triethoxy(3-phenoxypropyl)silane | 58096-84-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: triethoxy(3-phenoxypropyl)silane
• 英文别名: Phenoxypropyltriethoxysilane
• CAS: 58096-84-7
• 化学式: C₁₅H₂₆O₄Si
• 分子量: 298.455
• InChiKey: PSBNUYBJFLJEIG-UHFFFAOYSA-N

物化性质

• 沸点：
  95-105 °C(Press: 0.019 Torr)
• 密度：
  0.993±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  烯丙基苯基醚 在 dihydrogen hexachloroplatinate 、 三氯硅烷 作用下， 以 异丙醇 为溶剂， 反应 6.0h， 生成 triethoxy(3-phenoxypropyl)silane
  参考文献：
  名称：

  Belyakova,Z.V. et al., Journal of general chemistry of the USSR, 1976, vol. 46, # 5, p. 1030 - 1035

  摘要：

  DOI：

文献信息

• A Diphosphino-Functionalised MCM-41-Anchored Platinum Complex: An Efficient and Reusable Catalyst for the Hydrosilylation of Olefins
  作者：Lingfang Zha、Wenyan Hao、Mingzhong Cai

  DOI：10.3184/030823410x12887259824283

  日期：2010.11

  diphosphino-functionalised MCM-41 anchored platinum complex (MCM-41-2P-Pt) was conveniently synthesised from commercially available and cheap γ-aminopropyltriethoxysilane via immobilisation on MCM-41, followed by reactiopn with diphenylphosphinomethanol and potassium chloroplatinite. It was found that the title complex is a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane and can

  二膦基官能化的 MCM-41 锚定铂配合物 (MCM-41-2P-Pt) 是由市售且廉价的 γ-氨基丙基三乙氧基硅烷通过固定在 MCM-41 上方便地合成，然后与二苯基膦甲醇和氯铂酸钾反应。发现标题配合物是烯烃与三乙氧基硅烷氢化硅烷化的高效催化剂，可以通过反应溶液的简单过滤来回收和再循环，并用于至少 10 个连续反应而不会降低活性。
• Hydrosilylation of olefins over rhodium complex anchored over thioether-functionalized MCM-41
  作者：Lig Fang Zha、Wei Sen Yang、Wen Yan Hao、Ming Zhong Cai

  DOI：10.1016/j.cclet.2010.06.007

  日期：2010.11

  hydrosilylation of alkenes with triethoxysilane has been achieved at 120 °C in the presence of 0.01 mol% of thioether-functionalized MCM-41 anchored rhodium complex, affording the corresponding addition products in 68–91% yields. This supported rhodium complex can be reused several times without noticeable loss of activity. Our system not only solves the basic problems of catalyst separation and recovery

  在0.01摩尔％硫醚官能化的MCM-41锚固铑配合物的存在下，烯烃与三乙氧基硅烷的氢化硅烷化反应已在120°C下完成，从而以68-91％的产率提供了相应的加成产物。这种负载的铑配合物可以重复使用多次，而不会造成明显的活性损失。我们的系统不仅解决了催化剂分离和回收的基本问题，而且避免了使用膦配体。
• MCM-41-Supported Bidentate Phosphine Rhodium Complex: An Efficient and Recyclable Heterogeneous Catalyst for the Hydrosilylation of Olefins
  作者：Ronghua Hu、Wenyan Hao、Mingzhong Cai

  DOI：10.1002/cjoc.201180292

  日期：2011.8

  MCM‐41‐supported bidentate phosphine rhodium complex (MCM‐41‐2P‐RhCl3) was conveniently synthesized from commercially available and cheapγ‐aminopropyltriethoxysilane via immobilization on MCM‐41, followed by reacting with diphenylphosphinomethanol and rhodium chloride. It was found that the title complex is a highly efficient catalyst for the hydrosilylation of olefins with triethoxysilane and can

  MCM-41支持的二齿膦膦铑络合物（MCM-41-2P-RhCl 3）是通过固定在MCM-41上，由市售廉价的γ-氨基丙基三乙氧基硅烷方便地合成，然后与二苯基膦甲醇和氯化铑反应而合成的。发现标题配合物是用于烯烃与三乙氧基硅烷的氢化硅烷化的高效催化剂，并且可以通过简单过滤反应溶液来回收和再循环，并用于至少10次连续试验而活性没有任何降低。
• MCM-41-Immobilised Bidentate Nitrogen Platinum Complex: A Highly Efficient and Recyclable Phosphine-Free Catalytic System for the Hydrosilylation of Olefins
  作者：Hean Zhang、Jiaqin Liu、Shaojuan Cheng、Mingzhong Cai

  DOI：10.3184/174751912x13324196074823

  日期：2012.4

  MCM-41-immobilised bidentate nitrogen platinum complex (MCM-41-2N-Pt) was very conveniently synthesised from commercially available and cheap 3-(2-aminoethylamino)propyltrimethoxysilane by immobilisation on the mesoporous silica nanoparticles, MCM-41, followed by reaction with potassium chloroplatinite. It was found that the MCM-41-2N-Pt complex is a highly efficient catalyst for the hydrosilylation of olefins with

  MCM-41 固定的双齿氮铂络合物 (MCM-41-2N-Pt) 是由市售且廉价的 3-(2-氨基乙基氨基)丙基三甲氧基硅烷通过固定在介孔二氧化硅纳米粒子 MCM-41 上非常方便地合成，然后是与氯铂酸钾反应。结果表明，MCM-41-2N-Pt 络合物是烯烃与三乙氧基硅烷氢化硅烷化的高效催化剂，可以轻松回收和重复使用多次，而不会显着降低活性。
• New Heterogenized Rhodium Complexes, Methods of their Synthesis and Application as Hydrosilylation Catalysts
  申请人：Marciniec Bogdan

  公开号：US20100048932A1

  公开（公告）日：2010-02-25

  The subjects of the invention are new heterogenized rhodium complexes, the methods of their synthesis and their application as catalysts for synthesis of organosilicon compounds by hydrosilylation. The subject of the invention are new siloxide rhodium(I) complexes immobilised on the silica surface, of the general formula 1. [(≡SiO)(L)Rh(diene)] The second subject of the invention is the method of synthesis of the new rhodium complexes of the general formula 1. The third subject of the invention is the method of obtaining the organosilicon compounds in the reaction of hydrosilylation between the selected alkenes or functionalised alkenes containing the terminal C═C bond and the appropriate compounds containing the Si═H bond selected from silanes, (poly)siloxanes and (poly)carbosiloxanes, in the presence of heterogenized rhodium catalysts, of the general formula 1.

  该发明涉及新的杂化铑配合物，它们的合成方法以及它们作为有机硅化合物的氢硅烷基合成催化剂的应用。该发明涉及新的固定在硅表面上的硅氧化铑(I)配合物，其一般化学式为1. [(≡SiO)(L)Rh(diene)] 该发明的第二主题是合成新的一般式1的铑配合物的方法。该发明的第三主题是在选择的烯烃或含有末端C═C键的官能化烯烃与选择的含有Si═H键的适当化合物之间进行氢硅烷基反应，以在杂化铑催化剂的存在下获得有机硅化合物的方法，其一般化学式为1。