3-(4'-hydroxy-3'-methoxyphenyl)-1,2-propanediol triacetate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 3-(4'-hydroxy-3'-methoxyphenyl)-1,2-propanediol triacetate
• 英文别名: 3-(4-Acetoxy-3-methoxyphenyl)propane-1,2-diyl diacetate；[2-acetyloxy-3-(4-acetyloxy-3-methoxyphenyl)propyl] acetate
• 化学式: C₁₆H₂₀O₇
• 分子量: 324.331
• InChiKey: HOFDJSIQKCFJNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  23
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  丁香酚 在 吡啶 、 硫酸 、 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 3-(4'-hydroxy-3'-methoxyphenyl)-1,2-propanediol triacetate
  参考文献：
  名称：

  Antioxidative phenylpropanoids from berries of Pimenta dioica

  摘要：

  A phenylpropanoid, threo-3-chloro-1-(4-hydroxy-3-methoxy phenyl)propane-1,2-diol, was isolated from the berries of Pimenta dioica together with five known compounds. eugenol, 4-hydroxy-3-methoxycinnamaldehyde, 3,4-dimethoxycinnamaldehyde, vanillin and 3-(4-hydroxy-3-methoxyphenyl)propane-1,2-diol. In addition, the stereochemistry of 3-(4-hydroxy-3-methoxyphenyl)propane- 1,2-diol was determined. The phenylpropanoids inhibited autoxidation of linoleic acid in a water-alcohol system. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(99)00406-9

文献信息

• Antioxidative phenylpropanoids from berries of Pimenta dioica
  作者：Hiroe Kikuzaki、Sanae Hara、Yayoi Kawai、Nobuji Nakatani

  DOI：10.1016/s0031-9422(99)00406-9

  日期：1999.12

  A phenylpropanoid, threo-3-chloro-1-(4-hydroxy-3-methoxy phenyl)propane-1,2-diol, was isolated from the berries of Pimenta dioica together with five known compounds. eugenol, 4-hydroxy-3-methoxycinnamaldehyde, 3,4-dimethoxycinnamaldehyde, vanillin and 3-(4-hydroxy-3-methoxyphenyl)propane-1,2-diol. In addition, the stereochemistry of 3-(4-hydroxy-3-methoxyphenyl)propane- 1,2-diol was determined. The phenylpropanoids inhibited autoxidation of linoleic acid in a water-alcohol system. (C) 1999 Elsevier Science Ltd. All rights reserved.