phosphorous trisulfide | 131105-01-6

• 分子结构分类: 无机化合物 - 均质非金属化合物
• 英文名称: phosphorous trisulfide
• 英文别名: β-P4S6
• CAS: 131105-01-6
• 化学式: P₄S₆
• 分子量: 316.291
• InChiKey: XARBDGJHTXXWFD-DUHBMQHGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.63
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  亚锑氢化物 、 phosphorous trisulfide 生成 antimony(III) sulfide
  参考文献：
  名称：

  Krafft, F.; Neumann, R., Chemische Berichte, 1901, vol. 34, p. 567 - 567

  摘要：

  DOI：
• 作为产物：
  描述：

  phosphorus sulfide 在 三苯基膦 作用下， 以 二硫化碳 为溶剂， 生成 phosphorous trisulfide
  参考文献：
  名称：

  Bjorholm; Jakobsen, Journal of the American Chemical Society, 1991, vol. 113, # 1, p. 27 - 32

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: MVol.B3, 10, page 519 - 522
  作者：

  DOI：——

  日期：——
• Baudrimont, E., Annales de Chimie et de Physique, 1864, vol. 2, p. 5 - 67
  作者：Baudrimont, E.

  DOI：——

  日期：——
• REACTIONS IN LIQUID HYDROGEN SULFIDE. III THIOHYDROLYSIS OF CHLORIDES¹
  作者：A. W. Ralston、J. A. Wilkinson

  DOI：10.1021/ja01389a002

  日期：1928.2
• Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature
  作者：Mark E. Jason、Toan Ngo、Shahidur Rahman

  DOI：10.1021/ic9614879

  日期：1997.6.1

  The oxidation of phosphorus by sulfur at low temperatures (<100 degrees C) has been shown to produce complex mixtures that include 12 of the 17 known binary phosphorus sulfides. Two of these 17 sulfides have been observed in these mixtures for the first time, The rate-determining and first step in the reaction appears to be the formation of the Ss diradical, This proposal is supported by the observed rate at which the sulfides are formed and the distribution of the sulfide product stoichiometries. Photoinitiation of this oxidation at O degrees C produces a similar array of sulfides, The differences in the product distributions between the thermal and photochemical processes facilitate the understanding of the mother-daughter relationships between the products. The effects of oxidation by sulfur and reduction by phosphorus have been determined for several of the known phosphorus sulfides. The characterizations of phosphorus compounds in molten mixtures of phosphorus and sulfur were performed by P-31 NMR and Raman spectroscopy directly on the reaction mixtures.
• Blachnik, Roger; Peukert, Ulrike; Czediwoda, Anette, Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Blachnik, Roger、Peukert, Ulrike、Czediwoda, Anette、Engelen, B.、Boldt, K.

  DOI：——

  日期：——