N,N'-bis(dichlorophosphino)aniline | 39652-40-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(dichlorophosphino)aniline
• 英文别名: Imidodiphosphorous tetrachloride, phenyl-；N,N-bis(dichlorophosphanyl)aniline
• CAS: 39652-40-9
• 化学式: C₆H₅Cl₄NP₂
• 分子量: 294.872
• InChiKey: OSPHMGCJPWLCMM-UHFFFAOYSA-N

物化性质

• 沸点：
  318.7±25.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N'-bis(dichlorophosphino)aniline 在 双氧水 、 三乙胺 作用下， 以 乙醚 、 水 、 丙酮 为溶剂， 反应 28.0h， 生成 N,N-bis[bis(2-methoxyphenoxy)-oxidophosphaniumyl]aniline
  参考文献：
  名称：

  Synthesis and derivatization, structures and transition metal (Mo(0), Fe(II), Pd(II) and Pt(II)) complexes of phenylaminobis(diphosphonite), PhN{P(OC6H4OMe-o)2}2

  摘要：

  The synthesis, derivatization and coordination behavior of a new aminobis(diphosphonite), PhN{P(OC6H4OMe-o)(2)}(2) (1) is described. The ligand 1 reacts with H2O2, elemental sulfur or selenium to give the corresponding dichalcogenides PhN{P(E)(OC6H4OMe-o)(2)}(2) (E = O, 2; S, 3; Se, 4) in good yield. Reactions of 1 with Mo(CO)(6), Pd(NCCH3)(2)Cl-2 and Pt(COD)Cl-2 resulted in the formation of the chelate complexes, Mo(CO)(4)[PhN{P(OC6H4OMe-o)(2)}(2)] (5) and MCl2[PhN{P(OC6H4OMe-o)(2)}(2)] (M = Pd,7; M = Pt, 8) whereas in the reaction of 1 with [CpFe(CO)(2)](2), one of the P-N bonds cleaves due to the metal assisted hydrolysis to give a mononuclear complex, [CpFe(CO){P(O)(OC6H4OMe-o)(2)}{PhN(H)(P(OC6H4OMe-o)(2))}] (6). The molecular structures of 1, 4, 5 and 6 are determined by X-ray studies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.08.003
• 作为产物：
  描述：

  苯胺 在 三氯化磷 作用下， 生成 N,N'-bis(dichlorophosphino)aniline
  参考文献：
  名称：

  Davies,A.R. et al., Journal of the Chemical Society. Perkin transactions I, 1973, p. 379 - 385

  摘要：

  DOI：
• 作为试剂：
  描述：

  甲胺 在 N,N'-bis(dichlorophosphino)aniline 作用下， 生成 2,4,6,8,9,10-hexamethyl-2,4,6,8,9,10-hexaaza-1,3,5,7-tetraphophaadamantane
  参考文献：
  名称：

  Davies,A.R. et al., Journal of the Chemical Society. Perkin transactions I, 1973, p. 379 - 385

  摘要：

  DOI：

文献信息

• Organometallic derivatives of diphosphinoamines, X2PN(R)PX2. Reactions with carbonyl derivatives of group 6 metals and iron pentacarbonyl. The crystal structures of [Mo(CO)4PhN(P(OPh)2)2] and [W(CO)4iPrN(PPh2)2]
  作者：M.S. Balakrishna、T.K. Prakasha、S.S. Krishnamurthy、U. Siriwardane、N.S. Hosmane

  DOI：10.1016/0022-328x(90)85032-t

  日期：1990.7

  diphosphinoamines X2PN(R)PX2 (L) (R = Me or Ph, X = OCH2CF3 or OPh; R = Ph, X = OC6H4Br-p; R = iPr, X = Ph) react with group 6 metal carbonyl derivatives to yield the cis-chelate complexes [M(CO)4(L-PP′)]. The structures of cis-[Mo(CO)4PhN(P(OPh)2)2] (3d) and cis-[W(CO)4iPrN(PPh2)2] (4f) have been established by single crystal X-ray diffraction studies. Reactions with iron pentacarbonyl yield complexes

  二膦胺X 2 PN（R）PX 2（L）（R = Me或Ph，X = OCH 2 CF 3或OPh; R = Ph，X = OC 6 H 4 Br- p ; R = i Pr，X = Ph）与6族金属羰基衍生物反应生成顺式-螯合物[M（CO）4（L-PP'）]。的结构的顺式- [沫（CO）4 PHN（P（OPH）2）2 ]（3D）和顺式- [W（CO）4我PRN（PPH 2）2 ]（4F）是通过单晶X射线衍射研究确定的。与五羰基铁反应生成络合物，其中观察到配体的螯合或桥双齿配位方式。
• Synthesis and properties of new dichlorophoshinothioyl-derivatives of amines
  作者：R. Keat

  DOI：10.1039/dt9720002189

  日期：——

  amines, [Cl2P(S)]2NR and Cl2PS·NR·PCl2(R = Me, Et, or Ph), have been prepared by reactions of the bis(dichlorophosphino)-amines, (Cl2P)2NR (R = Me, Et, or Ph), with elemental sulphur in the presence of anhydrous aluminium chloride. The compounds Cl2P(S)·NR·PCl2 eliminate PCl3 when heated leaving cyclodiphosphazanes, [R·NP(S)Cl]2. Dichlorophosphinothioyl(dichlorophosphinyl)amines, Cl2P(S)·NR·P(O)Cl2(R

