methyl ammonium azide | 87321-27-5

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物
• 英文名称: methyl ammonium azide
• 英文别名: methylamine; azide；Methylamin; Azid
• CAS: 87321-27-5
• 化学式: CH₆N*N₃
• 分子量: 74.0854
• InChiKey: XPJJDBDCQLDJEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.45
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86.27
• 氢给体数：
  2.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  methyl ammonium azide 生成 5-苯基四氮唑
  参考文献：
  名称：

  TITOVA I. E.; POPLAVSKIJ V. S.; KOLDOBSKIJ G. I.; OSTROVSKIJ V. A.; NIKOL+, XIMIYA GETEROTSIKL. SOED.,(1986) N 8, 1086-1089

  摘要：

  DOI：
• 作为产物：
  描述：

  (甲基氨基甲酰)叠氮化 在 水 作用下， 生成 methyl ammonium azide
  参考文献：
  名称：

  Oliveri-Mandala; Calderaro, Gazzetta Chimica Italiana, 1913, vol. 43 I, p. 540

  摘要：

  DOI：

文献信息

• Reactions of NH Radicals. V. Photolysis of HN₃in the Presence of C₃H₈at 313 nm
  作者：Sukeya Kodama

  DOI：10.1246/bcsj.58.2900

  日期：1985.10

  The photolysis of HN3 vapor in the presence of C3H8 was studied at 313 nm and 30°C. The main products were N2, H2, CH4, C2H6, C3H6, NH4N3, CH3NH2·HN3, C2H5NH2·HN3, and n- and i-C3H7NH2·HN3. The quantum yields of these products were measured as a function of the pressure of HN3 or C3H8. The following mechanisms for the main reactions was proposed: HN3+hν(313 nm)→N2+NH(a1Δ); NH(a1Δ)+HN3→2N2+2H, NH2+N3, and N2+N2H2* (2); NH(a1Δ)+C3H8→C3H7NH2*(n- and i-propylamine) (3); NH(a1Δ)+C3H8→NH (X3Σ−)+C3H8 (4); C3H7NH2*→CH3+C2H4NH2 (5); CH4+C2H4NH (6), C2H4+CH3NH2 (7), C2H5+CH2NH2 (8), C2H6+CH2NH (9), H2+C3H6NH (10), and NH3+C3H6 (11); C3H7NH2*+HN3→C3H7NH2+HN3 (12); C3H7NH2*+ C3H8→C3H7NH2+C3H8 (13). The rate constant ratios are: k3⁄k2=1.28; k4⁄k2=0.262; k6⁄k5=0.109; k7⁄k5=0.050; k8⁄k5=1.39; k9⁄k5=0.040; k10⁄k5=1.20; k11⁄k5=4.72; k12⁄k5=666 dm3 mol−1; k13⁄k5=860 dm3 mol−1. The formation ratio of n-C3H7NH2/i-C3H7NH2 was 1.55, regardless of the total pressure. The half-life of 1.78×10−10 s for C3H7NH2* was obtained by using the collision theory. The relative and absolute rate constants were compared for the reactions of NH(a1Δ) with CH4, C2H6, and C3H8; it was found that the relative yield for the insertion of NH(a1Δ) into a C–H bond increases with a decrease in the C–H bond dissociation energy.

  在30°C和313 nm下研究了HN3蒸气在C3H8存在下的光解过程。主要产物为N2、H2、CH4、C2H6、C3H6、NH4N3、 NH2· 、 NH2· 以及n-和i-C3H7NH2· 。测量了这些产物的量子产率与 或 的压力的关系。提出了主要反应的以下机制： +hν(313 nm)→N2+NH(a1Δ)；NH(a1Δ)+ →2N2+2H，NH2+N3，以及N2+N2H2* (2)；NH(a1Δ)+ →C3H7NH2*(n-和i-丙胺) (3)；NH(a1Δ)+ →NH (X3Σ−)+ (4)；C3H7NH2*→CH3+ NH2 (5)； + NH (6)，C2H4+ NH2 (7)，C2H5+CH2NH2 (8)， +CH2NH (9)，H2+ NH (10)，以及NH3+ (11)；C3H7NH2*+ →C3H7NH2+ (12)；C3H7NH2*+ →C3H7NH2+ (13)。反应的速率常数比为：k3⁄k2=1.28；k4⁄k2=0.262；k6⁄k5=0.109；k7⁄k5=0.050；k8⁄k5=1.39；k9⁄k5=0.040；k10⁄k5=1.20；k11⁄k5=4.72；k12⁄k5=666 dm3 mol−1；k13⁄k5=860 dm3 mol−1。n-C3H7NH2/i-C3H7NH2的形成比为1.55，无论总压力如何。通过使用碰撞理论得到C3H7NH2*的半衰期为1.78×10−10 s。比较了NH(a1Δ)与 、 和 反应的相对和绝对速率常数；发现NH(a1Δ)插入C–H键的相对产率随着C–H键离解能的降低而增加。
• Derivatives of tetrazaborol-2-ine (cyclotetrazenoborane) V. Preparation and properties of B-alkyl, B-aryl and B-vinyl derivatives
  作者：J.B. Leach、J.H. Morris

  DOI：10.1016/s0022-328x(00)82759-x

  日期：1968.8

  Two routes for the preparation of B-substituted tetrazaborol-2-ines have been developed. The action of Grignard reagents on derivatives of the type R2N4BH produces compounds R2N4BR″ in high yield, through the intermediate formation of magnesium-containing complexes. Thermal degradation of a diorganoboron azide in the presence of an organic azide also produces boron-substituted tetrazaborol-2-ines.

