子利用率较高,收率高。
  • FORMULATIONS OF LIPOPHILIC BIOACTIVE MOLECULES
    申请人:Zumes, LLC
    公开号:US20140039052A1
    公开(公告)日:2014-02-06
    This invention provides aqueous and non-aqueous clear formulations including at least one lipophilic bioactive molecules and an amphiphilic solubilizing agent. Exemplary aqueous formulations include a water-soluble reducing agent, which diminishes or prevents chemical degradation of the lipophilic bioactive molecule. The invention also provides methods of using the formulations of the invention. For example, the invention provides beverages including the formulations of the invention. The invention further provides methods of making the formulations and beverages.
    本发明提供了包括至少一种亲脂性生物活性分子和一种两性溶解剂的水性和非水性透明配方。其中,水性配方包括水溶性还原剂,可减少或防止亲脂性生物活性分子的化学降解。本发明还提供了使用该配方的方法。例如,本发明提供了包括该配方的饮料。本发明还提供了制备该配方和饮料的方法。
  • Process for producing organic acid esters
    申请人:MITSUBISHI RAYON CO., LTD
    公开号:EP0514694A1
    公开(公告)日:1992-11-25
    An organic acid ester of ascorbic acid or erythorbic acid is produced by reacting ascorbic acid or erythorbic acid with an organic acid enol ester in an organic solvent with a solubility of ascorbic acid or erythorbic acid of more than 0.3% at 25°C in the presence of an active lipase.
    抗坏血酸或赤藓红酸的有机酸酯是在 25°C 时,在有活性脂肪酶存在的情况下,将抗坏血酸或赤藓红酸与有机酸烯醇酯在溶解度大于 0.3% 的有机溶剂中反应制得的。
  • ANTI-PLANT-VIRUS AGENT
    申请人:National University Corporation Hokkaido University
    公开号:EP2478768A1
    公开(公告)日:2012-07-25
    The present invention provides an anti-plant virus agent which exhibits preventative and therapeutic effects on plant virus diseases. The anti-plant virus agent of the present invention is characterized by containing at least one compound selected from the group consisting of ascorbic acid derivatives represented by Formula (I) (wherein, R1 to R4 each independently represents a hydrogen atom, -SO3H -PO3H2, a glycosyl group, or -COR11, wherein R11 represents an unsubstituted or substituted C1-30 alkyl group, or an unsubstituted or substituted C2-30 alkenyl group, with the proviso that R1 to R4 may not all be hydrogen atoms at the same time), and salts thereof.
    本发明提供了一种对植物病毒病具有预防和治疗作用的抗植物病毒剂。本发明的抗植物病毒剂的特征在于含有至少一种选自由式(I)代表的抗坏血酸衍生物(其中,R1至R4各自独立地代表氢原子、-SO3H -PO3H2、糖基或-COR11,其中R11代表未取代或取代的C1-30烷基,或未取代或取代的C2-30烯基,但R1至R4不一定同时都是氢原子)组成的组中的化合物及其盐类。
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