N-(pyridin-4-yl)decanamide | 80028-21-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(pyridin-4-yl)decanamide
• 英文别名: N-(4-Pyridyl)decanamide；N-(4-pyridinyl)decanamide；N-pyridin-4-yldecanamide
• CAS: 80028-21-3
• 化学式: C₁₅H₂₄N₂O
• 分子量: 248.368
• InChiKey: ISBMPAZHJIGIAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  42
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(pyridin-4-yl)decanamide 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 7.0h， 以51%的产率得到4-(Decylamino)pyridine
  参考文献：
  名称：

  Kerr, James M.; Suckling, Colin J.; Bamfield, Peter, Journal of the Chemical Society. Perkin transactions I, 1990, # 4, p. 887 - 895

  摘要：

  DOI：
• 作为产物：
  描述：

  正癸酸 在 氯化亚砜 作用下， 以 乙醚 为溶剂， 反应 0.5h， 生成 N-(pyridin-4-yl)decanamide
  参考文献：
  名称：

  Kumar, Ashwani; Singh, Surender; Jain, Sandeep, Acta poloniae pharmaceutica, 2011, vol. 68, # 2, p. 191 - 204

  摘要：

  DOI：

文献信息

• Poly(ethylenimines) with alternative (alkylamino)pyridines as nucleophilic catalysts
  作者：Edward J. Delaney、Leigh E. Wood、Irving M. Klotz

  DOI：10.1021/ja00367a025

  日期：1982.2
• Self-Assembled Bilayers as an Anchoring Strategy: Catalysts, Chromophores, and Chromophore-Catalyst Assemblies
  作者：Lei Wang、Dmitry E. Polyansky、Javier J. Concepcion

  DOI：10.1021/jacs.9b01044

  日期：2019.5.22

  Anchoring strategies for immobilization of molecular catalysts, chromophores, and chromophore-catalyst assemblies on electrode surfaces play an important role in solar energy conversion devices such as dye sensitized solar cells and dye-sensitized photoelectrosynthesis cells. They are also important in interfacial studies with surface-bound molecules including electron-transfer dynamics and mechanistic studies related to small molecule activation catalysis. Significant progress has been made in this area, but many challenges remain in terms of stability, synthetic complexity, and versatility. We report here a new anchoring strategy based on self assembled bilayers. This strategy takes advantage of noncovalent interactions between long alkyl chains chemically bound to a metal-oxide electrode surface and long alkyl chains on the molecule being anchored. The new methodology is applicable to the heterogenization of both catalysts and chromophores as well as to the in situ "synthesis" of chromophore-catalyst assemblies on the electrode surface.
• DELANEY, E. J.;WOOD, L. E.;KLOTZ, I. M., J. AMER. CHEM. SOC., 1982, 104, N 3, 799-807
  作者：DELANEY, E. J.、WOOD, L. E.、KLOTZ, I. M.

  DOI：——

  日期：——
• Kumar, Ashwani; Singh, Surender; Jain, Sandeep, Acta poloniae pharmaceutica, 2011, vol. 68, # 2, p. 191 - 204
  作者：Kumar, Ashwani、Singh, Surender、Jain, Sandeep、Kumar, Parvin

  DOI：——

  日期：——
• Kerr, James M.; Suckling, Colin J.; Bamfield, Peter, Journal of the Chemical Society. Perkin transactions I, 1990, # 4, p. 887 - 895
  作者：Kerr, James M.、Suckling, Colin J.、Bamfield, Peter

  DOI：——

  日期：——