(4E,7E)-Trideca-4,7-dienal | 1365566-75-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (4E,7E)-Trideca-4,7-dienal
• 英文别名: 4,7-Tridecadienal
• CAS: 1365566-75-1；91975-41-6
• 化学式: C₁₃H₂₂O
• 分子量: 194.317
• InChiKey: OVCWJANYDKDLMS-AVQMFFATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (E)-十一碳-1,5-二烯-3-醇 在 mercury(II) diacetate 作用下， 以 四氢呋喃 为溶剂， 生成 (4E,7E)-Trideca-4,7-dienal
  参考文献：
  名称：

  SEQUENTIAL [2,3]WITTIG AND CLAISEN REARRANGEMENT: A FACILE SYNTHETIC METHOD FOR (E,E)-4,7-ALKADIENALS AND -ALKADIENOIC ACIDS. A NEW FORMAL SYNTHESIS OF (±)-CERULENIN

  摘要：

  双烯丙基醚的亲区选择性[2,3]Wittig重排，以及随后的Claisen重排，可以方便地得到（E,E）-4,7-烯丙二烯醛和烯丙二烯酸。在具有多种生物活性的（±）-青霉烯素的新形式合成中，展示了西格马拓扑序列的多功能性。

  DOI：

  10.1246/cl.1981.1721

文献信息

• FLAVOR MODULATOR HAVING PYRIDINE DERIVATIVE OR SALT THEREOF AS ACTIVE INGREDIENT
  申请人：T. HASEGAWA CO., LTD.

  公开号：US20180072670A1

  公开（公告）日：2018-03-15

  2-(phenylalkyloxyalkyl)pyridine derivative or a 2-(phenylalkylthioalkyl)pyridine derivative imparts, when added to food and drink or cosmetics as an active ingredient, a flavor of natural impression thereto; and in particular, when added to food and drink, the compound imparts an umami imparting or enhancing, a saltiness enhancing a sweetness enhancing, and in particular, when added to a milk or dairy product, a food or drink product containing a milk or dairy product, or a dairy replacement product, the compound provides a milk richness enhancing.

  2-(苯基烷氧基烷基)吡啶衍生物或2-(苯基烷硫基烷基)吡啶衍生物，当作为食品、饮料或化妆品的活性成分添加时，赋予其一种天然印象的风味；特别是当添加到食品和饮料中时，该化合物赋予了一种鲜味、增强了咸味和甜味，特别是当添加到牛奶或乳制品中时，该化合物提供了增强奶香的效果。
• [EN] FRAGRANCE AND FLAVOR COMPOSITIONS CONTAINING ISOMERIC ALKADIENALS OR ISOMERIC ALKADIENENITRILES<br/>[FR] COMPOSITION AROMATISÉE OU PARFUMÉE CONTENANT DES ALCADIÉNALS ISOMÈRES OU DES ALCADIÈNENITRILES ISOMÈRES
  申请人：BEDOUKIAN RES INC

  公开号：WO2017100426A1

  公开（公告）日：2017-06-15

  A composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A consumer product containing the fragrance or flavor composition having at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the composition. A method of imparting a fragrance or flavor to a consumer product by adding to the consumer product a fragrance or flavor composition containing at least one isomeric alkadienal or at least one isomeric alkadienenitrile in an amount effective to impart a fragrance or flavor to the consumer product.

  一种含有至少一种异构的烯二醛或至少一种异构的烯二腈的组合物，其量足以赋予组合物香味或风味。一种香味或风味组合物，其中含有至少一种异构的烯二醛或至少一种异构的烯二腈，其量足以赋予组合物香味或风味。一种含有香味或风味组合物的消费品，其中至少含有一种异构的烯二醛或至少一种异构的烯二腈，其量足以赋予组合物香味或风味。一种通过向消费品添加含有至少一种异构的烯二醛或至少一种异构的烯二腈的香味或风味组合物的方法，以在消费品中赋予香味或风味。
• PERFUME COMPOSITIONS CONTAINING ISOMERIC ALKADIENALS
  申请人：BEDOUKIAN RESEARCH, INC.

