diethyl meso-2,5-diazidoadipate | 1123788-33-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diethyl meso-2,5-diazidoadipate
• 英文别名: Diethyl 2,5-diazidoadipate；diethyl 2,5-diazidohexanedioate
• CAS: 1123788-33-9
• 化学式: C₁₀H₁₆N₆O₄
• 分子量: 284.275
• InChiKey: YQLKWVWPZCLUGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  81.3
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  diethyl meso-2,5-diazidoadipate 在 platinum(II) oxide 盐酸 、 氢气 作用下， 以 乙醇 为溶剂， 生成 2.5-Diaminoadipinsaurediathylester
  参考文献：
  名称：

  The synthesis of symmetrical bis-1,2,5-thiadiazole ligands

  摘要：

  We have been engaged in a search for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate) with ethylene. We have been investigating complexes of late transition metals with heterocyclic ligands. In this report we describe the synthesis of a symmetrical bis-thiadiazole. We have characterized one of the intermediates using single crystal X-ray diffraction. Several unsuccessful approaches toward 1 are also described, which shed light on some of the unique chemistry of thiadiazoles. (C) 2004 lsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.05.045
• 作为产物：
  描述：

  2,5-二溴己二酸二乙酯 在 sodium azide 作用下， 以 水 、 乙腈 为溶剂， 反应 24.0h， 生成 diethyl meso-2,5-diazidoadipate
  参考文献：
  名称：

  It Is the Outside That Counts: Chemical and Physical Control of Dynamic Surfaces

  摘要：

  Materials capable of dynamically controlling surface chemistry and topography are highly desirable. We have designed a system that is uniquely able to remotely control the presented functionality and geometry at a given time by using a functionalizable shape memory material. This was accomplished by incorporating controlled amounts of an azide-containing monomer into a shape memory polymeric material. These materials are capable of physically changing surface geometry over a broad range of length scales from >1 mm to 100 nm. Using copper-assisted click chemistry, they can be functionalized with a variety of molecules to yield different surfaces. Combining these features gave materials that can change both the presented geometry and functionality at tunable transition temperatures.

  DOI：

  10.1021/ja308080g

文献信息

• The synthesis of symmetrical bis-1,2,5-thiadiazole ligands
  作者：Dean M. Philipp、Rick Muller、William A. Goddard、Khalil A. Abboud、Michael J. Mullins、R.Vernon Snelgrove、Phillip S. Athey

  DOI：10.1016/j.tetlet.2004.05.045

  日期：2004.7

  We have been engaged in a search for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate) with ethylene. We have been investigating complexes of late transition metals with heterocyclic ligands. In this report we describe the synthesis of a symmetrical bis-thiadiazole. We have characterized one of the intermediates using single crystal X-ray diffraction. Several unsuccessful approaches toward 1 are also described, which shed light on some of the unique chemistry of thiadiazoles. (C) 2004 lsevier Ltd. All rights reserved.
• It Is the Outside That Counts: Chemical and Physical Control of Dynamic Surfaces
  作者：Sarah M. Brosnan、Andrew H. Brown、Valerie Sheares Ashby

  DOI：10.1021/ja308080g

  日期：2013.2.27

  Materials capable of dynamically controlling surface chemistry and topography are highly desirable. We have designed a system that is uniquely able to remotely control the presented functionality and geometry at a given time by using a functionalizable shape memory material. This was accomplished by incorporating controlled amounts of an azide-containing monomer into a shape memory polymeric material. These materials are capable of physically changing surface geometry over a broad range of length scales from >1 mm to 100 nm. Using copper-assisted click chemistry, they can be functionalized with a variety of molecules to yield different surfaces. Combining these features gave materials that can change both the presented geometry and functionality at tunable transition temperatures.