o-Mercaptophenyl-diphenylarsine | 16823-73-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: o-Mercaptophenyl-diphenylarsine
• 英文别名: 1-AsPh2-2-SHC6H4；2-Diphenylarsanylbenzenethiol；2-diphenylarsanylbenzenethiol
• CAS: 16823-73-7
• 化学式: C₁₈H₁₅AsS
• 分子量: 338.305
• InChiKey: LCFZMLMCYLYISO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.49
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  o-Mercaptophenyl-diphenylarsine 在 butyloctylmagnesium 作用下， 以 正庚烷 、 甲苯 为溶剂， 反应 20.0h， 以75.3%的产率得到
  参考文献：
  名称：

  Valean, Ana-Maria; Gomez-Ruiz, Santiago; Loennecke, Peter, Revue Roumaine de Chimie, 2012, vol. 57, # 4-5, p. 293 - 303

  摘要：

  DOI：
• 作为产物：
  描述：

  (2-bromophenyl)diphenylarsine 生成 o-Mercaptophenyl-diphenylarsine
  参考文献：
  名称：

  钴（II），镍（II）和钯（II）与多齿配体的某些配合物以及配位醚和硫化物的配体场强

  摘要：

  多齿配体（o -X·C 6 H 4 ·Y·CH 2）2（X = NH 2，Y = O：ON; X = NH 2，Y = S：SN; X = NH 2，Y = NH ：NN； X = Ph 2 As，Y = O：OAS； X = Ph 2 As，Y = S：SAS）和（Y = O：ONO； Y = S：NNO； Y = NH：NNO） 。[CoCl 2（螯合物）] +（螯合物= ON，SN和NN）和[Co（螯合物）] +（螯合物= ONO，SNO和NNO）的钴（III）配合物的比较显示在钴的醚氧的配位场的强度（III）与硫化物硫相似，但低于亚氨基氮。镍（II）配合物[NiX 2（SN）]（X = Cl，Br，I和NCS）的S = 1，是八面体的，而相应的硝酸根和高氯酸盐衍生物（X = NO 3和ClO 4）可能会降低协调号。[PdX 2（螯合物）]（螯合物= ON，SN，OAS和SAS； X

  DOI：

  10.1039/j19670001277

文献信息

• Heteropolytopic Arsanylarylthiolato Ligands: Cis–Trans Isomerism of Nickel(II), Palladium(II), and Platinum(II) Complexes of 1-AsPh₂-2-SHC₆H₄
  作者：Alexandra Hildebrand、Imola Sárosi、Peter Lönnecke、Luminiţa Silaghi-Dumitrescu、Menyhárt B. Sárosi、Ioan Silaghi-Dumitrescu、Evamarie Hey-Hawkins

  DOI：10.1021/ic300002p

  日期：2012.7.2

  afforded the square-planar complexes trans-[Ni(AsS)-κ2S,As}2] (1), cis-[Pd(AsS)-κ2S,As}2] (2), trans-[Pd(AsS)-κ2S,As}2] (3), and cis-[Pt(AsS)-κ2S,As}2] (4). In the cases of nickel and platinum, only one isomer was isolated. With palladium, initially the cis isomer 2 is formed and undergoes slow isomerization to the trans isomer 3 in solution. Small amounts of the trinuclear complex [PtI(1-AsPh2-μ-2-S-C6H4-κ2S

  杂多芳基硫杂芳基配体1-AsPh 2 -2-SHC 6 H 4（AsSH），PhAs（2-SHC 6 H 4）2（AsS 2 H 2）和As（2-SHC 6 H 4）3（AsS 3 H 3）已经通过锂化-亲电取代程序制备。在2：1反应ASSH用的NiCl 2 ·6H 2 O，的Na 2 [的PdCl 4 ]和[PTI 2（COD）]（COD = 1,5-环辛二烯）在净的存在3得到正方形平面络合物反式- [镍（ASS）-κ 2小号，如} 2 ]（1），顺式- [钯（ASS）-κ 2小号，如} 2 ]（2），反式- [钯（ASS）-κ 2小号，如} 2 ]（3），以及顺式- [铂（ASS）-κ 2小号，正如} 2 ]（4）。在镍和铂的情况下，仅分离出一种异构体。与钯一起，最初形成顺式异构体2，并在溶液中缓慢地异构化为反式异构体3。少量三核的络合物[PTI（1- ASPH 2 -μ-2-SC
• When Arsine Makes the Difference: Chelating Phosphino and Bridging Arsinoarylthiolato Gallium Complexes
  作者：Ana Maria Vălean、Santiago Gómez-Ruiz、Peter Lönnecke、Ioan Silaghi-Dumitrescu、Luminiţa Silaghi-Dumitrescu、Evamarie Hey-Hawkins

