5-anilino-4-antipyrinylazo-2-benzoyl-3-methylthiophene | 1346240-79-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-anilino-4-antipyrinylazo-2-benzoyl-3-methylthiophene
• 英文别名: 4-[(2-Anilino-5-benzoyl-4-methylthiophen-3-yl)diazenyl]-1,5-dimethyl-2-phenylpyrazol-3-one
• CAS: 1346240-79-6
• 化学式: C₂₉H₂₅N₅O₂S
• 分子量: 507.616
• InChiKey: INCAUBWMRSTVOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  37
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  106
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2-acetyl-1-thioacetoacetanilide 在 sodium ethanolate 、 sodium acetate 作用下， 以 乙醇 为溶剂， 反应 4.0h， 生成 5-anilino-4-antipyrinylazo-2-benzoyl-3-methylthiophene
  参考文献：
  名称：

  New azodisperse dyes with thiazole, thiophene, pyridone and pyrazolone moiety for dyeing polyester fabrics

  摘要：

  New antipyrinylazo dyes were prepared by diazocoupling of 4-antipyrinyl diazonium chloride with a variety of coupling components e.g. thiazole, thiophene, pyridone, and pyrazole moieties. The synthesized dyes were characterized by UV-visible absorption, IR, (1)H NMR, and MS spectroscopy. These dyes were applied as disperse dyes for dyeing polyester fabrics and their fastness properties were evaluated. Also the position of color in CIELAB coordinates (L*, a*, b*, H*, C*) was assessed. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.07.009