(undecamethylcyclohexasilanyl)triphenylstannane | 299438-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (undecamethylcyclohexasilanyl)triphenylstannane
• CAS: 299438-03-2
• 化学式: C₂₉H₄₈Si₆Sn
• 分子量: 683.923
• InChiKey: ZQGLFLFPFDBZAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.22
• 重原子数：
  36
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (undecamethylcyclohexasilanyl)triphenylstannane 在 O₂ 作用下， 以 neat (no solvent, solid phase) 为溶剂， 生成 六苯基二锡
  参考文献：
  名称：

  Cyclohexasilanes with exocyclic organogermanium, -tin or -lead groups

  摘要：

  A new class of mono- (2- 4) and bis(undecamethylcyclohexasilanyl) (5-9) substituted germanium, tin and lead compounds is described. These molecules are accessible by treatment of undecamethylcyclohexasilanyl potassium (1) with chlorogermanes, -stannanes or plumbanes. Attempts to generate bis(cyclohexasilanyl)methanes, -plumbanes or tris(cyclohexasilanyl)-methylstannane starting from dihalomethanes, -plumbanes or methyltrichlorostannane and 1 result only in transmetallation reactions. The molecular structures of a mono- (3) and a dicyclohexasilanyl stannane derivative 5 were determined by single-crystal X-ray crystallography. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00249-7
• 作为产物：
  描述：

  三苯基氯化锡 、 undecamethylcyclohexasilanyl potassium 以 四氢呋喃 、 乙醇 、 二乙二醇二甲醚 为溶剂， 以77%的产率得到(undecamethylcyclohexasilanyl)triphenylstannane
  参考文献：
  名称：

  Cyclohexasilanes with exocyclic organogermanium, -tin or -lead groups

  摘要：

  A new class of mono- (2- 4) and bis(undecamethylcyclohexasilanyl) (5-9) substituted germanium, tin and lead compounds is described. These molecules are accessible by treatment of undecamethylcyclohexasilanyl potassium (1) with chlorogermanes, -stannanes or plumbanes. Attempts to generate bis(cyclohexasilanyl)methanes, -plumbanes or tris(cyclohexasilanyl)-methylstannane starting from dihalomethanes, -plumbanes or methyltrichlorostannane and 1 result only in transmetallation reactions. The molecular structures of a mono- (3) and a dicyclohexasilanyl stannane derivative 5 were determined by single-crystal X-ray crystallography. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00249-7

文献信息

• Cyclohexasilanes with exocyclic organogermanium, -tin or -lead groups
  作者：U Englich、E Hengge、U Hermann、C Marschner、K Ruhlandt-Senge、F Uhlig

  DOI：10.1016/s0022-328x(00)00249-7

  日期：2000.6

  A new class of mono- (2- 4) and bis(undecamethylcyclohexasilanyl) (5-9) substituted germanium, tin and lead compounds is described. These molecules are accessible by treatment of undecamethylcyclohexasilanyl potassium (1) with chlorogermanes, -stannanes or plumbanes. Attempts to generate bis(cyclohexasilanyl)methanes, -plumbanes or tris(cyclohexasilanyl)-methylstannane starting from dihalomethanes, -plumbanes or methyltrichlorostannane and 1 result only in transmetallation reactions. The molecular structures of a mono- (3) and a dicyclohexasilanyl stannane derivative 5 were determined by single-crystal X-ray crystallography. (C) 2000 Elsevier Science S.A. All rights reserved.