  公开号：US20160052855A1

  公开（公告）日：2016-02-25

  A perfume composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. The isomers of 4,8-undecadienal comprise Z,Z-4,8-undecadienal, E,E-4,8-undecadienal, and mixed Z/E isomers of 4,8-undecadienal; the isomers of 4,9-dodecadienal comprise Z,Z-4,9-dodecadienal, E,E-4,9-dodecadienal, and mixed Z/E isomers of 4,9-dodecadienal; and the isomers of 4,10-tridecadienal comprise Z,Z-4,10-tridecadienal, E,E-4,10-tridecadienal, and mixed Z/E isomers of 4,10-tridecadienal. A composition comprising an effective amount of at least one alkadienal selected from 4,8-undecadienal and isomers thereof, 4,9-dodecadienal and isomers thereof, and 4,10-tridecadienal and isomers thereof. Processes for the preparation of the isomer mixtures of alkadienals are provided. The isomeric alkadienals have a range of fresh, watery, ozone, grapefruit, tangerine, orange peel, aldehydic notes of exceptional strength.

  一种香水组合物，包括有效量的至少一种选择自4,8-十一烯醛及其异构体、4,9-十二烯醛及其异构体和4,10-十三烯醛及其异构体的烯醛。4,8-十一烯醛的异构体包括Z,Z-4,8-十一烯醛、E,E-4,8-十一烯醛和混合的Z/E异构体；4,9-十二烯醛的异构体包括Z,Z-4,9-十二烯醛、E,E-4,9-十二烯醛和混合的Z/E异构体；4,10-十三烯醛的异构体包括Z,Z-4,10-十三烯醛、E,E-4,10-十三烯醛和混合的Z/E异构体。组合物包括有效量的至少一种选择自4,8-十一烯醛及其异构体、4,9-十二烯醛及其异构体和4,10-十三烯醛及其异构体的烯醛。提供制备烯二醛异构体混合物的过程。异构烯二醛具有一系列新鲜、水、臭氧、葡萄柚、橘子、橙皮、醛类的气味，具有异常强的香气。
• ACID TASTE/ACID SMELL-REDUCING AGENT
  申请人：Haraguchi Kenji

  公开号：US20140120232A1

  公开（公告）日：2014-05-01

  Provided is an acid taste and/or acid smell-reducing agent that can effectively reduce acid taste/acid smell without adding off-taste and off-smell. The acid taste and/or acid smell-reducing agent is composed of 4,7-tridecadienal and/or 2,4,7-tridecatrienal and is added to a food or drink having acid taste and/or acid smell.

  提供了一种酸味和/或酸味减少剂，可以有效地减少酸味/酸味，而不会添加异味和异味。该酸味和/或酸味减少剂由4,7-十三烯醛和/或2,4,7-十三烯三醛组成，并添加到具有酸味和/或酸味的食品或饮料中。
• Perfume compositions and perfumed products which contain one or more 4,7-alkadienals as the essential substance
  申请人：NAARDEN INTERNATIONAL N.V.

  公开号：EP0173395A1

  公开（公告）日：1986-03-05

  Perfume compositions and perfumed products containing as perfume component one or more 4,7-alkadienals with the formula wherein R represents a straight-chain or branched-chain alkyl or alkenyl group containing 2-5 carbon atoms and wherein the 4-5 double bond has the cis-configuration and the 7-8 double bond can have the cis or trans configuration.

  含有一种或多种 4,7-烷二烯醛的香水组合物和香水产品，其配方中 R 代表含有 2-5 个碳原子的直链或支链烷基或烯基，其中 4-5 双键为顺式构型，7-8 双键可为顺式或反式构型。