  DOI：10.1021/ic801582b

  日期：2008.12.1

  The (organo)gallium compounds GaCl(SC6H4-2-PPh2)-kappa S-2,P}(2) (1), Ga(SC6H4-2-PPh2)-kappa S-2,P[(SC6H4-2-PPh2)-kappa S}(2) (2), GaMe2(SC6H4-2-PPh2)-kappa S-2} (3), (GaBu2)-Bu-t(SC6H4-2-PPh2)-kappa S-2,P) (4), (GaBu)-Bu-t((SC6H4-2-PPh2)-kappa S-2,P}(SC6H4-2-PPh2)-kappa S) (5), [GaMe2(mu(2)-SC6H4-2-AsPh2)-kappa S}](2) (6), and (GaBu)-Bu-t(SC6H4-2-AsPh2)-kappa S-2,As}(SC6H4-2-AsPh2)-kappa S} (7) were obtained from the reaction of 2-EPh2C6H4SH (E = P (PSH), As (AsSH)) with GaCl3 (1, 2) or GaR3 (R = Me, Bu-t; 3-7) in different molar ratios and under different reaction conditions. Compound 2 was also obtained from Li(PS) and GaCl3 (3.5:1). While a monomeric structure with a chelating phosphinoarylthiolato ligand is observed in GaMe2SC6H4-2-PPh2)-kappa S-2,P} (3), a dimeric arsinoarylthiolato-bridged complex [GaMe2[(mu(2)-SC6H4-2-AsPh2)-kappa S}](2) (6) is obtained with the corresponding Ass(-) ligand. B3LYP/6-31G(d) calculations show that although the dimer is thermodynamically favored for both ligands, the formation of 3 is due to the combination of higher stability of the chelate compared with the monodentate phosphorus ligand and a higher barrier for the ring opening of the PS- than of the AsS- chelate.
• Aurophilic interaction leads to distortion of the ten-membered centrosymmetric Au2As2S2C4 ring in [Au2{μ-(SC6H4-2-AsPh2)-κS,κAs}2]
  作者：Alexandra Hildebrand、Peter Lönnecke、Luminita Silaghi-Dumitrescu、Evamarie Hey-Hawkins

  DOI：10.1016/j.poly.2022.115755

  日期：2022.5
• Some complexes of cobalt(II), nickel(II), and palladium(II), with multidentate ligands and the ligand field strength of co-ordinated ethers and sulphides
  作者：R. D. Cannon、B. Chiswell、L. M. Venanzi

  DOI：10.1039/j19670001277

  日期：——

  The multidentate ligands (o-X·C6H4·Y·CH2)2(X = NH2, Y = O:ON; X = NH2, Y = S:SN; X = NH2, Y = NH:NN; X = Ph2As, Y = O:OAS; X = Ph2As, Y = S:SAS) and (Y = O:ONO; Y = S:NNO; Y = NH:NNO) have been prepared. Comparison of the complexes of cobalt(III), of the types [CoCl2(chelate)]+(chelate = ON, SN, and NN) and [Co(chelate)]+(chelate = ONO, SNO, and NNO) shows that the ligand field strength of the ether-oxygen

  多齿配体（o -X·C 6 H 4 ·Y·CH 2）2（X = NH 2，Y = O：ON; X = NH 2，Y = S：SN; X = NH 2，Y = NH ：NN； X = Ph 2 As，Y = O：OAS； X = Ph 2 As，Y = S：SAS）和（Y = O：ONO； Y = S：NNO； Y = NH：NNO） 。[CoCl 2（螯合物）] +（螯合物= ON，SN和NN）和[Co（螯合物）] +（螯合物= ONO，SNO和NNO）的钴（III）配合物的比较显示在钴的醚氧的配位场的强度（III）与硫化物硫相似，但低于亚氨基氮。镍（II）配合物[NiX 2（SN）]（X = Cl，Br，I和NCS）的S = 1，是八面体的，而相应的硝酸根和高氯酸盐衍生物（X = NO 3和ClO 4）可能会降低协调号。[PdX 2（螯合物）]（螯合物= ON，SN，OAS和SAS； X
• Valean, Ana-Maria; Gomez-Ruiz, Santiago; Loennecke, Peter, Revue Roumaine de Chimie, 2012, vol. 57, # 4-5, p. 293 - 303
  作者：Valean, Ana-Maria、Gomez-Ruiz, Santiago、Loennecke, Peter、Silaghi-Dumitrescu, Luminita、Hey-Hawkins, Evamarie

  DOI：——

  日期：——