  已经开发了两种制备B-取代的四氮杂硼烷-2-胺的途径。格氏试剂对R 2 N 4 BH类型衍生物的作用是通过中间形成含镁配合物而以高收率产生化合物R 2 N 4 BR”。在有机叠氮化物的存在下，二有机硼叠氮化物的热降解也会产生硼取代的四氮杂硼烷-2-胺。已经研究了化合物的UV，IR和NMR光谱。
• Reactions of NH Radicals. IV. Photolysis of HN₃in the Presence of CH₄at 313 nm
  作者：Sukeya Kodama

  DOI：10.1246/bcsj.58.2891

  日期：1985.10

  The photolysis of HN3 vapor in the presence of CH4 was studied at 313 nm, 30 °C, and a low light intensity. The reaction products were N2, H2, NH4N3, CH3NH2·HN3, and CH3N3. CH3 radicals were also detected as intermediates. The quantum yields of these products were measured as a function of the CH4 and HN3 pressures. The following mechanisms for the main reactions were proposed: HN3+hν(313nm)→N2+NH(a1Δ); NH(a1Δ)+HN3→2N2+2H(2a); NH(a1Δ)+HN3→N3+NH2 (2b); NH(a1Δ)+HN3→N2+N2H2* (2c); NH(a1Δ)+ CH4→CH3NH2* (3); NH(a1Δ)+CH4→NH(X3Σ−)+CH4 (4); CH3NH2*→H+CH2NH2 or CH3NH (5); CH3NH2*→CH3+NH2 (6). The rate-constant ratios at 30°C were: k3⁄k2=0.175; k4⁄k2=0.177; k6⁄k5=0.133. The collisional deactivation of CH3NH2* was not found in the total pressure range, from 6.4 to 24.3 kPa.

  在 313 nm、30 °C 和低光强条件下，研究了 HN3 蒸汽在 CH4 存在下的光解过程。反应产物为 N2、H2、NH4N3、 NH2- 和 CH3N3。还检测到 CH3 自由基作为中间产物。测量了这些产物的量子产率与 和 压力的函数关系。主要反应的机理如下： +hν(313nm)→N2+NH(a1Δ); NH(a1Δ)+ →2N2+2H(2a); NH(a1Δ)+ →N3+NH2 (2b); NH(a1Δ)+ →N2+N2H2* (2c)；NH(a1Δ)+ → NH2* (3)；NH(a1Δ)+ →NH(X3Σ-)+ (4)； NH2*→H+CH2NH2 或 NH (5)； NH2*→ +NH2 (6)。30°C 时的速率常数比为：k3⁄k2=0.175；k4⁄k2=0.177；k6⁄k5=0.133。在 6.4 至 24.3 千帕的总压力范围内，未发现 NH2* 的碰撞失活现象。
• Reactions of NH Radicals. II. Photolysis of HN₃in the Presence of C₂H₆at 313 nm
  作者：Sukeya Kodama

  DOI：10.1246/bcsj.56.2355

  日期：1983.8

  The photolysis of HN3 vapor in the presence of C3H8 was studied at 313 nm and 30°C. The main products were N2, H2, CH4, C2H6, C3H6, NH4N3, CH3NH2·HN3, C2H5NH2·HN3, and n- and i-C3H7NH2·HN3. The quantum yields of these products were measured as a function of the pressure of HN3 or C3H8. The following mechanisms for the main reactions was proposed: HN3+hν(313 nm)→N2+NH(a1Δ); NH(a1Δ)+HN3→2N2+2H, NH2+N3

  在 313 nm 和 30°C 下研究了在 C3H8 存在下 HN3 蒸气的光解。主要产品有N2、H2、CH4、C2H6、C3H6、NH4N3、 NH2· 、 NH2· 、n-和i- 7NH2· 。这些产物的量子产率作为 或 压力的函数进行测量。提出了以下主要反应机理： +hν(313 nm)→N2+NH(a1Δ)；NH(a1Δ)+ →2N2+2H、NH2+N3和N2+N2H2* (2)；NH(a1Δ)+ → 7NH2*(正丙胺和异丙胺)(3)；NH(a1Δ)+ →NH(X3Σ-)+ (4)； 7NH2*→CH3+ NH2 (5)； + NH(6)、C2H4+ NH2(7)、C2H5+CH2NH2(8)、 +CH2NH(9)、H2+ NH(10)和NH3+ (11)；C3H
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.4, 12.5, page 305 - 310
  作者：

  DOI：——

  日期：——