1,4-bis(N-phenothiazinylmethyl)benzene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 1,4-bis(N-phenothiazinylmethyl)benzene
• 英文别名: 1,4-bis[(phenothiazin-10-yl)methyl]benzene；10-[[4-(Phenothiazin-10-ylmethyl)phenyl]methyl]phenothiazine
• 化学式: C₃₂H₂₄N₂S₂
• 分子量: 500.688
• InChiKey: DOEQICUZCGWEEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  57.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-bis(N-phenothiazinylmethyl)benzene 在 哌啶 、 三氯氧磷 作用下， 以 氯仿 、 1,1,2-三氯乙烷 为溶剂， 反应 8.0h， 生成
  参考文献：
  名称：

  Enhanced Performance of the Dye-Sensitized Solar Cells with Phenothiazine-Based Dyes Containing Double D−A Branches

  摘要：

  Double donor-acceptor (D-A) branched dyes (DBD) with a phenothiazine unit as electron donor and a 2-cyanoacrylic acid unit as electron acceptor were synthesized and used as sensitizers for solar cells (DSSCs). The conversion efficiency of the DSSCs amounts up to 4.22% (2.91% for the single D-A branched dye) under AM 1.5 G irradiation. The results show that the performance of DSSCs can be effectively enhanced by the cooperation of two donor-acceptor containing branches in one molecule of the dyes.

  DOI：

  10.1021/ol2000167
• 作为产物：
  描述：

  吩噻嗪 、 1,4-对二氯苄 在 N-甲基吡咯烷酮 、 氢氧化钾 作用下， 反应 10.0h， 以62%的产率得到1,4-bis(N-phenothiazinylmethyl)benzene
  参考文献：
  名称：

  Vitrigens. I. Synthesis and Characterization of Low Molecular Weight Organic Glasses

  摘要：

  New low molecular weight organic materials with a strong tendency towards glass formation and glass temperatures above room temperature were synthesized. These materials consist of twin molecules where two bulky groups, i.e. carbazole (Ca), 3,6-dibromocarbazole (DBrCa), 2,3-benzocarbazole (BC), 1,2-benzo-3,4-dihydrocarbazole (BCDH), phenothiazine (Ph), 1,8-naphthalic acid anhydride (NI), and pyrene-l-aldehyde (PY) have been linked by flexible or semiflexible aliphatic or aromatic central units. Their structure-glass temperature relationship and some relations between thermodynamic parameters and amorphous properties are discussed.

  DOI：

  10.1002/(sici)1521-3897(199902)341:2<128::aid-prac128>3.0.co;2-m

文献信息

• Electrochemical Detection of Substrates
  申请人：Elliott C. Michael

  公开号：US20080081329A1

  公开（公告）日：2008-04-03

  The present invention provides a method for detecting probe-target substrate binding. In particular, the present invention provides a method for detecting a surface bound target complex by detecting the redox reaction of a redox transition metal complex that is catalyzed by a redox-catalyst complex.
• US7892816B2
  申请人：——

  公开号：US7892816B2

  公开（公告）日：2011-02-22