N-羟基-3,3'-亚氨基二丙酸 | 89531-79-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: N-羟基-3,3'-亚氨基二丙酸
• 中文别名: N-羟基-3,3’-亚氨基二丙酸
• 英文名称: N-(2-carboxyethyl)-N-hydroxy-beta-Alanine
• 英文别名: 3-[2-carboxyethyl(hydroxy)amino]propanoic acid
• CAS: 89531-79-3
• 化学式: C₆H₁₁NO₅
• 分子量: 177.16
• InChiKey: GOKVSLADUAKALT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.5
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  98.1
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  羟胺 、 丙烯酸 在 水 作用下， 以 甲醇 为溶剂， 反应 32.5h， 以to give 30.4 g (85%) of the desired compound的产率得到N-羟基-3,3'-亚氨基二丙酸
  参考文献：
  名称：

  Method for preparing hydroxylamines using vinylic compounds without base

  摘要：

  在适当的溶剂中，通过将羟胺与带有电子提取取代基的乙烯化合物反应，可以制备用于摄影处理溶液的取代羟胺。在没有中和碱的情况下，可以直接使用反应溶液中的产物，无需分离。

  公开号：

  US05646327A1

文献信息

• Inhibition of pulp and paper yellowing using hydroxylamines and other coadditives
  申请人：——

  公开号：US20020174964A1

  公开（公告）日：2002-11-28

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio item substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，尤其是化学机械或热机械纸浆或纸张，如果它们含有有效稳定剂量的N,N-二烷基羟胺、酯、酰胺或硫代物取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，它们具有增强的抗黄变性能。当它们与紫外线吸收剂、聚合抑制剂、亚硝基化合物、荧光增白剂和金属螯合剂等共添加剂之一或多个存在时，这种性能通常会进一步增强。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐对此具有惊人的有效性。羟胺或其盐、苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。
• Method for preparing hydroxylamines using vinylic compounds without base
  申请人：Eastman Kodak Company

  公开号：US05646327A1

  公开（公告）日：1997-07-08

  Substituted hydroxylamines useful in photographic processing solution can be prepared by reacting a hydroxylamine with a vinylic compound having an electron withdrawing substituent in a suitable solvent, in the absence of a neutralizing base. The resulting products can be used without isolation from the reaction solution.

  在适当的溶剂中，通过将羟胺与带有电子提取取代基的乙烯化合物反应，可以制备用于摄影处理溶液的取代羟胺。在没有中和碱的情况下，可以直接使用反应溶液中的产物，无需分离。
• Ink jet ink and recording material
  申请人：——

  公开号：US20040126510A1

  公开（公告）日：2004-07-01

  The present invention relates to an ink jet ink, an ink jet recording material or an ink jet system comprising at least one sterically hindered N-hydroxylamine strong acid salt, for example 1-hydroxy-2,2,6,6-tetramethyl-4-hydroxypiperidinium chloride or bis(1-hydroxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate dihydrochloride; or comprising at least one dialkyl N-hydroxylamine salt, for example chloride, bisulfate, sulfate, phosphate, nitrate, ascorbate, formate, acetate, benzoate, oxalate, citrate, a carboxylate of ethylenediaminetetraacetic acid or of diethylenetriaminepentaacetic acid or polyacrylate salts of N,N-diethylhydroxylamine, N,N-bis(2-hydroxypropyl)hydroxylamine, N,N-bis(3-hydroxypropyl)hydroxylamine, N,N-dibenzylhydroxylamine or the N,N-di(alkyl)hydroxylamine produced by the direct oxidation of N,N-di(hydrogenated tallow)amine.

  本发明涉及一种喷墨墨水、喷墨记录材料或喷墨系统，其包含至少一种立体位阻的N-羟胺强酸盐，例如1-羟基-2,2,6,6-四甲基-4-羟基哌啶盐酸盐或双(1-羟基-2,2,6,6-四甲基哌啶-4-基)癸二酸二盐酸盐；或包含至少一种双烷基N-羟胺盐，例如氯化物、硫酸氢盐、硫酸盐、磷酸盐、硝酸盐、抗坏血酸盐、甲酸盐、乙酸盐、苯甲酸盐、草酸盐、柠檬酸盐、乙二胺四乙酸或二乙三胺五乙酸的羧酸盐或N,N-二乙基羟胺、N,N-双(2-羟基丙基)羟胺、N,N-双(3-羟基丙基)羟胺、N,N-二苄基羟胺或通过N,N-二(氢化牛脂)胺的直接氧化产生的N,N-二(烷基)羟胺。
• INHIBITION OF PULP AND PAPER YELLOWING USING HYDROXYLAMINES AND OTHER COADDITIVES
  申请人：——

  公开号：US20020088574A1

  公开（公告）日：2002-07-11

  Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a N,N-dialkylhydroxylamine, an ester, amide or thio substituted N,N-dialkylhydroxylamine or N,N-dibenzylhydroxylamine or an amminium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents and metal chelating agents. Combinations of hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. N,N-Diethylhydroxylamine and N,N-dibenzylhydroxylamine and their acid salts are surprisingly effective for this purpose.

  含有木质素的纸浆或纸张，特别是化学机械或热机械纸浆或纸张，如果它们含有有效稳定量的N,N-二烷基羟胺，酯，酰胺或硫代取代的N,N-二烷基羟胺或N,N-二苄基羟胺或其铵盐，则具有增强的抗黄变性能。当其中还存在来自紫外线吸收剂，聚合抑制剂，亚硝基，荧光增白剂和金属螯合剂的一种或多种辅助剂时，这种性能通常会进一步增强。羟胺或其盐，苯并三唑或苯并酚紫外线吸收剂和金属螯合剂的组合特别有效。N,N-二乙基羟胺和N,N-二苄基羟胺及其酸盐出人意料地有效。
• A photographic processing composition and a processing process therewith
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0649057A2

  公开（公告）日：1995-04-19

  A processing composition for a silver halide photographic material, which comprises at least one of Fe (III), Mn (III), Co (III), Rh (II), Rh (III), Au (II), Au (III), and Ce (IV) chelate compounds of a compound represented by formula (I) or a salt thereof: wherein R1 represents a hydrogen atom, an aliphatic group or an aromatic group; R2 represents an aromatic group; L3 represents a divalent aliphatic group; n represents 0 or 1; X1 represents a hydrogen atom or -L4-A2; L1, L2 and L4 each represents a divalent aliphatic group, a divalent aromatic group, or a divalent linkage group comprising a combination thereof; A1 and A2 each represent a carboxy group, a phosphono group, a sulfo group, or a hydroxy group; and Z represents an oxygen atom or a sulfur atom.

  一种用于卤化银感光材料的冲洗组合物，它包含由式 (I) 所代表的化合物或其盐组成的 Fe (III)、Mn (III)、Co (III)、Rh (II)、Rh (III)、Au (II)、Au (III) 和 Ce (IV) 螯合物中的至少一种： 其中 R1 代表氢原子、脂肪族基团或芳香族基团；R2 代表芳香族基团；L3 代表二价脂肪族基团；n 代表 0 或 1；X1 代表氢原子或 -L4-A2；L1、L2 和 L4 分别代表二价脂肪族基团、二价芳香族基团或由其组合而成的二价连接基团；A1 和 A2 分别代表羧基、膦基、磺基或羟基；Z 代表氧原子或硫原子。