乙二酸钡

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 乙二酸钡
• 中文别名: 草酸钡,一水
• 英文名称: barium oxalate hydrate
• 英文别名: barium oxalate * H2O；barium oxalate monohydrate；Bariumoxalat-Monohydrat；barium(2+);oxalate;hydrate
• 化学式: Ba*C₂O₄*H₂O
• 分子量: 243.365
• InChiKey: TYPZPLBGEPGJFK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -4.72
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.3
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  乙二酸钡 以 neat (no solvent) 为溶剂， 生成 barium carbonate
  参考文献：
  名称：

  Kinetic study of Y, Ba, Cu oxalates and coprecipitated Y-Ba-Cu oxalate

  摘要：

  The kinetics of the decomposition of Y, Ba and Cu oxalates and coprecipitanted Y-Ba-Cu oxalate was investigated under a nitrogen atmosphere on the basis of dynamic thermogravimetric data, the average activation energies of the decomposition of Y, Ba and Cu oxalates were obtained from the slopes of the T. Ozawa plot.The average activation energies for the dehydration of these oxalate and coprecipitated Y-Ba-Cu oxalate were also evaluated from the thermogravimetric curves.

  DOI：

  10.1007/bf02719031
• 作为产物：
  描述：

  草酸氢铵(一水) 在 barium(II) chloride dihydrate 作用下， 生成 乙二酸钡
  参考文献：
  名称：

  草酸钡半水合物的振动光谱

  摘要：

  摘要 草酸钡半水合物 BaC2O4·0.5H2O 的红外和拉曼光谱被记录和讨论，基于它们的结构特性并与先前研究的草酸钙和锶的光谱进行比较。

  DOI：

  10.1080/00387010.2015.1133651

文献信息

• Precision of a crystal structure derived from a synchrotron X-ray powder pattern. The structure of Barium oxalate hydrate, BaC2O4·2H2O
  作者：A.Nørlund Christensen、R.G. Hazell、A.M.T. Bell、A. Altomare

  DOI：10.1016/0022-3697(95)00070-4

  日期：1995.10

  The crystal structure of barium oxalate hydrate, BaC204.2H20, was reinvestigated using a synchrotron X-ray powder pattern and a single crystal X-ray data set. The compound is monoclinic, a = 7.538(l), b = 11.062(l), c = 7.105(1) angstroms, beta = 105.42(l)“, space group P21/c, with Z = 4. The precision of the structure arrived at with the synchrotron X-ray powder pattern is not as high as that obtained

  使用同步加速器 X 射线粉末图案和单晶 X 射线数据集重新研究草酸钡水合物 BaC2O4.2H2O 的晶体结构。该化合物为单斜晶系，a = 7.538(l), b = 11.062(l), c = 7.105(1) 埃，β = 105.42(l)"，空间群 P21/c，Z = 4。用同步加速器 X 射线粉末图得到的结构不如用单晶 X 射线数据得到的结构高。钡原子与 键合。草酸根离子和水分子之间具有 2.71(l)-2.97(l) 埃范围内的 9 个钡氧键。该结构具有范围为 2.72(2)-2.91(2) 埃的氢键，并且草酸根离子与平面性的偏差很小。
• The thermal decomposition of oxalates. Part 18. The preparation and thermal decomposition of acid barium oxalates
  作者：Asif.S. Bhatti、David Dollimore、Albert Fletcher

  DOI：10.1016/0040-6031(84)87133-6

  日期：1984.7

  study entails the preparation of various forms of barium oxalate. The main method of preparation used was the simultaneous mixing of equimolar solutions of barium chloride and oxalic acid over a range of concentrations of starting materials from 0.2 to 1.6 mol. Each compound was analysed for its percentage of barium, oxalate and water content. Thermogravimetric and differential thermal analysis data were

  摘要 本研究涉及各种形式的草酸钡的制备。所用的主要制备方法是将氯化钡和草酸的等摩尔溶液在 0.2 至 1.6 mol 的起始材料浓度范围内同时混合。分析每种化合物的钡、草酸盐和水含量的百分比。获得了热重和差热分析数据，并通过与化学分析数据的比较来验证结果。结果表明，改变制备条件会产生化学成分不同的草酸钡形式。
• Controlled synthesis of barium chromate multi-layered microdiscs and their photocatalytic activity
  作者：Mattawan Japa、Patchareeporn Panoy、Supanan Anuchai、Sukon Phanichphant、Piyarat Nimmanpipug、Sulawan Kaowphong、Doldet Tantraviwat、Burapat Inceesungvorn

  DOI：10.1039/c5ra23482d

  日期：——

  BaCrO₄ microdiscs composed of multi-layered microplates were successfully synthesized by a facile oxalate-assisted precipitation method. Based on time-dependent experiments, a dissolution–recrystallization–self-assembly process has been proposed.

  BaCrO₄ 微盘由多层微板组成，通过简便的草酸辅助沉淀法成功合成。基于时间依赖性实验，提出了一种溶解-再结晶-自组装过程。
• Grain size dependence of the critical current density in YBa₂Cu₃O_<i>x</i>superconductors
  作者：M. Kuwabara、H. Shimooka

  DOI：10.1063/1.102373

  日期：1989.12.25

  The grain size dependence of the critical current density in bulk single‐phase YBa2Cu3Ox ceramics was investigated. The grain size of the materials was changed to range approximately from 1.0 to 25 μm by changing the conditions of power processing and sintering, associated with an increase in the sintered density of the materials with increasing grain size. The critical current density has been found

  研究了大块单相 YBa2Cu3Ox 陶瓷中临界电流密度的晶粒尺寸依赖性。通过改变功率加工和烧结条件，材料的晶粒尺寸改变到大约 1.0 到 25 μm 的范围，这与材料的烧结密度随着晶粒尺寸的增加而增加有关。已经发现临界电流密度表现出显着的晶粒尺寸依赖性，从 880 A/cm2 变为 100 A/cm2 的值，平均晶粒尺寸从 1.2 到 2.0 μm 略有增加。这似乎提供了有关可能控制材料临界电流密度的超导晶粒之间薄弱环节性质的信息。
• The importance of the CO 2 2− anion in the mechanism of thermal decomposition of oxalates
  作者：A. Górski、A. D. Kraśnicka

  DOI：10.1007/bf01905177

  日期：1987.7