Tetradecanedioic acid dibutyl ester | 15805-82-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Tetradecanedioic acid dibutyl ester
• 英文别名: n-ω,ω'-Tetradecandisaeure-di-n-butylester；Dibutyl tetradecanedioate
• CAS: 15805-82-0
• 化学式: C₂₂H₄₂O₄
• 分子量: 370.573
• InChiKey: CMZRHNCSOMISKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  26
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  十四烷二酸 、 正丁醇 生成 Tetradecanedioic acid dibutyl ester
  参考文献：
  名称：

  MOLNAR-PERL, I.;PINTER-SZAKACS, M.;MORVAI, M.;FABIAN-VONSIK, V., J. CHROMATOGR., 446,(1988) 237-246

  摘要：

  DOI：

文献信息

• Selective monoesterification of dicarboxylic acids catalysed by ion-exchange resins
  作者：Takeshi Nishiguchi、Yasuhiro Ishii、Shizuo Fujisaki

  DOI：10.1039/a902325i

  日期：——

  Symmetrical dicarboxylic acids with 4–14 carbon atoms gave selectively the corresponding monoesters in high yields in the transesterification catalysed by strongly acidic ion-exchange resins in ester–hydrocarbon mixtures. It was found that the rate of the esterification of the dicarboxylic acids is much higher than that of the monocarboxylic acids formed. This result can explain the high selectivity for the monoester formation and can also be explained by the existence of an aqueous layer on the surface of the resins. This method of selective esterification is quite simple and practical.

  具有4至14个碳原子的对称二羧酸在强酸性离子交换树脂催化下的转酯化反应中，可以在酯-烃混合物中高选择性地获得相应的单酯，产率很高。研究发现，二羧酸的酯化速率远高于形成的单羧酸的速率。这一结果可以解释单酯形成的高选择性，也可以通过树脂表面存在的水层来解释。这种选择性酯化方法相当简单且实用。
• Convenient selective monoesterification of α, ω-dicarboxylic acids catalyzed by ion-exchange resins
  作者：Masahiko Saitoh、Shizuo Fujisaki、Yasuhiro Ishii、Takeshi Nishiguchi

  DOI：10.1016/s0040-4039(96)01454-2

  日期：1996.9

  Symmetric dicarboxylic acids, ranging from pentanedioic acid to tetradecanedioic acid, gave selectively the corresponding monoesters in high yields in the transesterification catalyzed by strongly acidic ion-exchange resins in ester/octane mixtures. Copyright (C) 1996 Elsevier Science Ltd
• OLEFIN POLYMERIZATION CATALYST COMPONENT AND PRODUCTION PROCESS THEREOF, AND PRODUCTION PROCES OF OLEFIN POLYMERIZATION CATALYST AND OLEFIN POLYMER
  申请人：OKADA Mitsuhiro

  公开号：US20110245439A1

  公开（公告）日：2011-10-06

  A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and a defined internal electron donor such as dodecanedioyl dichloride; a production process of such a solid catalyst component, using a titanium compound, a magnesium compound, and the above internal electron donor, or using a solid component containing a titanium atom and a magnesium atom, and the above internal electron donor; a production process of a solid catalyst, using (i) the above solid catalyst component, (ii) an organoaluminum compound, and (iii) an external electron donor; and a production process of an olefin polymer using the above solid catalyst.
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.
• US4051087A
  申请人：——

  公开号：US4051087A

  公开（公告）日：1977-09-27