9,9'-bis(4-hydroxyphenyl)-10-anthrone | 16889-49-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,9'-bis(4-hydroxyphenyl)-10-anthrone
• 英文别名: 9,9'-bis(4-hydroxyphenyl)anthrone-10；10,10-bis-(4-hydroxy-phenyl)-anthrone；10,10-Bis-(4-hydroxy-phenyl)-anthron；10,10 bis-(4-hydroxyl phenyl) anthrone；10,10-bis(4-hydroxyphenyl)anthrone；9,9-Bis(4-hydroxyphenyl)-10-anthron；10,10-bis(4-hydroxyphenyl)-9(10H)-anthracenone；10,10-bis(4-hydroxyphenyl)anthracen-9-one
• CAS: 16889-49-9
• 化学式: C₂₆H₁₈O₃
• 分子量: 378.427
• InChiKey: ZDSPTFQHKJLGFQ-UHFFFAOYSA-N

物化性质

• 熔点：
  305-306 °C
• 沸点：
  561.2±50.0 °C(Predicted)
• 密度：
  1.322±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  29
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  9,9'-bis(4-hydroxyphenyl)-10-anthrone 在 sodium hydroxide 、 苯 作用下， 生成 10-Hydroxy-9.9.10-tris-(4-methoxy-phenyl)-9.10-dihydro-anthracen
  参考文献：
  名称：

  Hydroxy- and Methoxyphenylanthrones. II

  摘要：

  DOI：

  10.1021/ja01278a027
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 三氯化铝 作用下， 生成 9,9'-bis(4-hydroxyphenyl)-10-anthrone
  参考文献：
  名称：

  Scharwin; Naumow; Gandurin, Chemische Berichte, 1904, vol. 37, p. 3620

  摘要：

  DOI：

文献信息

• [EN] BINAPHTHYL COMPOUNDS<br/>[FR] COMPOSÉS BINAPHTYLE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019043060A1

  公开（公告）日：2019-03-07

  The present invention relates to binaphthyl compounds of the formula (I), which are suitable as monomers for preparing polycarbonate resins having beneficial optical properties and which can be used for producing optical lenses: Formula (I) where X is C2-C4-alkandiyl or C1-C4-alkandiyl-C(O)-, where C(O) is bound to the oxygen atom of the hydroxyl group and where C2-C4-alkandiyl or C1-C4-alkandiyl, respectively, are unsubstituted or carry a phenyl ring; R and R' are identical or different and selected from mono or polycyclic aryl having from 6 to 36 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 36 atoms, which are ring members, where 1, 2, 3 or 4 of these atoms are selected from nitrogen, sulfur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl and mono- or polycyclic hetaryl are unsubstituted or carry 1 or 2 radicals Ra, which are selected from the group consisting of CN, CH3, OCH3, O-phenyl, O-naphthyl, S-phenyl, S-naphthyl, CI or F; and, if X is C1-C4-alkandiyl-C(O)-, the esters thereof, in particular the C1-C4-aIkyIesters thereof.

  本发明涉及通式(I)的双萘基化合物，其适于作为单体用于制备具有有益光学性能的聚碳酸酯树脂，并可用于生产光学透镜：式(I)中，X为C2-C4-亚烷基或C1-C4-亚烷基-C(O)-，其中C(O)键合于羟基的氧原子上，且所述C2-C4-亚烷基或C1-C4-亚烷基分别为未取代的或带有苯环；R和R'相同或不同，选自具有6至36个碳原子的单环或多环芳基以及具有总共5至36个原子的单环或多环杂芳基，这些原子为环成员，其中1、2、3或4个原子选自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基和单环或多环杂芳基为未取代的或带有1或2个选自CN、CH3、OCH3、O-苯基、O-萘基、S-苯基、S-萘基、Cl或F的基团Ra；并且，如果X为C1-C4-亚烷基-C(O)-，则为其酯，特别是其C1-C4-烷基酯。
• Azine-based dimeric charge transport materials
  申请人：——

  公开号：US20040265717A1

  公开（公告）日：2004-12-30

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula 1 where R 1 , R 2 , R 3 , and R 4 comprise, each independently, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a ring group; X and X′ comprise, each independently, an aromatic group; Y and Y′ comprise, each independently, a (disubstituted)methylene group; and Z is a linking group; (b) a charge generating compound; and (c) an electrically conductive substrate on which said charge transport material and said charge generating compound are located. Corresponding electrophotographic apparatuses and imaging methods are also described.

  改进的有机光感受器包括一个电导基底和位于电导基底上的光电导元件，所述光电导元件包括： (a) 具有下列结构式1的电荷传输材料： 其中，R1、R2、R3和R4分别独立地包括烷基、烯基、芳香基、杂环基或环基的一部分； X和X'分别独立地包括芳香基； Y和Y'分别独立地包括(二取代)亚甲基基团； Z是一个连接基团； (b) 一个电荷生成化合物；以及 (c) 位于所述电导基底上的所述电荷传输材料和所述电荷生成化合物。 还描述了相应的电子照相设备和成像方法。
• Linked dihydrazone-based charge transport compounds
  申请人：——