  胺的二氯膦硫基酰基衍生物[Cl 2 P（S）] 2 NR和Cl 2 PS·NR·PCl 2（R = Me，Et或Ph）是通过双（二氯膦基）-胺的反应制备的， （Cl 2 P）2 NR（R = Me，Et或Ph），在无水氯化铝存在下具有元素硫。化合物Cl 2 P（S）·NR·PCl 2加热时消除PCl 3，剩下环二磷氮烷[R·NP（S）Cl] 2。二氯膦硫基（二氯膦基）胺，Cl 2 P（S）·NR·P（O）Cl 2（R = Me，Ph）和双（二氯膦硫基）胺，[Cl 2 P（S）]在三乙胺存在下，通过将Cl 2 P（S）·NHR与P（O）Cl 3或P（S）Cl 3分别缩合，制得2 NR（R = Me，Ph）。在大气压力下，以上所有化合物对无水氯化氢均无反应。讨论了这些化合物的1 H和31 P nmr和ir光谱。
• Formation of cyclophosph(III)azanes and their oxo- and thioxo-derivatives
  作者：Robin Jefferson、John F. Nixon、Terence M. Painter、Rodney Keat、Leslie Stobbs

  DOI：10.1039/dt9730001414

  日期：——

  isopropylamine and t-butylamine, cyclodi-phosph(III)azans, (ClPNR)2(R = PrI and But) are obtained as major products. There is mass spectroscopic evidence for the cyclophosph(III)azans, (ClPNEt)n(n= 2 or 3) in the products from the reaction with ethylamine, but these compounds have not been obtained pure. Several other potential routes to N-methylcydophosph(III)azanes were examined, inculding the reaction of

  三氯化磷与三摩尔当量的甲胺和乙胺的反应生成双-（二氟膦基）胺（Cl 2 P）2 NR（R = Me和Et），与异丙胺和叔丁胺，环二磷（III）氮杂，（ClPNR）2（R = PR我和BU吨）作为主要产物而获得。质谱证据表明，与乙胺反应的产物中的环磷（III）氮杂（ClPNEt）n（n = 2或3），但这些化合物并非纯净。几个其它潜在路线Ñ -methylcydophosph（III检查了三氯乙烷，并注入了三氯化磷或双（二氯膦基）甲胺（Cl 2 P）2 NMe与七甲基二硅氮烷（Me 3 Si）2 NMe的反应，得到了二氯次膦胺Cl 2 P·NMe·SiMe 3（Cl 2 P）2 NMe和笼型化合物P 4（NMe）6，但未获得（ClPNMe）n类型的化合物。类似地，dichloroaiylphosphines和hepiamcthyldisilazane得到phosphinamines ClArP·NME·森达3和（ClArP）2
• Syntheses and Characterization of Ten-Membered Cyclic and Large Bite Acyclic Bis(phosphines)
  作者：Maravanji S. Balakrishna、Rashmishree Panda

  DOI：10.1080/10426500307891

  日期：2003.6

  Reaction of bis(dichlorophosphino)aniline with CH 2 bridged bis(phenols) or substituted diamine gives the 10-membered heterocyclic phosphorochloridities in quantitative yield. The bis(phenols) also react with chlorodiphenylphosphine to afford the bulky acyclic bis(phosphinites).

  双（二氯膦基）苯胺与 CH 2 桥连的双（酚）或取代的二胺反应以定量产率得到 10 元杂环磷酰氯。双（酚）也与氯二苯基膦反应，得到庞大的无环双（亚膦酸酯）。
• Short-bite aminobis(phosphonite) containing olefinic functionalities, PhN{P(OC6H3(OMe-o)(C3H5-p))2}2: Synthesis and transition metal complexes
  作者：Maravanji S. Balakrishna、Susmita Naik、S.M. Mobin

  DOI：10.1016/j.ica.2010.03.030

  日期：2010.10

  functionalities, PhNP(OC 6 H 3 (OMe- o )(C 3 H 5 - p )) 2 } 2 ( 1 ) was synthesized by reacting PhN(PCl 2 ) 2 with eugenol in the presence of triethylamine. The ligand 1 acts as a bidentate chelating ligand toward metal complexes [M(CO) 4 (C 5 H 10 NH) 2 ] forming [M(CO) 4 η 2 -PhNP(OC 6 H 3 (OMe- o )(C 3 H 5 - p )) 2 } 2 }] (M = Mo, 2 ; W, 3 ). The reaction between 1 and [CpFe(CO) 2 ] 2 leads to the cleavage

  摘要通过使PhN（PCl 2）2反应，合成了具有烯烃官能团的短咬合氨基双（亚膦酸酯）PhN P（OC 6 H 3（OMe- o）（C 3 H 5-p））2} 2（1）。在三乙胺存在下用丁子香酚。配体1充当金属配合物[M（CO）4（C 5 H 10 NH）2]的双齿螯合配体，形成[M（CO）4 η2 -PhN P（OC 6 H 3（OMe- o ）（C 3 H 5 -p））2} 2}]（M = Mo，2; W，3）。1与[CpFe（CO）2] 2之间的反应由于金属辅助水解而产生一个P–N键的裂解，从而得到单核络合物[CpFe（CO）P（O）（OC 6 H 3（OMe- o）（C 3 H 5-p））2} PhN（H）（P（OC 6 H 3（OMe- o）（C 3 H 5-p））2）}]（4） 。用金（I）衍生物[AuCl（SMe 2）]处理1导致形成双核络合物，[（AuCl）2 PhN