  公开号：US20030232264A1

  公开（公告）日：2003-12-18

  Improved organophotoreceptors comprise: (a) a charge transport compound having the formula 1 where n is an integer from 0 to 1; X is an (N,N-disubstituted)arylamine group; Ar is an aryl group or a heterocyclic group; A is a first linking group with the formula —(CH 2 ) p — which can be branched or linear, where p is an integer from 3 to 20 inclusive and where one or more methylene groups can be optionally replaced by O, S, a carbonyl group, urethane, urea, an ester group, a —NR 21 group, a CHR 22 group, or a CR 23 R 24 group where R 21 , R 22 , R 23 and R 24 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, an aryl group, or part of a ring; and B is a second linking group having the formula -Q-Z-Q′-, where Q and Q′ are, independently, O, S, or NR 1 ; wherein when Q or Q′ is NR 1 or Q=O and Q′=S, Z comprises an aryl group, and wherein when Q=Q′=S or Q=Q′=O, Z comprises a multi-ring conjugated group or —Y—W—Y′— wherein Y and Y′ comprise, independently, an aryl group and W comprises a CR 2 R 3 group; wherein R 1 is hydrogen or comprises an alkyl group or an aryl group; R 2 is a hydrogen or comprises an alkyl group, or an aryl group; and R 3 comprises an alkyl group or an aryl group or may form a ring structure along with the R 2 group; (b) a charge generating compound; and (c) an electrically conductive substrate over which said charge transport compound and said charge generating compound are located.

  改进的有机光受体包括：(a) 具有下列结构的电荷传输化合物：其中 n 是从 0 到 1 的整数；X 是 (N,N-二取代)芳胺基团；Ar 是芳基团或杂环基团；A 是具有下列结构的第一连接基团，—(CH2)p—，其中 p 是从 3 到 20 的整数，其中一个或多个亚甲基基团可以选择性地被 O、S、羰基、脲、尿素、酯基团、—NR21基团、CHR22基团或 CR23R24基团取代，其中 R21、R22、R23 和 R24 独立地是 H、羟基、硫醇基、胺基团、烷基团、烷芳基团、芳基团或环的一部分；B 是具有下列结构的第二连接基团，-Q-Z-Q′-，其中 Q 和 Q′ 独立地是 O、S 或 NR1；当 Q 或 Q′ 是 NR1 或 Q=O 且 Q′=S 时，Z 包括芳基团，当 Q=Q′=S 或 Q=Q′=O 时，Z 包括多环共轭基团或 —Y—W—Y′—，其中 Y 和 Y′ 独立地是芳基团，W 包括 CR2R3基团；其中 R1 是氢或包括烷基团或芳基团；R2 是氢或包括烷基团或芳基团；R3 包括烷基团或芳基团或可能与 R2 基团一起形成环结构；(b) 电荷生成化合物；和 (c) 电导底物，其上覆盖有所述电荷传输化合物和所述电荷生成化合物。
• Organophotoreceptor with a charge transport material having two (9-fluorenylidene) malononitrile groups
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1452925A1

  公开（公告）日：2004-09-01

  The present invention provides an organophotoreceptor comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula         X―Z―X'    where X and X' are, each independently, a (9-fluorenylidene)malononitrile group, and Z is a linking group having the formula -(CH2)m-, branched or linear, where m is an integer between 1 and 30, inclusive, and one or more of the methylene groups may be replaced by O, S, C=O, Si=O, S(=O)2, P(=O)2, an aromatic group, a heterocyclic group, an aliphatic cyclic group, a Si(R1)(R2) group, a BR3 group, a NR4 group, a CHR5 group, or a CR6R7 group where R1, R2, R3, R4, R5, R6, and R7 are, each independently, H, halogen, hydroxyl, thiol, an alkoxy group, an alkyl group, an alkenyl group, an aromatic group, a heterocyclic group, or a part of a cyclic ring; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

  本发明提供了一种有机光感受器，包括具有电导底板和位于电导底板上的光电元件，所述光电元件包括：(a) 具有以下结构式的电荷传输材料X-Z-X'，其中X和X'各自独立地为(9-芴基亚甲基)马隆腈基团，Z为具有以下结构式的连接基-(CH2)m-，其中m为1到30之间的整数，包括1和30，并且一个或多个亚甲基基团可以被O、S、C=O、Si=O、S(=O)2、P(=O)2、芳香族基、杂环基、脂环基、Si(R1)(R2)基、BR3基、NR4基、CHR5基或CR6R7基取代；以及(b) 电荷生成化合物。描述了相应的电子照相设备和成像方法。
• [EN] TRIARYLMETHANE COMPOUNDS<br/>[FR] COMPOSÉS DE TRIARYLMÉTHANE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019154727A1

  公开（公告）日：2019-08-15

  The present invention relates to triarylmethane compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. (I) where R1, R2 are e.g. hydrogen; Y is an alkylene group having 2, 3 or 4 carbon atoms, Ar is selected from mono-or polycyclic aryl and mono-or polycyclic hetaryl; X1, X2, X3, X4 are CH, C-Rx or N, provided that in each ring at most two of X1, X2, X3, X4 are N; Rx is e.g. halogen, CN or CH=CH2. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I).

  本发明涉及具有以下式（I）的三芳基甲烷化合物，该化合物适用作为制备具有有益光学性能的热塑性树脂的单体，并可用于生产光学器件。其中R1，R2例如是氢；Y是具有2、3或4个碳原子的烷基基团，Ar选自单环或多环芳基和单环或多环杂芳基；X1、X2、X3、X4是CH、C-Rx或N，要求在每个环中最多有两个是N；Rx例如是卤素、CN或CH=CH2。该发明还涉及包含具有上述式（I）化合物的聚合单元的热塑性树脂。